Bài 14 : 

Vì metan không tác dụng với Brom nên : 

\(n_{C2H4Br2}=\dfrac{4,7}{188}=0,025\left(mol\right)\)

a) Pt : \(C_2H_4+Br_2\rightarrow C_2H_4Br_{2|}\)

              1          1                1

            0,025                    0,025

b) \(n_{C2H4}=\dfrac{0,025.1}{1}=0,025\left(mol\right)\)

\(V_{C2H4\left(dktc\right)}=0,025.22,4=0,56\left(l\right)\)

\(V_{CH4\left(dktc\right)}=1,4-0,56=0,84\left(l\right)\)

⁰/₀V_CH4 = \(\dfrac{0,84.100}{1,4}=60\)⁰/₀

⁰/₀V_C2H4 = \(\dfrac{0,56.100}{1,4}=40\)⁰/₀

 Chúc bạn học tốt

n Br2=\(\dfrac{32}{160}\)=0,2 mol

C2H2+2Br2->C2H2Br4

0,1------0,2 mol

=>%VC2H2=\(\dfrac{0,1.22,4}{5,6}\).100=40%

=>%VCH4=100-40=60%

=>n CH4=\(\dfrac{5,6-0,1.22,4}{22,4}\)=0,15 mol

CH4+2O2-to>CO2+2H2O

0,15----0,3

C2H2+\(\dfrac{5}{2}\)O2-to>2CO2+H2O

0,1-----0,25 mol

=>VO2=(0,3+0,25).22,4=12,32l

\(n_{C_2H_4Br_2}=\dfrac{9,4}{188}=0,05mol\)

\(n_{hh}=\dfrac{5,6}{22,4}=0,25mol\)

\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

0,05       0,05         0,05           ( mol )

\(m_{Br_2}=0,05.160=8g\)

\(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,05}{0,25}.100=20\%\\\%V_{CH_4}=100\%-20\%=80\%\end{matrix}\right.\)

1. \(n_{Br_2}=0,4.0,5=0,2\left(mol\right)\)

PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Theo PT: \(n_{C_2H_4}=n_{Br_2}=0,2\left(mol\right)\Rightarrow V_{C_2H_4}=0,2.22,4=4,48\left(l\right)\)

2. \(n_{C_2H_4Br_2}=\dfrac{9,4}{188}=0,05\left(mol\right)\)

PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Theo PT: \(n_{C_2H_4}=n_{C_2H_4Br_2}=0,05\left(mol\right)\)

\(\Rightarrow\%V_{C_2H_4}=\dfrac{0,05.22,4}{1,4}.100\%=80\%\)

\(\Rightarrow\%V_{CH_4}=100-80=20\%\)

\(a,n_{Br_2}=\dfrac{6,4}{160}=0,04\left(mol\right)\)

PTHH: C₂H₄ + Br₂ ---> C₂H₄Br₂

           0,04<---0,04

\(\rightarrow\left\{{}\begin{matrix}V_{C_2H_4}=0,04.22,4=0,896\left(l\right)\\V_{CH_4}=2,24-0,896=1,344\left(l\right)\end{matrix}\right.\\ b,\rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,896}{2,24}.100\%=40\%\\\%V_{CH_4}=100\%-40\%=60\%\end{matrix}\right.\)

a, PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

b, - Khí thoát ra là CH₄.

⇒ V_CH4 = 4,48 (l)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{4,48}{11,2}.100\%=40\%\\\%V_{C_2H_4}=100-40=60\%\end{matrix}\right.\)

a) \(C_2H_4 + Br_2 \to C_2H_4Br_2\)

b)

\(n_{C_2H_4} = n_{Br_2} = \dfrac{5,6}{160} = 0,035(mol)\\ \%V_{C_2H_4} = \dfrac{0,035.22,4}{0,86}.100\% = 91,16\%\\ \%V_{CH_4} = 100\% - 91,16\% = 8,84\%\)

Cho hỗn hợp qua dung dịch brom dư

\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Khí thoát ra là \(CH_4\)

\(CH_4+2O_2\rightarrow^{t^o}CO_2+2H_2O\)

\(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)

Ta có:

\(n_{CaCO_3}=\frac{40}{100}=0,4mol=n_{CO_2}=n_{CH_4}\)

\(\rightarrow V_{CH_4}=0,4.22,4=8,96l\)

\(\rightarrow\%V_{CH_4}=\frac{8,96}{13,56}=66\%\rightarrow\%V_{C_2H_4}=34\%\)

\(n_{Br_2}=\dfrac{m_{Br_2}}{M_{Br_2}}=\dfrac{16}{160}=0,1mol\)

\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

0,1         0,1                        ( mol )

\(\%V_{C_2H_4}=\dfrac{0,1.22,4}{16,8}.100=13,33\%\)

\(\%V_{CH_4}=100\%-13,33\%=86,67\%\)