số xấu lắm bn coi có lộn số j hơm:<

nAl=0,337 mol á 

t có đề i hệt giải cho dc khong

\(a,PTHH:2Al+3X_2\rightarrow2AlX_3\\ Theo.ĐLBTKL,ta.có:\\ m_{Al}+m_{X_2}=m_{AlX_3}\\ \Leftrightarrow m_{Al}+33,6=37,38\\ \Leftrightarrow m_{Al}=3,78\left(g\right)\\ \Rightarrow n_{Al}=\dfrac{3,78}{27}=0,14\left(mol\right)\\ n_{X_2}=\dfrac{3}{2}.0,14=0,21\left(mol\right)\\ \Rightarrow M_{X_2}=\dfrac{33,6}{0,21}=160\left(\dfrac{g}{mol}\right)\\ \Rightarrow M_X=80\left(\dfrac{g}{mol}\right)\\ \Rightarrow X:Brom\left(Br=80\right)\\ b,n_{AlBr_3}=\dfrac{42,72}{267}=0,16\left(mol\right)\\ AlBr_3+3AgNO_3\rightarrow Al\left(NO_3\right)_3+3AgBr\downarrow\left(vàng.nhạt\right)\\ n_{AgBr}=n_{AgNO_3}=0,16.3=0,48\left(mol\right)\\ \Rightarrow m_T=m_{\downarrow}=m_{AgBr}=188.0,48=90,24\left(g\right)\)

\(m_{ddZ}=42,72+447,52-90,24=400\left(g\right)\\ n_{Al\left(NO_3\right)_3}=n_{AlBr_3}=0,16\left(mol\right)\\ \Rightarrow C\%_{ddZ}=C\%_{ddAl\left(NO_3\right)_3}=\dfrac{0,16.213}{400}.100=8,52\%\)

\(c,n_{Br_2}=\dfrac{12,8}{160}=0,08\left(mol\right)\\ 2NaI+Br_2\rightarrow2NaBr+I_2\\ n_{I_2}=n_{Br_2}=0,08\left(mol\right);n_{NaI}=2.0,08=0,16\left(mol\right)\\ \Rightarrow x=C_{MddNaI}=\dfrac{0,16}{0,25}=0,64\left(M\right)\\ m_{I_2}=0,08.254=20,32\left(g\right)\)

a, Gọi \(m_{NaCl\left(thêm\right)}=a\left(g\right)\)

\(m_{NaCl\left(bđ\right)}=5\%.100=5\left(g\right)\\ \Rightarrow C\%_{NaCl}=\dfrac{5+a}{100+a}.100\%=5,5\%\\ \Leftrightarrow a=0,53\left(g\right)\)

b, \(m_{NaCl}=58,5.5,5\%=3,2175\left(g\right)\\ n_{NaCl}=\dfrac{3,2175}{58,5}=0,055\left(mol\right)\)

PTHH: NaCl + AgNO₃ ---> AgCl↓ + NaNO₃

          0,055-->0,055------>0,055---->0,055

\(m_{AgCl}=0,055.143,5=7,8925\left(g\right)\\ m_{ddY}=58,5+200-7,8925=250,6075\left(g\right)\\ \Rightarrow C\%_{NaNO_3}=\dfrac{0,055.85}{250,6075}.100\%=1,87\%\)

Đáp án B

Đáp án B

Ag + + Cl -  → AgCl

n AgNO 3  = 0,8 mol

Áp dụng ĐL BTKL:

m X + m AgNO 3 = m kết   tủa + m muối   Y

m muối   Y = m X + m AgNO 3 - m kết   tủa  = 46,5 + 0,8x170 - 114,8 = 67,7g

Câu 1:

Gọi số mol NaCl, KCl là a, b (mol)

=> 58,5a + 74,5b = 6,81 (1)

\(n_{AgCl}=\dfrac{14,35}{143,5}=0,1\left(mol\right)\)

Bảo toàn Cl: a + b = 0,1 (2)

(1)(2) => a = 0,04 (mol); b = 0,06 (mol)

\(\left\{{}\begin{matrix}m_{NaCl}=0,04.58,5=2,34\left(g\right)\\m_{KCl}=0,06.74,5=4,47\left(g\right)\end{matrix}\right.\)

Câu 2:

Gọi số mol MgCl₂, KCl là a, b (mol)

=> 95a + 74,5b = 3,93 (1)

25ml dd A chứa \(\left\{{}\begin{matrix}MgCl_2:0,05a\left(mol\right)\\KCl:0,05b\left(mol\right)\end{matrix}\right.\)

n_AgNO3 = 0,05.0,06 = 0,003 (mol)

=> n_AgCl = 0,003 (mol)

Bảo toàn Cl: 0,1a + 0,05b = 0,003 (2)

(1)(2) => a = 0,01 (mol); b = 0,04 (mol)

\(\left\{{}\begin{matrix}\%m_{MgCl_2}=\dfrac{0,01.95}{3,93}.100\%=24,173\%\\\%m_{KCl}=\dfrac{0,04.74,5}{3,93}.100\%=75,827\%\end{matrix}\right.\)