$FeO + CO \xrightarrow{t^o} Fe + CO_2$

Theo PTHH :  $n_{FeO} = n_{CO\ pư} = n_{Fe} = n_{CO_2} = a(mol)$

$\Rightarrow m_{giảm} = m_{FeO} - m_{Fe} = 72a -56a = 16a = 1,6(gam)$
$\Rightarrow a = 0,1(mol)$

$m_{Fe} = 0,1.56 = 5,6(gam)$
$n_{CO\ dư} = 0,2 - 0,1 = 0,1(mol)$
$\%V_{CO\ dư} = \%V_{CO_2} = \dfrac{0,1}{0,1 + 0,1}.100\% = 50\%$

\(n_{CO_2}=\dfrac{5,6}{22,4}=0,25mol\)

\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)

0,25      0,5             0,25                  ( mol )

\(m_{CH_4}=0,25.16=4g\)

\(V_{O_2}=0,5.22,4=11,2l\)

TK

a, Theo gt ta có: $n_{H_2}=0,15(mol);n_{O_2}=0,05(mol)$

$2H_2+O_2\rightarrow 2H_2O$

Sau phản ứng $H_2$ còn dư. Và dư 0,05.22,4=1,12(l)

b, Ta có: $n_{H_2O}=2.n_{O_2}=0,1(mol)\Rightarrow m_{H_2O}=1,8(g)$

nH2 = 3.36/22.4 = 0.15 (mol) 

nO2 = 1.12/22.4 = 0.05 (mol) 

2H2 + O2 -to-> 2H2O 

0.1___0.05_____0.1 

VH2 (dư) = ( 0.15 - 0.1) * 22.4 = 1.12 (l) 

mH2O = 0.1*18 = 1.8 (g) 

\(n_{KMnO_4}=\dfrac{31,6}{158}=0,2mol\)

\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)

0,2                 0,1              0,1        0,1

a)\(V_{O_2}=0,1\cdot22,4=2,24l\)

b)\(m_{CRắn}=m_{K_2MnO_4}+m_{MnO_2}=0,1\cdot197+0,1\cdot87=28,4g\)

c)\(n_{CH_4}=\dfrac{11,2}{22,4}=0,5mol\)

\(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)

0,5        0,1    0              0

0,05      0,1    0,05         0,1

0,45       0      0,05         0,1

\(V_{CO_2}=0,05\cdot22,4=1,12l\)

\(m_{H_2O}=0,1\cdot18=1,8g\)

PTHH: 2KMnO4--t^o-> K2MnO4+MnO2+O2

              0,2----------------0,1---------0,1-----0,1

b, n_KMnO4= \(\dfrac{31,6}{158}\)=0,2 mol

Theo pt: n_O2=\(\dfrac{1}{2}\).0,2=0,1 mol

=> V_O2= 0,1.22,4= 2,24 l

=>m cr=0,1.197+0,1.87=28,4g

CH4+2O2-to>CO2+2H2O

            0,5-----0,25-----0,5

n CH4=\(\dfrac{11,2}{22,4}\)=0,5 mol

=>Oxi du

=>V CO2=0,25.22,4=5,6l

=>m H2O=0,5.18=9g

\(n_{Cu} = a ; n_{Al} = b ; n_{Fe} = c(mol)\\ \Rightarrow 64a + 27b + 56c = 28,6(1)\\ 2Al + 6HCl \to 2AlCl_3 + 3H_2\\ Fe + 2HCl \to FeCl_2 + H_2\\ n_{H_2} = 1,5b + c = \dfrac{13,44}{22,4} = 0,6(2)\\ \text{Mặt khác} : n_{O_2} = \dfrac{8,96}{22,4} = 0,4(mol)\\ 2Cu + O_2 \xrightarrow{t^o} 2CuO\\ 4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3\\ 4Fe + 3O_2 \xrightarrow{t^o} 2Fe_2O_3\\ \)

Ta có :

\(\dfrac{n_X}{n_{O_2}}=\dfrac{a+b+c}{0,5a +0,75b + 0,75c} = \dfrac{0,6}{0,4}(3)\\ (1)(2)(3)\Rightarrow a = \dfrac{317}{1460} ; b = \dfrac{121}{365}; c = \dfrac{15}{146}\\ \%m_{Cu} = \dfrac{\dfrac{317}{1460}.64}{28,6}.100\% = 48,59\%\\ \%m_{Al} = \dfrac{\dfrac{121}{365}.27}{28,6}.100\% = 31,3\%\\ \%m_{Fe} = 100\% - 41,59\% - 31,3\% = 27,11\%\)

help

me

\(n_{\text{khí}}=\frac{11,2}{22,4}=0,5mol\)

Đặt \(\hept{\begin{cases}x\left(mol\right)=n_C\\y\left(mol\right)=n_S\end{cases}}\)

\(\rightarrow12x+32y=10\left(1\right)\)

PTHH: \(C+O_2\rightarrow^{t^o}CO_2\)

\(S+O_2\rightarrow^{t^o}SO_2\)

Từ phương trình \(\hept{\begin{cases}n_{CO_2}=n_C=x\left(mol\right)\\n_{SO_2}=n_S=y\left(mol\right)\end{cases}}\)

\(\rightarrow x+y=0,5\left(2\right)\)

Từ (1) và (2) \(\rightarrow\hept{\begin{cases}x=0,3\\y=0,2\end{cases}}\)

\(\rightarrow m_C=12.0,3=3,6g\)

\(\rightarrow m_S=32.0,2=6,4g\)

Câu 2: 

\(n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

PTHH: \(2KMnO_4\xrightarrow[]{t^o}K_2MnO_4+MnO_2+O_2\)

               0,6<------------------------------------0,3

\(\Rightarrow m_{KMnO_4}=0,6.158=94,8\left(g\right)\)

Câu 3: 

\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

             0,2<-----------------------0,2

=> m_Zn = 0,2.65 = 13 (g)

Câu 4:

\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)

PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\)

           0,4------------------------->0,4

             \(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)

              0,4<---0,4

\(\Rightarrow m_{CuO}=0,4.80=32\left(g\right)\)

\(a) Zn + 2HCl \to ZnCl_2 + H_2\\ n_{H_2} = n_{Zn} = \dfrac{13}{65} = 0,2(mol)\\ V_{H_2} = 0,2.22,4 = 4,48(lít)\\ b)n_{O_2} =\dfrac{4,8}{32}=0,15(mol)\\ 2H_2 + O_2 \xrightarrow{t^o} 2H_2O\\ \dfrac{n_{H_2}}{2} = 0,1 < \dfrac{n_{O_2}}{1} = 0,15 \to O_2\ dư\\ n_{H_2O} = n_{H_2} = 0,2(mol)\\ \Rightarrow m_{H_2O} = 0,2.18= 3,6(gam)\)

a. \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)

\(n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

PTHH : 2Mg + O₂ -> 2MgO

               0,2      0,1       0,2

Xét tỉ lệ : \(\dfrac{0,2}{2}< \dfrac{0,3}{1}\) => Mg đủ , O₂ dư

\(m_{O_2\left(dư\right)}=\left(0,3-0,1\right).32=6,4\left(g\right)\)

b) \(m_{MgO}=0,2.40=8\left(g\right)\)

\(a.n_{Mg}=0,2\left(mol\right);n_{O_2}=0,3\left(mol\right)\\ 2Mg+O_2\rightarrow2MgO\\ LTL:\dfrac{0,2}{2}< \dfrac{0,3}{1}\Rightarrow O_2dư\\ n_{O_2\left(dư\right)}=0,3-0,1=0,2\left(mol\right)\\ m_{O_2}=0,2.32=6,4\left(g\right)\\ b.n_{MgO}=n_{Mg}=0,2\left(mol\right)\\ \rightarrow m_{MgO}=0,2.40=8\left(g\right)\)