GIẢI :

a) \(PTHH:Na_2CO_3+2HCl\rightarrow2NaCl+CO_2+H_2O\)

b) \(n_{Na_2CO_3}=\dfrac{m}{M}=\dfrac{5,3}{106}=0,05\left(mol\right)\)

Số mol : 1mol ------------------------------------1mol

Suy ra : 0,05mol-----------------------------------0,05mol

\(V_{CO_{2\left(đktc\right)}}=n.22,4=0,05.22,4=1,12\left(l\right)\)

c) \(n_{HCl}=\dfrac{0,05.2}{1}=0,1\left(mol\right)\)

\(m_{ct}=n.M=0,1.36,5=3,65\left(g\right)\)

\(m_{dd}=m_{HCl}=100g\)

Nồng độ % của dd HCl đã dùng là :

\(C_{\%HCl}=\dfrac{m_{ct}}{m_{dd}}.100=\dfrac{3,65}{100}.100=3.65\%\)

d) Nồng độ % của dd sau phản ứng là :

\(C_{\%NaCl}=\dfrac{m_{ct}}{m_{dd}}.100=\dfrac{n_{NaCl}.M_{NaCl}}{m_{HCl}+m_{Na_2CO_3}}.100=\dfrac{0,1.58,5}{100+5,3}.100=\dfrac{5,85}{105,3}.100\approx5,56\%\)

\(a,n_{Fe}=\dfrac{5,6}{56}=0,1mol\\ Fe+2HCl\rightarrow FeCl_2+H_2\)

0,1      0,2             0,1          0,1

\(V_{H_2}=0,1.22,4=2,24l\\ b)C_{\%HCl}=\dfrac{0,2.36,5}{200}\cdot100=3,65g\)     

a) \(n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

PTHH: 2HCl + CaCO₃ → CaCl₂ + CO₂ + H₂O

Mol:      0,4                         0,2        0,2

b) \(C\%_{ddHCl}=\dfrac{0,4.36,5.100\%}{100}=14,6\%\)

c) \(m_{CaCl_2}=0,2.101=20,2\left(g\right)\)

a) \(n_{Na_2CO_3}=\dfrac{21,2}{106}=0,2\left(mol\right)\)

PTHH: Na₂CO₃ + 2HCl --> 2NaCl + CO₂ + H₂O

                0,2------------------>0,4---->0,2

m_{dd sau pư} = 200 + 21,2 - 0,2.44 = 212,4(g)

=> \(C\%\left(NaCl\right)=\dfrac{0,4.58,5}{212,4}.100\%=11,017\%\)

$PTHH:Na_2CO_3+2HCl\to 2NaCl+H_2O+CO_2\uparrow$

$n_{Na_2CO_3}=\dfrac{21,2}{106}=0,2(mol)$

Theo PT: $n_{NaCl}=n_{CO_2}=0,2(mol)$

$\Rightarrow m_{NaCl}=0,4.58,5=23,4(g);m_{CO_2}=0,2.44=8,8(g)$

$\Rightarrow C\%_{NaCl}=\dfrac{23,4}{21,2+200-8,8}.100\%\approx 11,01\%$

Câu 1:

a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

b, \(n_{Zn}=\dfrac{16,25}{65}=0,25\left(mol\right)\)

\(n_{H_2}=n_{Zn}=0,25\left(mol\right)\)

\(\Rightarrow V_{H_2}=0,25.24,79=6,1975\left(l\right)\)

c, \(n_{HCl}=2n_{Zn}=0,5\left(mol\right)\)

\(\Rightarrow m_{HCl}=0,5.36,5=18,25\left(g\right)\)

\(\Rightarrow m_{ddHCl}=\dfrac{18,25}{10\%}=182,5\left(g\right)\)

d, \(n_{ZnCl_2}=n_{Zn}=0,25\left(mol\right)\)

\(\Rightarrow C\%_{ZnCl_2}=\dfrac{0,25.136}{16,25+182,5-0,25.2}.100\%\approx17,15\%\)

Câu 2:

a, \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)

c, \(n_{NaOH}=\dfrac{40}{40}=1\left(mol\right)\)

Theo PT: \(n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,5\left(mol\right)\)

\(\Rightarrow V_{H_2SO_4}=\dfrac{0,5}{2}=0,25\left(l\right)\)

d, \(n_{Na_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,5\left(mol\right)\)

\(\Rightarrow C_{M_{Na_2SO_4}}=\dfrac{0,5}{0,25}=2\left(M\right)\)

Ta có: \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)

a. PTHH: Zn + H₂SO₄ ---> ZnSO₄ + H₂

b. Theo PT: \(n_{H_2}=n_{Zn}=0,1\left(mol\right)\)

=> \(V_{H_2}=0,1.22,4=2,24\left(lít\right)\)

c. Theo PT: \(n_{H_2SO_4}=n_{Zn}=0,1\left(mol\right)\)

=> \(m_{H_2SO_4}=0,1.98=9,8\left(g\right)\)

Ta có: \(C_{M_{H_2SO_4}}=\dfrac{9,8}{m_{dd_{H_2SO_4}}}.100\%=25\%\)

=> \(m_{dd_{H_2SO_4}}=39,2\left(g\right)\)

Ta có: \(m_{H_2}=0,1.2=0,2\left(g\right)\)

=> \(m_{dd_{ZnSO_4}}=6,5+39,2-0,2=45,5\left(g\right)\)

Theo PT: \(n_{ZnSO_4}=n_{Zn}=0,1\left(mol\right)\)

=> \(m_{ZnSO_4}=0,1.161=16,1\left(g\right)\)

=> \(C_{\%_{ZnSO_4}}=\dfrac{16,1}{45,5}.100\%=35,4\%\)

a.\(PTHH:\)

                      \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

                 \(1mol\) \(2mol\) \(1mol\)  \(1mol\)

             \(0,3mol\) \(0,6mol\) \(0,3mol\) \(0,3mol\)

Số mol của kẽm là:

\(n_{Zn}=\frac{19,5}{65}=0,3\left(mol\right)\)

Thể tích khí hiđro ở (đktc) là:

\(V_{H_2}=0,3.22,4=6,72\left(l\right)\)

c.Khố lượng muối tạo thành \(\left(ZnCl_2\right)\)là:

\(m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)

d.Khối lượng của HCl là:

\(m_{HCl}=0,6.36,5=21,9\left(g\right)\)

Nồng độ phần trăm của HCl sau phản ứng là:

\(C\%=\frac{21,9}{500}.100=4,38\left(\%\right)\)

a, \(MgCO_3+2HCl\rightarrow MgCl_2+CO_2+H_2O\)

Ta có: \(n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

Theo PT: \(n_{MgCO_3}=n_{CO_2}=0,2\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{MgCO_3}=\dfrac{0,2.84}{64,8}.100\%\approx25,93\%\\\%m_{MgSO_4}\approx74,07\%\end{matrix}\right.\)

b, - Dung dịch C gồm: MgCl₂, MgSO₄ và HCl dư.

Theo PT: \(\left\{{}\begin{matrix}n_{MgCl_2}=n_{CO_2}=0,2\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{CO_2}=0,4\left(mol\right)\end{matrix}\right.\)

Ta có: \(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)

\(\Rightarrow n_{HCl\left(dư\right)}=0,5-0,4=0,1\left(mol\right)\)

\(m_{MgSO_4}=64,8-0,2.84=48\left(g\right)\Rightarrow n_{MgSO_4}=\dfrac{48}{120}=0,4\left(mol\right)\)

Có: m _{dd sau pư} = 64,8 + 100 - 0,2.44 = 156 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{MgCl_2}=\dfrac{0,2.95}{156}.100\%\approx12,18\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,1.36,5}{156}.100\%\approx2,34\%\\C\%_{MgSO_4}=\dfrac{48}{156}.100\%\approx30,77\%\end{matrix}\right.\)

c, PT: \(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_{2\downarrow}\)

\(HCl+NaOH\rightarrow NaCl+H_2O\)

\(MgSO_4+2NaOH\rightarrow Na_2SO_4+Mg\left(OH\right)_{2\downarrow}\)

\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)

Theo PT: \(n_{MgO}=n_{Mg\left(OH\right)_2}=n_{MgCl_2}+n_{MgSO_4}=0,6\left(mol\right)\)

\(\Rightarrow m_{cr}=m_{MgO}=0,6.40=24\left(g\right)\)