*Sửa đề: "13,44 lít H₂" và "24,9 gam hh 2 kim loại"

PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)

               a_____3a_____________\(\dfrac{3}{2}\)a                (mol)

            \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)

               b_____2b_____________b                   (mol)

Ta lập HPT: \(\left\{{}\begin{matrix}27a+65b=24,9\\\dfrac{3}{2}a+b=\dfrac{13,44}{22,4}=0,6\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}a=0,2\\b=0,3\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}n_{Al}=0,2\left(mol\right)\\n_{Zn}=0,3\left(mol\right)\\n_{HCl}=1,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,2\cdot27=5,4\left(g\right)\\m_{Zn}=19,5\left(g\right)\\m_{ddHCl}=\dfrac{1,2\cdot36,5}{7,3\%}=600\left(g\right)\end{matrix}\right.\)

\(n_{H2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\)

Pt : \(2Al+6HCl\rightarrow2AlCl_3+3H_2|\)

        2           6              2           3

        a          0,6                       1,5a

    \(Fe+2HCl\rightarrow FeCl_2+H_2|\)

      1         2                       1b

      b       0,8

a) Gọi a là số mol của Al

           b là số mol của Fe

\(m_{Al}+m_{Fe}=27,8\left(g\right)\)

⇒ \(n_{Al}.M_{Al}+n_{Fe}.M_{Fe}=27,8g\)

  ⇒ 27a + 56b = 27,8g(1)

Theo phương trình : 1,5a + 1b = 0,7(2)

Từ(1),(2), ta có hệ phương trình : 

          27a + 56b = 27,8

           1,5a + 1b = 0,7

           ⇒ \(\left\{{}\begin{matrix}a=0,2\\b=0,4\end{matrix}\right.\)

    \(m_{Al}=0,2.27=5,4\left(g\right)\)

    \(m_{Fe}=0,4.56=22,4\left(g\right)\)

b) ⁰/₀Al = \(\dfrac{5,4.100}{27,8}=19,42\)⁰/₀

    ⁰/₀Fe = \(\dfrac{22,4.100}{27,8}=80,58\)⁰/₀

c) \(n_{HCl\left(tổng\right)}=0,6+0,8=1,4\left(g\right)\)

⇒ \(m_{HCl}=1,4.36,5=51,1\left(g\right)\)

 Chúc bạn học tốt

Zn+2HCl->ZnCl2+H2

ZnO+2HCl->ZnCl2+H2O

nH2=0.2(mol)->nZn=0.2(mol).mZn=13(g)

mZnO=21.1-13=8.1(g)

nZnO=0.1(mol)

Tổng nHCl cần dùng:0.2*2+0.1*2=0.6(mol)

mHCl=21.9(g)

C%ddHCl=21.9:200*100=10.95%

n muối=0.2+.1=0.3(mol)

m muối=40.8(g)

Giúp mình câu b) với 

a) $n_{Al} = 0,2(mol)$

b)

$n_{H_2SO_4} = \dfrac{294.20\%}{98} = 0,6(mol)$

$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$

$Al_2O_3 + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2O$

$\Rightarrow n_{Al_2O_3} = \dfrac{0,6 - 0,2.1,5}{3} = 0,1(mol)$
$m = 0,1.102 = 10,2(gam)$
$n_{Al_2(SO_4)_3} = \dfrac{1}{3}n_{H_2SO_4} = 0,2(mol)$

$m_{dd} = 0,2.27 + 10,2 + 294 - 0,3.2 = 309(gam)$
$C\%_{Al_2(SO_4)_3} = \dfrac{0,2.342}{309}.100\% = 22,1\%$

\(n_{H_2}=\dfrac{17,353}{24,79}=0,7\left(mol\right)\\ Đặt:n_{Al}=a\left(mol\right);n_{Fe}=b\left(mol\right)\left(a,b>0\right)\\ PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ \Rightarrow\left\{{}\begin{matrix}27a+56b=27,8\\1,5a+b=0,7\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,4\end{matrix}\right.\\ a,\%m_{Al}=\dfrac{0,2.27}{27,8}.100\%=19,424\%\\\Rightarrow\%m_{Fe}=80,576\%\\ b,n_{HCl}=3a+2b=1,4\left(mol\right)\\ m_{ddHCl}=\dfrac{1,4.36,5.100}{20}=255,5\left(g\right) \Rightarrow4\approx\approx\approx\Rightarrow FeHCm=\)

PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)

            \(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)

a) Ta có: \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)=n_{Zn}\)

\(\Rightarrow\%m_{Zn}=\dfrac{0,4\cdot65}{36,2}\cdot100\%\approx71,23\%\) \(\Rightarrow\%m_{Al_2O_3}=28,77\%\)

c) Ta có: \(n_{Al_2O_3}=\dfrac{36,2-0,4\cdot65}{102}=0,1\left(mol\right)\)

Theo PTHH: \(n_{HCl}=2n_{Zn}+6n_{Al_2O_3}=1,4\left(mol\right)\)

\(\Rightarrow m_{ddHCl}=\dfrac{1,4\cdot36,5}{10\%}=511\left(g\right)\) \(\Rightarrow V_{ddHCl}=\dfrac{511}{1,1}\approx464,5\left(ml\right)=0,4645\left(l\right)\)

c) Theo PTHH: \(\left\{{}\begin{matrix}n_{ZnCl_2}=0,4\left(mol\right)\\n_{AlCl_3}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{ZnCl_2}}=\dfrac{0,4}{0,4645}\approx0,86\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,2}{0,4645}\approx0,43\left(M\right)\end{matrix}\right.\)

Câu 1 : 

\(n_{H2}=\dfrac{5,04}{22,4}=0,225\left(mol\right)\)

Pt : \(2Al+6HCl\rightarrow2AlCl_3+3H_2|\)

         2          6            2             3

         a       0,15                       1,5a

        \(Zn+2HCl\rightarrow ZnCl_2+H_2|\) 

         1          2               1          1

         b        0,3                          1b

a) Gọi a là số mol của Al

           b là số mol của Zn

\(m_{Al}+m_{Zn}=11,1\left(g\right)\)

⇒ \(n_{Al}.M_{Al}+n_{Zn}.M_{Zn}=11,1g\)

 ⇒ 27a + 65b = 11,1g(1)

Theo phương trình : 1,5a + 1b = 0,225(2)

Từ(1),(2), ta có hệ phương trình : 

          27a + 65b = 11,1g

          1,5a + 1b = 0,225

            ⇒ \(\left\{{}\begin{matrix}a=0,05\\b=0,15\end{matrix}\right.\)

\(m_{Al}=0,05.27=1,35\left(g\right)\)

\(m_{Zn}=0,15.65=9,75\left(g\right)\)

⁰/₀Al = \(\dfrac{1,35.100}{11,1}=12,16\)⁰/₀

⁰/₀Zn = \(\dfrac{9,75.100}{11,1}=87,84\)⁰/₀

b) \(n_{HCl\left(tổng\right)}=0,15+0,3=0,45\left(mol\right)\)

\(V_{ddHCl}=\dfrac{0,45}{1}=0,45\left(l\right)\)

 Chúc bạn học tốt

Câu 2 : 

\(n_{H2}=\dfrac{1,456}{22,4}=0,065\left(mol\right)\)

Pt : \(Fe+2HCl\rightarrow FeCl_2+H_2|\)

         1         2             1           1

         a        0,1                        1a

          \(2Al+6HCl\rightarrow2AlCl_3+3H_2|\)

             2          6              2            3

              b       0,03                         1,5b

a) Gọi a là số mol của Fe

           b là số mol của Al

\(m_{Fe}+m_{Al}=3,07\left(g\right)\)

⇒ \(n_{Fe}.M_{Fe}+n_{Al}.M_{Al}=3,07g\)

⇒ 56a + 27b = 3,07g(1)

Theo phương trình : 1a + 1,5b = 0,065(2)

Từ(1),(2),ta có hệ phương trình : 

         56a + 27b = 3,07g

         1a + 1,5b = 0,065

            ⇒ \(\left\{{}\begin{matrix}a=0,05\\b=0,01\end{matrix}\right.\)

\(m_{Fe}=0,05.56=2,8\left(g\right)\)

\(m_{Al}=0,01.27=0,27\left(g\right)\)

⁰/₀Fe = \(\dfrac{2,8.100}{3,07}=91,21\)⁰/₀

⁰/₀Al = \(\dfrac{0,27.100}{3,07}=8,79\)⁰/₀

b) \(n_{HCl\left(tổng\right)}=0,1+0,03=0,13\left(mol\right)\)

\(m_{HCl}=0,13.36,5=4,745\left(g\right)\)

\(m_{ddHCl}=\dfrac{4,745.100}{10}=47.45\left(g\right)\)

 Chúc bạn học tốt

a) PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

                   a_____2a______a_____a      (mol)

                \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)

                    b_____3b_______b_____\(\dfrac{3}{2}\)b         (mol)

Ta lập HPT: \(\left\{{}\begin{matrix}56a+27b=36,1\\a+\dfrac{3}{2}b=\dfrac{21,28}{22,4}=0,95\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,5\\b=0,3\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,5\cdot56=28\left(g\right)\\m_{Al}=8,1\left(g\right)\end{matrix}\right.\)

b+c) Theo các PTHH: \(\left\{{}\begin{matrix}n_{HCl}=2a+3b=1,9\left(mol\right)\\n_{FeCl_2}=0,5\left(mol\right)\\n_{AlCl_3}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{HCl}}=\dfrac{1,9}{0,2}=9,5\left(M\right)\\C_{M_{FeCl_2}}=\dfrac{0,5}{0,2}=2,5\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\end{matrix}\right.\)

a) PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)

                \(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)

b) Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)=n_{Zn}\) \(\Rightarrow n_{ZnO}=\dfrac{20-0,1\cdot65}{81}=\dfrac{1}{6}\left(mol\right)\)

\(\Rightarrow n_{ZnCl_2}=n_{Zn}+n_{ZnO}=\dfrac{4}{15}\left(mol\right)\) 

Mặt khác: \(m_{H_2}=0,1\cdot2=0,2\left(g\right)\)

\(\Rightarrow m_{dd}=m_{hh}+m_{ddHCl}-m_{H_2}=119,8\left(g\right)\) \(\Rightarrow C\%_{ZnCl_2}=\dfrac{\dfrac{4}{15}\cdot136}{119,8}\cdot100\%\approx30,27\%\)

c) Giả sử khí là SO₂

PTHH: \(Zn+H_2SO_{4\left(đ\right)}\xrightarrow[]{t^o}ZnSO_4+SO_2\uparrow+H_2O\)

Theo PTHH: \(n_{SO_2}=n_{Zn}=0,1\left(mol\right)\) \(\Rightarrow V_{SO_2}=0,1\cdot22,4=2,24\left(l\right)\)