\(m_{HCl}=\dfrac{300.7,3\%}{100\%}=21,9g\\ n_{HCl}=\dfrac{21,9}{36,5}=0,6mol\\ HCl+NaOH\rightarrow NaCl+H_2O\left(1\right)\\ n_{NaOH\left(1\right)}=n_{HCl}=0,6mol\\ m_{H_2SO_4}=\dfrac{200.9,8\%}{100\%}=19,6g\\ n_{H_2SO_4}=\dfrac{19,6}{98}=0,2mol\\ H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\left(2\right)\\ n_{NaOH\left(2\right)}=0,2.2=0,4mol\\ n_{NaOH}=0,4+0,6=1mol\\ m_{NaOH}=1.40=40g\\ m_{ddNaOH}=\dfrac{40}{5\%}\cdot100\%=800g\)

Bài 1: 

PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)

Ta có: \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,4\left(mol\right)\\n_{H_2}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddHCl}=\dfrac{0,4\cdot36,5}{14,6\%}=100\left(g\right)\\V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\end{matrix}\right.\)

Bài 2:

PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{KOH}=\dfrac{100\cdot11,2\%}{56}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{150\cdot9,8\%}{98}=0,15\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,15}{1}\) \(\Rightarrow\) H₂SO₄ còn dư, KOH p/ứ hết

\(\Rightarrow\left\{{}\begin{matrix}n_{K_2SO_4}=0,1\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{K_2SO_4}=0,1\cdot174=17,4\left(g\right)\\m_{H_2SO_4\left(dư\right)}=0,05\cdot98=4,9\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{ddKOH}+m_{ddH_2SO_4}=250\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{K_2SO_4}=\dfrac{17,4}{250}\cdot100\%=6,96\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{4,9}{250}\cdot100\%=1,96\%\end{matrix}\right.\)

\(n_{Al}=\dfrac{2,7}{27}=0,1mol\)

\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

0,1       0,15             0 ,05            0,15

a)\(V=0,15\cdot22,4=3,36\left(l\right)\)

b)\(m_{H_2SO_4}=0,15\cdot98=14,7\left(g\right)\)

   \(\Rightarrow m_{ddHCl}=\dfrac{14,7}{9,8}\cdot100=150\left(g\right)\)

c) \(m_{H_2}=0,15\cdot2=0,3\left(g\right)\)

    \(m_{ddsau}=2,7+150-0,3=152,4\left(g\right)\)

    \(m_{Al_2\left(SO_4\right)_3}=0,05\cdot342=17,1\left(g\right)\)

   \(\Rightarrow C\%=\dfrac{17,1}{152,4}\cdot100=11,22\%\)

a) \(n_{NaOH}=0,2.1=0,2\left(mol\right);n_{H_2SO_4}=0,15.2=0,3\left(mol\right)\)

PTHH: 2NaOH + H₂SO₄ → Na₂SO₄ + 2H₂O

Mol:         0,2                            0,1

Ta có: \(\dfrac{0,2}{2}< \dfrac{0,3}{1}\) ⇒ NaOH hết, H₂SO₄ dư

\(m_{Na_2SO_4}=0,1.142=14,2\left(g\right)\)

b) V_{dd sau pứ} = 0,2 + 0,15 = 0,35 (l)

\(C_{M_{ddNa_2SO_4}}=\dfrac{0,1}{0,35}=\dfrac{2}{7}\approx0,2857M\)

\(C_{M_{ddH_2SO_4dư}}=\dfrac{0,3-0,1}{0,35}=\dfrac{4}{7}\approx0,57M\)

Đáp án A

Thí nghiệm 2: 0,2 mol X + 0,6 mol KHCO₃ → 0,4 mol CO₂ + dung dịch M

a, PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)

Ta có: \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)

\(n_{HCl}=0,5.1=0,5\left(mol\right)\)

Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,5}{2}\), ta được HCl dư.

Theo PT: \(\left\{{}\begin{matrix}n_{FeCl_2}=n_{H_2}=n_{Fe}=0,2\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Fe}=0,4\left(mol\right)\Rightarrow n_{HCl\left(dư\right)}=0,1\left(mol\right)\end{matrix}\right.\)

b, Dung dịch a gồm HCl dư và FeCl₂.

PT: \(HCl+NaOH\rightarrow NaCl+H_2O\)

\(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_{2\downarrow}+2NaCl\)

Theo PT: \(n_{NaOH}=n_{HCl\left(dư\right)}+2n_{FeCl_2}=0,5\left(mol\right)\)

\(\Rightarrow a=C_{M_{NaOH}}=\dfrac{0,5}{0,2}=2,5M\)

c, \(V_{H_2}=0,2.22,4=4,48\left(l\right)\)

Bạn tham khảo nhé!