a,PT: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)

Ta có: \(n_{CH_4}=\dfrac{3,2}{16}=0,2\left(mol\right)\)

Theo PT: \(n_{O_2}=2n_{CH_4}=0,4\left(mol\right)\)

\(\Rightarrow V_{O_2}0,4.22,4=8,96\left(l\right)\)

b, Theo PT: \(n_{CO_2}=n_{CH_4}=0,2\left(mol\right)\)

PT: \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)

Theo PT: \(n_{CaCO_3}=n_{CO_2}=0,2\left(mol\right)\)

\(\Rightarrow m_{\downarrow}=m_{CaCO_3}=0,2.100=20\left(g\right)\)

Bạn tham khảo nhé!

a) 

n_Br2 = 0,2.0,2 = 0,04 (mol)

n_CaCO3 = \(\dfrac{10}{100}=0,1\left(mol\right)\)

PTHH: C₂H₄ + Br₂ --> C₂H₄Br₂

            0,04<--0,04---->0,04

            C₂H₄ + 3O₂ --t^o--> 2CO₂ + 2H₂O

             0,04--------------->0,08

            CH₄ + 2O₂ --t^o--> CO₂ + 2H₂O

           0,02<-------------0,02

             Ca(OH)₂ + CO₂ --> CaCO₃ + H₂O

                                 0,1<------0,1

=> \(\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,02}{0,02+0,04}.100\%=33,33\%\\\%V_{C_2H_4}=\dfrac{0,04}{0,02+0,04}.100\%=66,67\%\end{matrix}\right.\)

b) m_C2H4Br2 = 0,04.188 = 7,52 (g)

a)

$CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O$
$C_2H_4 + 3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O$

$CO_2 + Ba(OH)_2 \to BaCO_3 + H_2O$

b)

Gọi $n_{CH_4} = a(mol) ; n_{C_2H_4} = b(mol)$
$\Rightarorw a + b = \dfrac{1,68}{22,4} = 0,075(1)$

Theo PTHH : $n_{BaCO_3} = n_{CO_2} = a + 2b = \dfrac{19,7}{197} = 0,1(2)$
Từ (1)(2) suy ra : a = 0,05 ; b = 0,025

$\%V_{CH_4} = \dfrac{0,05}{0,075}.100\% = 66,67\%$

$\%V_{C_2H_4} = 100\% - 66,67\% = 33,33\%$

c) $n_{O_2} = 2n_{CH_4} + 3n_{C_2H_4} = 0,175(mol)$
$\Rightarrow V_{O_2} = 0,175.22,4 = 3,92(lít)$
$\Rightarrow V_{kk} = 5V_{O_2} = 19,6(lít)$

1.Khí thoát ra là CH4 nCH4=0,1 mol mà tổng n khí=0,15 mol

=>nC2H2=0,05 mol

C2H2+2Br2 =>C2H2Br4

%VCH4=0,1/0,15.100%=66,67%

%VC2H2=33,33%

CH4+2O2=>CO2+2H2O

C2H2+5/2O2=>2CO2+H2O

Tổng mol O2=0,1.2+0,05.2,5=0,325 mol

=>VO2=0,325.22,4=7,28l

=>Vkk=7,28/20%=36,4lít

2.

C2H2        +2Br2=>C2H2Br4

0,025 mol<=0,05 mol

CH4+2O2=>CO2+2H2O
nCaCO3=nCO2=0,15 mol=>nCH4=0,15 mol

nBr2=8/160=0,05 mol=>nC2H2=0,025 mol

%VCH4=0,15/0,175.100%=85,71%

%VC2H2=14,29%
3.

nCO2=11,2/22,4=0,5 mol

C6H12O6=>2C2H5OH +2CO2

0,25 mol<=0,5 mol<=0,5 mol

mC2H5OH=0,5.46=23g

nC6H12O6=(0,5/2)/80%=0,3125 mol

=>m glucozo bđ=0,3125.180=56,25g

\(Đặt:n_{CH_4}=a\left(mol\right),n_{C_2H_2}=b\left(mol\right)\)

\(n_{hh}=a+b=0.35\left(mol\right)\left(1\right)\)

\(BTC:\)

\(a+2b=0.6\)

\(a=1\)

\(b=0.25\)

\(\%CH_4=\dfrac{0.1}{0.35}\cdot100\%=28.57\%\)

\(\%C_2H_2=71.43\%\)

\(\left\{{}\begin{matrix}n_{CH_4}=x\left(mol\right)\\n_{C_2H_2}=y\left(mol\right)\end{matrix}\right.\)⇒ x + y = \(\dfrac{7,84}{22,4} = 0,35(mol)\)

\(CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_2 + \dfrac{5}{2}O_2 \xrightarrow{t^o} 2CO_2 + H_2O\\ CO_2 + Ca(OH)_2 \to CaCO_3 + H_2O\)

Theo PTHH : x + 2y = \(\dfrac{60}{100} = 0,6(2)\)

Từ (1)(2) suy ra x = 0,1 ; y = 0,25

Vậy : 

\(\%V_{CH_4} = \dfrac{0,1}{0,35}.100\% = 28,57\%\\ \%V_{C_2H_2} = 100\% - 28,57\% = 71,43\%\)