\(n_{H_2}=\dfrac{6.72}{22.4}=0.3\left(mol\right)\)

\(\Rightarrow n_{HCl}=2\cdot n_{H_2}=2\cdot0.3=0.6\left(mol\right)\)

BTKL : 

\(m_{Muối}=m_{hh}+m_{HCl}-m_{H_2}=18.6+0.6\cdot36.5-0.3\cdot2=39.9\left(g\right)\)

a) Gọi \(\left\{{}\begin{matrix}n_{Fe}=a\left(mol\right)\\n_{Zn}=b\left(mol\right)\end{matrix}\right.\) \(\Rightarrow56a+65b=12,1\)  (1)

Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

Bảo toàn electron: \(2n_{Fe}+2n_{Zn}=2n_{H_2}\) \(\Rightarrow2a+2b=0,4\)  (2)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,1\cdot56}{12,1}\cdot100\%\approx46,28\%\\\%m_{Zn}=53,72\%\end{matrix}\right.\)

b)

Bảo toàn nguyên tố: \(\left\{{}\begin{matrix}n_{FeSO_4}=n_{Fe}=n_{Zn}=n_{ZnSO_4}=0,1\left(mol\right)\\n_{H_2SO_4\left(p.ứ\right)}=n_{H_2}=0,2\left(mol\right)\Rightarrow\Sigma n_{H_2SO_4}=0,2\cdot110\%=0,22\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{FeSO_4}=0,1\cdot152=15,2\left(g\right)\\m_{ZnSO_4}=0,1\cdot161=16,1\left(g\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\\m_{H_2SO_4\left(dư\right)}=\left(0,22-0,2\right)\cdot98=1,96\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{KL}+m_{ddH_2SO_4}-m_{H_2}=211,7\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{FeSO_4}=\dfrac{15,2}{211,7}\cdot100\%\approx7,18\%\\C\%_{ZnSO_4}=\dfrac{16,1}{211,7}\cdot100\%\approx7,61\%\\C\%_{H_2SO_4}=\dfrac{1,96}{22,4}\cdot100\%\approx0,93\%\end{matrix}\right.\)

a. PTHH:

Cu + HCl ---x--->

Fe + 2HCl ---> FeCl₂ + H₂

Vậy chất rắn A là Cu.

b. Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

Theo PT: \(n_{Fe}=n_{H_2}=0,3\left(mol\right)\)

=> \(m_{Fe}=0,3.56=16,8\left(g\right)\)

=> \(\%_{m_{Fe}}=\dfrac{16,8}{30}.100\%=56\%\)

\(\%_{m_{Cu}}=100\%-56\%=44\%\%\)

c.

Theo PT: \(n_{FeCl_2}=n_{Fe}=0,3\left(mol\right)\)

=> \(m_{FeCl_2}=0,3.127=38,1\left(g\right)\)

d. 

Ta có: \(m_{dd_{FeCl_2}}=100+16,8=116,8\left(g\right)\)

=> \(C_{\%_{FeCl_2}}=\dfrac{38,1}{116,8}.100\%=32,62\%\)

ta có Cu ko phản ứng với HCl 

-> V khí là do Fe phản ứng hết tạo ra

Fe + 2HCl -> FeCl2 + H2 

0,3 .............................0,3 

n H2 = 6,72 : 22,4=0,3 mol 

m Fe = 0,3.56 =16,8 g

% Fe = 16,8 : 30 .100 = 56 %

% Cu = 100% - 56% = 44% 

a, \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

PTHH: Zn + 2HCl → ZnCl₂ + H₂

Mol:     0,2                              0,2

(do Cu ko tác dụng với HCl loãng)

b, \(m_{Zn}=0,2.65=13\left(g\right)\)

  \(m_{Cu}=19,4-13=6,4\left(g\right)\)