Sửa: \(32g\) oxit sắt

\(n_{H_2}=\dfrac{13,44}{22,4}=0,6(mol)\\ PTHH:Fe_xO_y+yH_2\to xFe+yH_2O\\ \Rightarrow y.n_{Fe_xO_y}=n_{H_2}=0,6(mol)\\ \Rightarrow \dfrac{32y}{56x+16y}=0,6\\ \Rightarrow 32y=33,6x+9,6y\\ \Rightarrow 33,6x=22,4y\\ \Rightarrow \dfrac{x}{y}=\dfrac{22,4}{33,6}=\dfrac{2}{3}\\ \Rightarrow x=2;y=3\)

Vậy CTHH là \(Fe_2O_3\)

\(n_{H_2\left(đktc\right)}=\dfrac{V}{22,4}=\dfrac{17,92}{22,4}=0,8\left(mol\right)\)

\(yH_2+Fe_xO_y\rightarrow^{t^0}yH_2O+xFe\)

  y   :       1        (mol)

 0,8   :     \(\dfrac{0,8}{y}\)    (mol)

\(\Rightarrow M_{Fe_xO_y}=\dfrac{m}{n}=\dfrac{46,4}{\dfrac{0,8}{y}}=58y\) (g/mol)

\(\Rightarrow56x+16y=58y\)

\(\Rightarrow56x=42y\)

\(\Rightarrow\dfrac{x}{y}=\dfrac{42}{56}=\dfrac{3}{4}\Rightarrow x=3;y=4\)

-CTHH của oxit sắt là Fe₃O₄

PTHH: Fe_xO_y + yCO =(nhiệt)=> xFe + yCO₂

Ta có: n_FexOy = \(\frac{2,32}{56x+16y}\left(mol\right)\)

n_CO2 = \(\frac{0,896}{22,4}=0,04\left(mol\right)\)

\(\Rightarrow n_{FexOy}=\frac{0,04}{y}\left(mol\right)\)

\(\Rightarrow\frac{2,32}{56x+16y}=\frac{0,04}{y}\)

Giải ra, ta được \(\frac{x}{y}=\frac{3}{4}\)

=> CTHH : Fe₃O₄

\(n_{H_2}=\dfrac{0,672}{22,4}=0,03\left(mol\right)\) \(\Rightarrow y=0,03\left(mol\right)\)

\(Fe_xO_y+yH_2\rightarrow\left(t^o\right)xFe+yH_2O\)

\(n_{H_2}=\dfrac{0,448}{22,4}=0,02mol\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

0,02                                  0,02   ( mol )

\(\Rightarrow x=0,02\left(mol\right)\)

\(\Rightarrow\dfrac{x}{y}=\dfrac{0,02}{0,03}=\dfrac{2}{3}\)

\(\Rightarrow CTHH:Fe_2O_3\)

\(n_{H_2\left(thu\right)}=\dfrac{V}{22,4}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

1                                 :    1    (mol)

0,02                            :  0,02 (mol)

\(n_{H_2\left(dùng\right)}=\dfrac{V}{22,4}=\dfrac{0,672}{22,4}=0,03\left(mol\right)\)

\(yH_2+Fe_xO_y\rightarrow^{t^0}xFe+yH_2O\)

y                      :       x  (mol)

0,03                 :      0,02 (mol)

\(\Rightarrow\dfrac{0,03}{y}=\dfrac{0,02}{x}\)

\(\Rightarrow\dfrac{x}{y}=\dfrac{0,02}{0,03}=\dfrac{2}{3}\Rightarrow x=2;y=3\)

-Vậy CTHH của oxit sắt là Fe₂O₃.

a) nH2= 0,4(mol) ; nFe=0,3(mol)

PTHH: FexOy + y H2 -to-> x Fe + y H2O

Ta có: x:y= nFe:nH2= 0,3:0,4=3:4

=> CTHH oxit sắt : Fe3O4

PTHH: Fe3O4 + 4 H2 -to-> 3 Fe + 4 H2O

Ta có: \(n_{H_2}=\dfrac{7,392}{22,4}=0,33\left(mol\right)\)

Gọi: n_{H2 (pư)} = a (mol) ⇒ n_{H2 (dư)} = 10%a (mol)

⇒ a + 10%a = 0,33 

⇒ a = 0,3 (mol)

Có: \(H_2+O_{\left(trongoxit\right)}\rightarrow H_2O\)

⇒ n_{O (trong oxit)} = 0,3 (mol)

\(\Rightarrow n_{Fe}=\dfrac{16-m_{O\left(trongoxit\right)}}{56}=0,2\left(mol\right)\)

\(\Rightarrow\dfrac{x}{y}=\dfrac{0,2}{0,3}=\dfrac{2}{3}\)

Vậy: CTHH cần tìm là Fe₂O₃.

\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ n_O=\dfrac{11,6-0,15}{16}=0,2\left(mol\right)\)

CTHH: Fe_xO_y

\(\rightarrow x:y=n_{Fe}:n_O=0,15:0,2=3:4\)

CTHH: Fe₃O₄

PTHH: Fe₃O₄ + 4H₂ --to--> 3Fe + 4H₂O

                           0,2              0,15

=> V_H2 = 0,2.22,4 = 4,48 (l)

\(n_{Fe}=\dfrac{8,4}{56}=0,15mol\)

\(n_{Fe_xO_y}=\dfrac{11,6}{56x+16y}\) mol

\(Fe_xO_y+yH_2\rightarrow\left(t^p\right)xFe+yH_2O\)

\(\dfrac{11,6}{56x+16y}\)               \(\dfrac{11,6x}{56x+16y}\)         ( mol )

\(\Rightarrow\dfrac{11,6x}{56x+16y}=0,15\)

\(\Leftrightarrow11,6x=8,4x+2,4y\)

\(\Leftrightarrow3,2x=2,4y\)

\(\Leftrightarrow4x=3y\)

\(\Leftrightarrow x=3;y=4\)

\(\Rightarrow CTHH:Fe_3O_4\)

\(\Rightarrow n_{H_2}=0,15.4:3=0,2mol\)

\(V_{H_2}=0,2.22,4=4,48l\)

Gọi số mol CuO, Fe_xO_y là a (mol)

=> 80a + a(56x + 16y) = 2,4 (1)

PTHH: CuO + H₂ --t^o--> Cu + H₂O

               a-------------->a

             Fe_xO_y + yH₂ --t^o--> xFe + yH₂O

                a------------------>ax

=> 64a + 56ax = 1,76 

PTHH: Fe + 2HCl --> FeCl₂ + H₂

           ax---------------------->ax

=> \(ax=\dfrac{0,448}{22,4}=0,02\left(mol\right)\)

=> a = 0,01

=> x = 2

(1) => y = 3

=> CTHH: Fe₂O₃