Gọi a=nCu; b=nZn

Ta có 64a+65b=15,75 (1)

Zn+H2ZO4-> ZnSO4+H2

b.                                     b

 b=nH2= 3,36/22,4=0,15mol

mZn= 0,15.65= 9,75g

mCu=15,75-9,75=6(g)

%mZn=9,75.100%/15,75 =61,9%

%mCu=6.100%/15,75*38,1%

\(n_{H_2}=\dfrac{3,36}{22,4}=0,15(mol)\\ Zn+H_2SO_4\to ZnSO_4+H_2\\ \Rightarrow n_{Zn}=0,15(mol)\\ \Rightarrow \%_{Zn}=\dfrac{0,15.65}{15,75}.100\%=61,9\%\\ \Rightarrow \%_{Cu}=100\%-61,9\%=38,1\%\\ b,n_{ZnSO_4}=0,15(mol)\\ \Rightarrow m_{ZnSO_4}=0,15.161=24,15(g)\)

Tr oi cuu với ạ

ta co cu khong pu voi h2so4 zn td tao ra khi la h2,viet pt tinh mol suy he pt tinh mol cua zn tinh khoi luong zn lay hh ban dau - khoi luong zn tim duoc khoi luong cu .b)tu khi suy he pt tinh mol muoi roi tinh khoi luong

\(n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)

PTHH: Zn + H₂SO₄ --> ZnSO₄ + H₂

_____0,05<------------------------0,05

=> m_Zn = 0,05.65 = 3,25 (g)

=> m_Cu = 6,45 - 3,25 = 3,2 (g)

\(33,6(l) \to 3,36(l)\\ Zn+H_2SO_4 \to ZnSO_4+H_2\\ n_{H_2}=0,15(mol)\\ n_{Zn}=n_{H_2}=0,15(mol)\\ a/\\ \%m_{Zn}=\frac{0,15.65}{15,75}.100\%=61,9\%\\ \%m_{Cu}=38,06\%\\ b/\\ n_{ZnSO_4}=n_{H_2}=0,15(mol)\\ m_{ZnSO_4}=0,15.161=24,15(g)\)

a) \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

PTHH: 2Al + 3H₂SO₄ --> Al₂(SO₄)₃ + 3H₂

           0,1<----------------------------0,15

=> \(\%m_{Al}=\dfrac{0,1.27}{7,5}.100\%=36\%\)

\(\%m_{Cu}=100\%-36\%=64\%\)

b) \(n_{Cu}=\dfrac{7,5-0,1.27}{64}=0,075\left(mol\right)\)

PTHH: Cu + 2H₂SO₄ --> CuSO₄ + SO₂ + 2H₂O

          0,075------------------------>0,075

            2Al + 6H₂SO₄ --> Al₂(SO₄)₃ + 3SO₂ + 6H₂O

              0,1----------------------------->0,15

=> V_SO2 = (0,075 + 0,15).22,4 = 5,04 (l)

Bài 1:

PTHH: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)

            \(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)

Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)=n_{Fe}\)

\(\Rightarrow\%m_{Fe}=\dfrac{0,1\cdot56}{37,6}\cdot100\%\approx14,89\%\)

\(\Rightarrow\%m_{Fe_2O_3}=85,11\%\) 

Bài 3: 

PTHH: \(2HNO_3+Ba\left(OH\right)_2\rightarrow Ba\left(NO_3\right)_2+2H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{HNO_3}=0,05\cdot1=0,05\left(mol\right)\\n_{Ba\left(OH\right)_2}=\dfrac{342\cdot5\%}{171}=0,1\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,05}{2}< \dfrac{0,1}{1}\) \(\Rightarrow\) Axit p/ứ hết, Bazơ còn dư sau p/ứ

\(\Rightarrow\) Dung dịch sau p/ứ làm quỳ tím hóa xanh

Theo PTHH: \(n_{Ba\left(NO_3\right)_2}=\dfrac{1}{2}n_{HNO_3}=0,025\left(mol\right)\) \(\Rightarrow m_{Ba\left(NO_3\right)_2}=0,025\cdot261=6,525\left(g\right)\)

Bài 2:

Theo đề bài: \(\%m_{Cu}=\dfrac{6,4}{14,2}\cdot100\%\approx45,07\%\)

PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)

               a_________________________\(\dfrac{3}{2}\)a   (mol)

            \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\uparrow\)

                b_____________________b     (mol)

Ta lập được hệ phương trình \(\left\{{}\begin{matrix}27a+24b=14,2-6,4=7,8\\\dfrac{3}{2}a+b=\dfrac{8,96}{22,4}=0,4\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2\cdot27}{14,2}\cdot100\%\approx38,03\%\\\%m_{Mg}=100\%-38,03\%-45,07\%=16,9\%\end{matrix}\right.\)

\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

PTHH: Fe + H₂SO₄ --> FeSO₄ + H₂

_____0,15<--------------0,15<---0,15

=> m_Fe = 0,15.56 = 8,4 (g)

=> m_Cu = 11,6 - 8,4 = 3,2 (g)

\(\left\{{}\begin{matrix}\%Fe=\dfrac{8,4}{11,6}.100\%=72,414\%\\\%Cu=\dfrac{3,2}{11,6}.100\%=27,586\%\end{matrix}\right.\)

m_FeSO4 = 0,15.152 = 22,8 (g)