PTHH: \(CaCl_2+Na_2CO_3\rightarrow CaCO_3\downarrow+2NaCl\)

a+b) Ta có: \(n_{CaCl_2}=0,1\cdot2=0,2\left(mol\right)\) 

\(\Rightarrow\left\{{}\begin{matrix}n_{CaCO_3}=0,2\left(mol\right)\\n_{NaCl}=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CaCO_3}=0,2\cdot100=20\left(g\right)\\C_{M_{NaCl}}=\dfrac{0,4}{0,1+0,2}\approx1,33\left(M\right)\end{matrix}\right.\)

c) PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\)

Theo PTHH: \(n_{HCl}=2n_{CaCO_3}=0,4\left(mol\right)\) \(\Rightarrow m_{ddHCl}=\dfrac{0,4\cdot36,5}{10\%}=146\left(g\right)\)

a.PTHH:CaCl2+Na2CO3--->CaCO3+2NaCl

Ta có:nCaCl2=0,2

=>nCaCO3=nCaCl2=0,2(mol)=>mCaCO3(kết tủa)=100.0,2=2(g)

b.Vdd=100+200=300(ml)=0,3(l)

CM Nacl=(2.0,2)/0,3=4/3(M)(Đề cho 2 chất td vừa đủ nên dd sau pứ chỉ có NaCl)

c.CaCO3+2HCl--->CaCl2+CO2+H2O

nHCl(cần dùng)=2.0.2=0,4(mol)=>mHCl=36,5.0,4=14,6(g)

=>mddHCl=14,6/10%=146(g)

\(n_{NaOH}=0.2\cdot0.5=0.1\left(mol\right)\)

\(n_{CuSO_4}=0.1\cdot2=0.2\left(mol\right)\)

\(2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\)

\(0.1.............0.05...............0.05...........0.05\)

\(m_{Cu\left(OH\right)_2}=0.05\cdot98=4.9\left(g\right)\)

\(C_{M_{Na_2SO_4}}=\dfrac{0.05}{0.2+0.1}=0.167\left(M\right)\)

\(C_{M_{CuSO_4\left(dư\right)}}=\dfrac{0.2-0.05}{0.1}=1.5\left(M\right)\)

PTHH: \(Na_2SO_4+CaCl_2\rightarrow2NaCl+CaSO_4\downarrow\)

Ta có: \(\left\{{}\begin{matrix}n_{Na_2SO_4}=0,1\cdot0,5=0,05\left(mol\right)\\n_{CaCl_2}=0,1\cdot0,4=0,04\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Na₂SO₄ dư

\(\Rightarrow\left\{{}\begin{matrix}n_{CaSO_4}=0,04\left(mol\right)\\n_{NaCl}=0,08\left(mol\right)\\n_{Na_2SO_4\left(dư\right)}=0,01\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CaSO_4}=0,04\cdot136=5,44\left(g\right)\\C_{M_{NaCl}}=\dfrac{0,08}{0,1+0,1}=0,4\left(M\right)\\C_{M_{Na_2SO_4\left(dư\right)}}=\dfrac{0,01}{0,2}=0,05\left(M\right)\end{matrix}\right.\)

200ml = 0,2l

\(n_{CuSO4}=1.0,2=0,2\left(mol\right)\)

a) Pt : \(CuSO_4+2KOH\rightarrow Cu\left(OH\right)_2+K_2SO_4|\)

               1               2                1                  1

              0,2          0,4               0,2                0,2

b) \(n_{KOH}=\dfrac{0,2.2}{1}=0,4\left(mol\right)\) 

200ml = 0,2l

\(C_{M_{ddKOH}}=\dfrac{0,4}{0,2}=2\left(M\right)\)

c) \(n_{Cu\left(OH\right)2}=\dfrac{0,4.1}{2}=0,2\left(mol\right)\)

⇒ \(m_{Cu\left(OH\right)2}=0,2.98=19,6\left(g\right)\)

d) \(n_{K2SO4}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)

\(V_{ddspu}=0,2+0,2=0,4\left(l\right)\)

\(C_{M_{K2SO4}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\)

 Chúc bạn học tốt

PTHH: \(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_2\downarrow\)

            \(Cu\left(OH\right)_2\xrightarrow[]{t^o}CuO+H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{CuCl_2}=0,2\cdot2=0,4\left(mol\right)\\n_{NaOH}=0,2\cdot2=0,4\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,4}{1}>\dfrac{0,4}{2}\) \(\Rightarrow\) CuCl₂ còn dư

\(\Rightarrow\left\{{}\begin{matrix}n_{NaCl}=0,4\left(mol\right)\\n_{Cu\left(OH\right)_2}=0,2\left(mol\right)=n_{CuO}=n_{CuCl_2\left(dư\right)}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CuO}=0,2\cdot80=16\left(g\right)\\C_{M_{NaCl}}=\dfrac{0,4}{0,2+0,2}=1\left(M\right)\\C_{M_{CuCl_2}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\\\end{matrix}\right.\)