\(n_{Na_2CO_3}=\dfrac{200.0,159}{106}=0,3mol\\ n_{BaCl_2}=\dfrac{200.0,208}{208}=0,2mol\\ a.Na_2CO_3+BaCl_2->2NaCl+BaCO_3\\ n_{Na_2CO_3}:1>n_{BaCl_2}:1\\ m_B=197.0,2=39,4g\\ Na_2CO_3+2HCl->2NaCl+H_2O+CO_2\\ V=\dfrac{2.0,1}{1}=0,2\left(L\right)=200\left(mL\right)\\ b.m_A=200+200-39,4=360,6g\\ C\%_{Na_2CO_3du}=\dfrac{106.0,1}{360,6}.100\%=2,94\%\\ C\%_{NaCl}=\dfrac{58,5.0,4}{360,6}.100\%=6,49\%\)

a) 

\(Na_2CO_3+BaCl_2\rightarrow BaCO_3+2NaCl\)

0,2 <---------- 0,2 ------> 0,2 -----> 0,4

\(n_{Na_2CO_3}=\dfrac{200.15,9\%}{100\%}:106=0,3\left(mol\right)\)

\(n_{BaCl_2}=\dfrac{200.20,8\%}{100\%}:208=0,2\left(mol\right)\)

Do \(\dfrac{0,3}{1}>\dfrac{0,2}{1}\) nên \(Na_2CO_3\) dư sau phản ứng.

Dung dịch A: \(n_{Na_2CO_3}=0,3-0,2=0,1\left(mol\right);n_{NaCl}:0,4\left(mol\right)\)

Kết tủa B: \(BaCO_3\)

\(m_B=m_{BaCO_3}=0,2.197=39,4\left(g\right)\)

Dung dịch A td với HCl:

\(Na_2CO_3+2HCl\rightarrow2NaCl+H_2O+CO_2\)

0,1 ---------> 0,2

\(V=V_{HCl}=\dfrac{0,2}{1}=0,2\left(l\right)\)

b)

\(m_{dd}=m_{dd.Na_2CO_3}+m_{dd.BaCl_2}-m_{BaCO_3}=200+200-39,4=360,6\left(g\right)\)

\(C\%_{Na_2CO_3}=\dfrac{0,1.106.100\%}{360,6}=2,94\%\)

\(C\%_{NaCl}=\dfrac{0,4.58,5.100\%}{360,6}=6,49\%\)

\(n_{KOH}=\dfrac{200.8,4}{100}:56=0,3\left(mol\right)\)

\(n_{FeCl_3}=\dfrac{250.3,25}{100}:162,5=0,05\left(mol\right)\)

\(3KOH+FeCl_3\rightarrow Fe\left(OH\right)_3\downarrow+3KCl\)

 0,15 <----- 0,05 -----> 0,05 --------> 0,15

Xét tỉ lệ thấy: \(\dfrac{0,3}{3}>\dfrac{0,05}{1}\) nên KOH dư sau phản ứng.

\(n_{KOH.dư}=0,3-0,15=0,15\left(mol\right)\)

Theo pthh \(n_{kt}=n_{Fe\left(OH\right)_3}=n_{FeCl_3}=0,05\left(mol\right)\)

\(\Rightarrow m=m_{Fe\left(OH\right)_3}=0,05.107=5,35\left(g\right)\)

Nung kết tủa:

\(2Fe\left(OH\right)_3\underrightarrow{t^o}Fe_2O_3+3H_2O\)

0,05---------> 0,025

Theo pthh \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=\dfrac{1}{2}.0,05=0,025\left(mol\right)\)

\(q=m_{F_2O_3}=0,025.160=4\left(g\right)\)

Dung dịch X gồm \(\left\{{}\begin{matrix}KOH:0,15\left(mol\right)\\KCl:0,15\left(mol\right)\end{matrix}\right.\)

\(m_{dd.X}=m_{dd.KOH}+m_{dd.FeCl_3}-m_{Fe\left(OH\right)_3}=200+250-5,35=444,65\left(g\right)\)

\(C\%_{KOH}=\dfrac{0,15.56.100}{444,65}=1,89\%\)

\(C\%_{KCl}=\dfrac{0,15.74,5.100}{444,65}=2,51\%\)

\(n_{Ba\left(OH\right)_2}=\dfrac{200.15\%}{100\%.171}=\dfrac{10}{57}mol\\ Ba\left(OH\right)_2+H_2SO_4\rightarrow BaSO_4+2H_2O\\ n_{Ba\left(OH\right)_2}=n_{BaSO_4}=\dfrac{10}{57}mol\\ b=m_{BaSO_4}=\dfrac{10}{57}\cdot233=40,88g\)

A chỉ còn nước thôi nên không có nồng độ % nhé

Bạn ơi , câu 1 sao dd NaCl lại tác dụng với NaCl v ?

\(C\%_X=\frac{40}{240}.100\%=16,7\left(\%\right)\)

\(PTHH:2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\downarrow\)

\(n_X=\frac{200.16,7}{100.40}=0,835\left(mol\right)\)

\(PTHH:Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)

\(m_{CuO}=0,835.80=66,8\left(g\right)\)

\(C\%_Y=\frac{0,835.142}{200+100-0,835.98}.100\%=42,17\left(\%\right)\)

( k chắc :>>)

nHCl=(200.14,6%)/100=0,8(mol)

nBa(OH)2=(17,1%.200)/100=0,2(mol)

PTHH: Ba(OH)2 +2 HCl -> BaCl2 + 2 H2O

Ta có: 0,8/2 > 0,2/1

=> HCl dư, Ba(OH)2 hết=> Tính theo nHCl

=> nBaCl2=nBa(OH)2=0,2(mol) => mBaCl2= 208.0,2= 41,6(g)

nHCl(dư)=0,8 - 0,2.2=0,4(mol) => mHCl(dư)=0,4.36,5=14,6(g)

mddsau= 200+200=400(g)

C%ddBaCl2=(41,6/400).100=10,4%

C%ddHCl(dư)= (14,6/400).100=3,65%

Chúc em học tốt!