\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

PTHH: Zn + 2HCl ---> ZnCl₂ + H₂

           0,2<--0,4<------0,2<-----0,2

=> \(\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,2.65}{21,1}.100\%=61,61\%\\\%m_{ZnO}=100\%-61,61\%=38,39\%\end{matrix}\right.\)

\(n_{ZnO}=\dfrac{21,1-0,2.65}{81}=0,1\left(mol\right)\)

PTHH: ZnO + 2HCl ---> ZnCl₂ + H₂O

            0,1---->0,2------>0,1

=> \(C\%_{HCl}=\dfrac{\left(0,2+0,4\right).36,5}{200}.100\%=10,95\%\)

\(m_{mu\text{ố}i}=m_{ZnCl_2}=\left(0,1+0,2\right).136=40,8\left(g\right)\)

- Cả 2 chất trong hhA đều tác dụng được với dd HCl dư. Nhưng chỉ có Zn tác dụng với dd HCl dư mới sinh ra khí H₂

\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ PTHH:\left(1\right)Zn+2HCl\rightarrow ZnCl_2+H_2\\ \left(2\right)ZnO+2HCl\rightarrow ZnCl_2+H_2O\\ TheoPTHH\left(1\right):n_{Zn}=n_{ZnCl_2\left(1\right)}=n_{H_2}=0,2\left(mol\right)\\ m_{ZnO}=m_{hhA}-m_{Zn}=21,1-65.0,2=8,1\left(g\right)\\ n_{ZnO}=\dfrac{8,1}{81}=0,1\left(mol\right)\\ n_{ZnCl_2\left(2\right)}=n_{ZnO}=0,1\left(mol\right)\\ n_{ZnCl_2\left(tổng\right)}=0,2+0,1=0,3\left(mol\right)\\ m_{ddB}=m_{hhA}+m_{ddHCl}-m_{H_2}=21,1+200-0,2.2=220,7\left(g\right)\\ C\%_{ddZnCl_2}=\dfrac{136.0,3}{220,7}.100\%\approx18,487\%\)

\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\\ Zn+2HCl\rightarrow ZnCl_2+H_2\left(1\right)\\ n_{Zn}=n_{H_2}=n_{ZnCl_2\left(1\right)}=0,2mol\\ n_{ZnO}=\dfrac{21,1-0,2.65}{81}=0,1mol\\ ZnO+2HCl\rightarrow ZnCl_2+H_2O\left(2\right)\\ n_{ZnCl_2\left(2\right)}=n_{ZnO}=0,1mol\\ C_{\%B}=C_{\%ZnCl_2}=\dfrac{\left(0,2+0,1\right).136}{21,1+200-0,2.2}\cdot100\%=18,49\%\)

Gọi \(n_{Fe}=x\left(mol\right)\)\(;n_{Zn}=y\left(mol\right)\)

\(n_{H_2}=\dfrac{6,72}{22,4}=0,3mol\)

Ta có:  \(\left\{{}\begin{matrix}56x+65y=18,6\\2x+2y=2n_{H_2}=0,6\end{matrix}\right.\)\(\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)

\(\%m_{Fe}=\dfrac{0,1\cdot56}{18,6}\cdot100\%=30,11\%\)

\(\%m_{Zn}=100\%-30,11\%=69,89\%\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

0,1     0,2

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

0,2     0,4

\(n_{HCl}=0,2+0,4=0,6mol\)

\(C_M=\dfrac{n}{V}=\dfrac{0,6}{0,2}=3M\)

1> Mg+2HCl------>MgCl2+H2

      Zn+2HCl----->ZnCl2+H2

mHCl=250.7,3/100=18,25 g

nHCl=18,25/36,50,5 mol

Giả sử 4,93 g hỗn hợp toàn là kim loại Mg

n tối đa =4,93/24=0,205 mol--->nHCl tối đa=0,205.2=0,41 mol

giả sử 4,93 g hỗn hợp toàn là Zn

n tối thiểu =4,93/65=0,076 mol----->nHCl tối thiểu=0,076.2=0,152 mol-

----->0,152<nHCltham gia phản ứng<0,41

mà nHcl=0,5 mol----->HCl dư-----> hỗn hợp tan hết

PTHH: \(Fe_xO_y+yH_2\xrightarrow[]{t^o}xFe+yH_2O\)  (1)

            \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)  (2)

a) Ta có: \(\left\{{}\begin{matrix}n_O=n_{H_2O}=n_{H_2\left(1\right)}=\dfrac{0,672}{22,4}=0,03\left(mol\right)\\n_{Fe}=n_{H_2\left(2\right)}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(n_{Fe}:n_O=x:y=0,02:0,03=2:3\)

\(\Rightarrow\) CTHH của oxit là Fe₂O₃  

b) Theo PTHH: \(\left\{{}\begin{matrix}n_{FeCl_2}=n_{H_2}=0,02\left(mol\right)\\n_{HCl\left(dư\right)}=\dfrac{300\cdot7,3\%}{36,5}-2n_{H_2}=0,56\left(mol\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd\left(sau.p/ứ\right)}=m_{Fe}+m_{ddHCl}-m_{H_2}=0,02\cdot56+300-0,02\cdot2=301,08\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{FeCl_2}=\dfrac{0,02\cdot127}{301,08}\cdot100\%\approx0,84\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,56\cdot36,5}{301,08}\cdot100\%\approx6,79\%\end{matrix}\right.\)

a)

n HCl = 300.7,3%/36,5 = 0,6(mol)

n H2 = 0,448/22,4 = 0,02(mol)

$Fe + 2HCl \to FeCl_2 + H_2$

n HCl > 2n H2 nên HCl dư

$n_{Fe} = n_{H_2} = 0,02(mol)$

$H_2 + O_{oxit} \to H_2O$

n O(oxit) = n H2 = 0,672/22,4 = 0,03(mol)

Ta có : 

n Fe : n O =0,02 : 0,03 = 2 : 3

Vậy oxit là $Fe_2O_3$

b)

m dd = 0,02.56 + 300  -0,02.2 = 301,08(gam)

n HCl dư = 0,6 - 0,02.2 = 0,56(mol)

n FeCl2 = n Fe = 0,02(mol)

Vậy :

C% HCl = 0,56.36,5/301,08  .100% = 6,8%

C% FeCl2 = 0,02.127/301,08  .100% = 0,84%

\($a/$\\ Zn+2HCl \to ZnCl_2+H_2\\ b/\\ n_{Zn}=0,1(mol)\\ n_{HCl}=0,1.2=0,2(mol)\\ m_{ddHCl}=\frac{0,2.36,5.100}{7,3}=100(g)\\ C\%_{ZnCl_2}=\frac{0,1.136}{100+6,5-0,1.2}.100\%=12,8\%\)

\(a/\\ Zn+2HCl \to ZnCl_2+H_2\\ b/\\ n_{Zn}=\frac{6,5}{65}=0,1(mol)\\ n_{HCl}=0,2(mol)\\ m_{ddsaupu}=\frac{0,1.36,5.100}{7,3}+6,5-0,1.2=56,3(g)\\ C\%_{ZnCl_2}=\frac{0,1.136}{56,3}.100\%=24,16\%\)

a,\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)

PTHH: Zn + 2HCl → ZnCl₂ + H₂

Mol:     0,1    0,05       0,1

b, \(m_{HCl}=0,05.36,5=2,92\left(g\right)\)

  \(m_{ddHCl}=\dfrac{2,92}{7,3\%}=40\left(g\right)\)

  \(m_{ddsaupứ}=6,5+40-0,1.2=46,3\left(g\right)\)

\(\Rightarrow C\%_{ddZnCl_2}=\dfrac{0,1.136.100\%}{46,3}=29,4\%\)

Bài 1 : 

224ml = 0,224l

\(n_{H2}=\dfrac{0,224}{22,4}=0,01\left(mol\right)\)

Pt : \(Ba+2H_2O\rightarrow Ba\left(OH\right)_2+H_2|\)

         1         2               1               1

        0,01                     0,01          0,01

        \(BaO+H_2O\rightarrow Ba\left(OH\right)_2|\)

           1           1                 1

          0,01                         0,01

\(n_{Ba}=\dfrac{0,01.1}{1}=0,01\left(mol\right)\)

\(m_{Ba}=0,01.137=1,37\left(g\right)\)

\(m_{BaO}=2,9-1,37=1,53\left(g\right)\)

⁰/₀Ba = \(\dfrac{1,37.100}{2,9}=47,24\)⁰/₀

⁰/₀BaO = \(\dfrac{1,53.100}{2,9}=52,76\)⁰/₀

Có : \(m_{BaO}=1,53\left(g\right)\)

\(n_{BaO}=\dfrac{1,53}{153}=0,01\left(mol\right)\)

\(n_{Ba\left(OH\right)2\left(tổng\right)}=0,01+0,01=0,02\left(mol\right)\)

⇒ \(m_{Ba\left(OH\right)2}=0,02.171=3,42\left(g\right)\)

 Chúc bạn học tốt

Bài 2:

a, \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)

   \(m_{HCl}=200.7,3\%=14,6\left(g\right)\Rightarrow n_{HCl}=\dfrac{14,6}{36,5}=0,4\left(mol\right)\)

PTHH: Zn + 2HCl → ZnCl₂ + H₂

Mol:     0,1      0,2        0,1       0,1

Ta có: \(\dfrac{0,1}{1}< \dfrac{0,4}{2}\) ⇒ Zn pứ hết, HCl dư

\(m_{HCldư}=\left(0,4-0,2\right).36,5=7,3\left(g\right)\)

b, \(V_{H_2}=0,1.22,4=2,24\left(l\right)\)

c, \(m_{dd.sau.pứ}=6,5+200-0,1.2=206,3\left(g\right)\)

\(C\%_{HCldư}=\dfrac{7,3.100\%}{206,3}=3,54\%\)

\(C\%_{ZnCl_2}=\dfrac{0,1.136.100\%}{206,3}=6,59\%\)

Bài 1.

\(n_{H_2}=\dfrac{0,224}{22,4}=0,01mol\)

\(Ba+2H_2O\rightarrow Ba\left(OH\right)_2+H_2\)

  0,01                                    0,01     ( mol )

\(m_{Ba}=0,01.137=1,37g\)

\(\%m_{Ba}=\dfrac{1,37}{2,9}.100=47,24\%\)

\(\%m_{BaO}=100\%-47,24\%=52,76\%\)

\(m_{BaO}=2,9-1,37=1,53g\)

\(n_{BaO}=\dfrac{1,53}{153}=0,01mol\)

\(BaO+H_2O\rightarrow Ba\left(OH\right)_2\)

0,01                       0,01    ( mol )

\(Ba+2H_2O\rightarrow Ba\left(OH\right)_2+H_2\)

0,01                      0,01                     ( mol )

\(m_{Ba\left(OH\right)_2}=\left(0,01+0,01\right).171=3,42g\)

Bài 2.

\(n_{Zn}=\dfrac{6,5}{65}=0,1mol\)

\(m_{HCl}=200.7,3\%=14,6g\)

\(n_{HCl}=\dfrac{14,6}{36,5}=0,4mol\)

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

0,1  <  0,4                                 ( mol )

0,1       0,2               0,1        0,1     ( mol )

\(m_{HCl\left(dư\right)}=\left(0,4-0,2\right).36,5=7,3g\)

\(V_{H_2}=0,1.22,4=2,24l\)

a)

$Fe + 2HCl \to FeCl_2 + H_2$
$FeO +2 HCl \to FeCl_2 + H_2O$

b)

Theo PTHH : 

$n_{Fe} = n_{H_2} = \dfrac{4,48}{22,4} = 0,2(mol)$

$\%m_{Fe} = \dfrac{0,2.56}{20}.100\% = 56\%$

$\%m_{FeO} = 100\% - 56\% = 44\%$

c) $n_{FeO} = \dfrac{11}{90}(mol)$
$n_{HCl} = 2n_{Fe} + 2n_{FeO} = \dfrac{29}{45}(mol)$

$m_{dd\ HCl} = \dfrac{ \dfrac{29}{45}.36,5}{7,3\%} = 322,22(gam)$