a, PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)

Ta có: \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,1\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,1.27}{5,25}.100\%\approx51,43\%\\\%m_{Al_2O_3}\approx48,57\%\end{matrix}\right.\)

b, \(n_{Al_2O_3}=\dfrac{5,25-0,1.27}{102}=0,025\left(mol\right)\)

Theo PT: \(n_{HCl}=3n_{Al}+6n_{Al_2O_3}=0,45\left(mol\right)\)

\(\Rightarrow m_{ddHCl}=\dfrac{0,45.36,5}{29,2\%}=56,25\left(g\right)\)

c, \(n_{H_2SO_4}=\dfrac{1}{2}n_{HCl}=0,225\left(mol\right)\)

\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,225.98}{19,6\%}=112,5\left(g\right)\)

\(n_{H2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

a) Pt : \(2Al+2NaOH+2H_2O\rightarrow2NaAlO_2+3H_2|\)

             2             2             2                 2              3

           0,2           0,2                                             0,3

            \(Al_2O_3+2NaOH\rightarrow2NaAlO_2+H_2O|\)

                1              2                  2              1

               0,1          0,2

b) \(n_{Al}=\dfrac{0,3.2}{3}=0,2\left(mol\right)\)

\(m_{Al}=0,2.27=5,4\left(g\right)\)

\(m_{Al2O3}=15,6-5,4=10,2\left(g\right)\)

c) Có : \(m_{Al2O3}=10,2\left(g\right)\)

\(n_{Al2O3}=\dfrac{10,2}{102}=0,1\left(mol\right)\)

\(n_{NaOH\left(tổng\right)}=0,2+0,2=0,4\left(mol\right)\)

\(V_{ddNaOH}=\dfrac{0,4}{1}=0,4\left(l\right)=400\left(ml\right)\)

 Chúc bạn học tốt

a) \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

PTHH:
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\) (1)

\(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\) (2)

Theo PT (1): \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,2\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,2.27=5,4\left(g\right)\\m_{Al_2O_3}=15,6-5,4=10,2\left(g\right)\end{matrix}\right.\)

b) \(n_{Al_2O_3}=\dfrac{10,2}{102}=0,1\left(mol\right)\)

Theo PT (1), (2): \(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}+n_{Al_2O_3}=0,2\left(mol\right)\)

\(\Rightarrow m_{mu\text{ố}i}=m_{Al_2\left(SO_4\right)_3}=0,2.342=68,4\left(g\right)\)

c) Theo PT (1), (2): \(n_{H_2SO_4}=n_{H_2}+3n_{Al_2O_3}=0,6\left(mol\right)\)

\(\Rightarrow m_{H_2SO_4\left(c\text{ần}.d\text{ùng}\right)}=0,6.98=58,8\left(g\right)\)

Lượng khí hidro thoát ra là 0,15 mol.

a) Al₂O₃ + 2NaOH \(\rightarrow\) 2NaAlO₂ + H₂O

2Al + 2NaOH + 2H₂O \(\rightarrow\) 2NaAlO₂ + 3H₂.

b) Lượng Al phản ứng bằng 2/3 số mol khí hidro thoát ra và bằng 0,1 mol.

\(\Rightarrow\) %m_nhôm=\(\dfrac{27.0,1}{12,9}\).100%\(\approx\)20,93%, %m_{nhôm oxit}\(\approx\)100%-20,93%\(\approx\)79,07%.

\(n_{O_2}=\dfrac{5.6}{22.4}=0.25\left(mol\right)\)

\(n_{H_2}=\dfrac{10.08}{22.4}=0.45\left(mol\right)\)

\(n_{Fe}=a\left(mol\right),n_{Al}=b\left(mol\right)\)

\(3Fe+2O_2\underrightarrow{^{^{t^0}}}Fe_3O_4\)

\(a.......\dfrac{2a}{3}\)

\(4Al+3O_2\underrightarrow{^{^{t^0}}}2Al_2O_3\)

\(b.......\dfrac{3b}{4}\)

\(n_{O_2}=\dfrac{2a}{3}+\dfrac{3b}{4}=0.25\left(mol\right)\left(1\right)\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(n_{H_2}=a+1.5b=0.45\left(mol\right)\left(2\right)\)

\(\left(1\right),\left(2\right):a=0.15,b=0.2\)

\(m_{Fe}=0.15\cdot56=8.4\left(g\right)\)

\(m_{Al}=0.2\cdot27=5.4\left(g\right)\)

\(\%m_{Fe}=\dfrac{8.4}{8.4+5.4}\cdot100\%=60.8\%\)

\(\%m_{Al}=100-60.8=39.2\%\)

a, PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

\(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\)

Ta có: \(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,4\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,4.27}{14,8}.100\%\approx72,97\%\\\%m_{MgO}\approx27,03\%\end{matrix}\right.\)

b, Ta có: \(n_{MgO}=\dfrac{14,8-0,4.27}{40}=0,1\left(mol\right)\)

Theo PT: \(n_{H_2SO_4}=n_{H_2}+n_{MgO}=0,7\left(mol\right)\)

\(\Rightarrow m_{H_2SO_4}=0,7.98=68,6\left(g\right)\)

\(\Rightarrow m_{ddH_2SO_4}=\dfrac{68,6}{10\%}=686\left(g\right)\)

c, Theo PT: \(\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=0,2\left(mol\right)\\n_{MgSO_4}=n_{MgO}=0,1\left(mol\right)\end{matrix}\right.\)

Ta có: m _{dd sau pư} = 14,8 + 686 - 0,6.2 = 699,6 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{Al_2\left(SO_4\right)_3}=\dfrac{0,2.342}{699,6}.100\%\approx9,78\%\\C\%_{MgSO_4}=\dfrac{0,1.120}{699,6}.100\%\approx1,72\%\end{matrix}\right.\)

1. Gọi mol của Mg và Al là x, y mol

=> 24x + 27y = 12,6 (1)

nH2 = 0,6 mol => x + 1,5y = 0,6 (2)

Từ (1) (2) => x = 0,3 ; y = 0,2 

=> %Mg = 57,14%

=> %Al = 42,86%

1. Gọi mol của Mg và Al là x, y mol

=> 24x + 27y = 12,6 (1)

nH2 = 0,6 mol => x + 1,5y = 0,6 (2)

Từ (1) (2) => x = 0,3 ; y = 0,2 

=> %Mg = 57,14%

=> %Al = 42,86%

1. Gọi mol của Mg và Al là x, y mol

=> 24x + 27y = 12,6 (1)

nH2 = 0,6 mol => x + 1,5y = 0,6 (2)

Từ (1) (2) => x = 0,3 ; y = 0,2 

=> %Mg = 57,14%

=> %Al = 42,86%

Gọi mol của Mg và Al là x, y mol

=> 24x + 27y = 12,6 (1)

nH2 = 0,6 mol => x + 1,5y = 0,6 (2)

Từ (1) (2) => x = 0,3 ; y = 0,2 

=> %Mg = 57,14%

=> %Al = 42,86%