\(n_{SO_2}=\dfrac{V_{SO_2}}{22,4}=\dfrac{2,24}{22,4}=0,1mol\)

Gọi \(\left\{{}\begin{matrix}n_{Mg}=x\\n_{Cu}=y\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Mg}=24x\\m_{Cu}=64y\end{matrix}\right.\)

\(Mg+2H_2SO_4\rightarrow MgSO_4+SO_2+2H_2O\) 

 x           2x                               x                  ( mol )

\(Cu+2H_2SO_4\rightarrow CuSO_4+SO_2+2H_2O\)

 y            2x                              y                   ( mol )

Ta có:

\(\left\{{}\begin{matrix}24x+64y=4,4\\x+y=0,1\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,05\\y=0,05\end{matrix}\right.\)

\(\Rightarrow m_{Mg}=0,05.24=1,2g\)

\(\Rightarrow m_{Cu}=0,05.64=3,2\)

\(m_{H_2SO_4}=n_{H_2SO_4}.M_{H_2SO_4}=\left(2.0,05+2.0,05\right).98=0,2.98=19,6g\)

\(n_{SO_2}=\dfrac{2,24}{22,4}=0,1mol\)

Gọi \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{Cu}=y\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}24x+64y=4,4\\BTe:2x+2y=2n_{SO_2}=2\cdot0,1=0,2\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}x=0,05\\y=0,05\end{matrix}\right.\)

\(m_{Mg}=0,05\cdot24=1,2g\)

\(m_{Cu}=0,05\cdot64=3,2g\)

\(n_{H_2SO_4}=2n_{Mg}+2n_{Cu}=2\cdot0,05+2\cdot0,05=0,2mol\)

\(m_{H_2SO_4}=0,2\cdot98=19,6g\)

Đặt nMg=x(mol),nCu=y(mol)

Bảo toàn e : 2nMg+2nCu=2nSO2=0,2(mol)

Từ  giải được:

mMg=0,05.24=1,2(g)

mCu=0,05.64=3,2(g)

nH2SO4=2nSO2=0,2(mol)

mH2SO4=0,2.98=19,6(g)

Đặt nMg=x(mol);nCu=y(mol)

→24x+64y=4,4(1)

nSO2=\(\dfrac{2,24}{22,4}\)=0,1(mol)

Bảo toàn e: x+y=nSO2=0,1(2)

Từ (1)(2)→x=y=0,05(mol)

=>mMg=0,05.24=1,2(g)

mCu=0,05.64=3,2(g)

b)

Mg+2H2SO4→MgSO4+SO2+3H2O

Cu+2H2SO4→CuSO4+SO2+2H2O

Tho PT: ∑nH2SO4=2∑nSO2=0,2(mol)

→m_axit=0,2.98=19,6(g)

Bài 1  :

\(NaCl + H_2SO_{4_{đặc}} \xrightarrow{t^o} NaHSO_4 + HCl\\ MnO_2 + 4HCl \to MnCl_2 + Cl_2 + 2H_2O\\ Cl_2 + SO_2 + 2H_2O \to 2HCl + H_2SO_4\\ Cu + 2H_2SO_4 \to CuSO_4 + SO_2 + 2H_2O\)

Bài 2 : 

n Cu = a(mol) ; n Fe = b(mol) => 64a + 56b = 12(1)

n SO2 = 5,6/22,4 = 0,25(mol)

Bảo toàn electron : 

2n Cu + 3n Fe = 2n SO2

<=> 2a + 3b = 0,5(2)

Từ (1)(2) suy ra a = b = 0,1

Vậy :

%m Cu = 0,1.64/12  .100% = 53,33%
%m Fe = 100% -53,33% = 46,67%

a)

Gọi $n_{Mg} = a(mol) ; n_{Zn} = b(mol)$

Suy ra: $24a + 65b = 24,3(1)$
$n_{SO_2} = 0,5(mol)$

Bảo toàn electron : $2n_{Mg} + 2n_{Zn} = 2n_{SO_2}$
$\Rightarrow a + b = 0,5(2)$

Từ (1)(2) suy ra a = 0,2 ; b = 0,3

$m_{Mg} = 0,2.24 = 4,8(gam)$
$m_{Zn} = 0,3.65 = 19,5(gam)$
b)

Ta có :

$n_{H_2SO_4} = 2n_{SO_2} = 1(mol)$
$m_{H_2SO_4\ pư} = 1.98 = 98(gam)$

n SO2 = 0,25 mol

a) 

$Cu + 2H_2SO_4 \to CuSO_4 + SO_2 + H_2O$
$2Fe  + 6H_2SO_4 \to Fe_2(SO_4)_3 + 3SO_2 + 6H_2O$

b) n Cu =a (mol) ; n Fe = b(mol)

=> 64a + 56b = 12(1)

n SO2 = a + 1,5b = 5,6/22,4 = 0,25(2)

(1)(2) suy ra a = b = 0,1

%m Cu = 0,1.64/12  .100% = 53,33%
%m Fe = 100% -53,33% = 46,67%

c)

n CuSO4 = a = 0,1(mol)

n Fe2(SO4)3 = 0,5a = 0,05(mol)

m muối = 0,1.160  + 0,05.400 = 36(gam)

d) n H2SO4 = 2n SO2 = 0,5(mol)

V H2SO4 = 0,5/2 = 0,25(lít)

Gọi số mol Cu, Fe là a, b (mol)

=> 64a + 56b = 17,6 (1)

\(n_{SO_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)

PTHH: 2Fe + 6H₂SO₄ --> Fe₂(SO₄)₃ + 3SO₂ + 6H₂O

             b-------------------------------->1,5b

            Cu + 2H₂SO₄ --> CuSO₄ + SO₂ + 2H₂O

              a--------------------------->a

=> a + 1,5b = 0,4 (2)

(1)(2) => a = 0,1 (mol); b = 0,2 (mol)

=> \(\left\{{}\begin{matrix}\%m_{Cu}=\dfrac{0,1.64}{17,6}.100\%=36,36\%\\\%m_{Fe}=\dfrac{0,2.56}{17,6}.100\%=63,64\%\end{matrix}\right.\)

PTHH: \(2Fe+6H_2SO_{4\left(đ\right)}\underrightarrow{t^o}Fe_2\left(SO_4\right)_3+3SO_2\uparrow+6H_2O\)

            \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

a) Ta có: \(n_{SO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\) \(\Rightarrow n_{Fe}=\dfrac{1}{15}\left(mol\right)\)

\(\Rightarrow\%m_{Fe}=\dfrac{\dfrac{1}{15}\cdot56}{13,6}\cdot100\%\approx27,45\%\) \(\Rightarrow\%m_{CuO}=72,55\%\)

b) Ta có: \(m_{CuO}=13,6-\dfrac{1}{15}\cdot56\approx9,9\left(g\right)\) \(\Rightarrow n_{CuO}=n_{H_2SO_4}=\dfrac{9,9}{80}=0,12375\left(mol\right)\)

*Làm gì có H₂SO₄ loãng đâu nhỉ ??