+) Ta có:

 `V(dd(H_2SO_4)(1))=300(ml)=0,3(l)`

`V(dd(H_2SO_4)(2))=200(ml)=0,2(l)`

`=> n_((H_2SO_4)(1))=0,3.2=0,6(mol)`

 `->n_((H_2SO_4)(2))=0,2.1=0,2(mol)`

=> Nồng độ mol của dung dịch H2SO4 sau trộn:

`CM_(ddH2SO4(mới))=((0,6+0,2)/(0,3+0,2))=1,6M`

`#BTrancuato<3`

\(n_{HCl}=\dfrac{400\cdot3.65\%}{36.5}=0.4\left(mol\right)\)

\(C_{M_{HCl}}=\dfrac{0.4}{2}=0.2\left(M\right)\)

2

b

mNaCl=\(\dfrac{200.15}{100}\)=30(g)

nNaCl=\(\dfrac{30}{58,5}\)=0.51(mol)

VddNaCl=\(\dfrac{200}{1,1}\)=181.8(ml)=0.1818(l)

CMNaCl=\(\dfrac{0,51}{0,1818}\)=2.8(M)

B4:

nNaOH = 0,3 . 1,5 + 0,4 . 2,5 = 1,45 (mol)

VddNaOH = 0,3 + 0,4 = 0,7 (l)

CMddNaOH = 1,45/0,7 = 2,07M

B5:

nHCl (sau khi pha) = 0,5 . 2 = 1 (mol)

Gọi VHCl (0,2) = x (l); VHCl (0,8) = y (l)

x + y = 2 (1)

nHCl (0,2) = 0,2x (mol)

nHCl (0,8) = 0,8y (mol)

=> 0,2x + 0,8y = 1 (2)

(1)(2) => x = y = 1 (l)

\(n_{NaOH}=0,2.1=0,2\left(mol\right)\\ n_{H_2SO_4}=0,3.1,5=0,45\left(mol\right)\)

\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)

0,2------->0,1--------->0,1

Xét \(\dfrac{0,2}{2}< \dfrac{0,45}{1}\Rightarrow\) \(H_2SO_4\)dư

Trong dung dịch D có:

\(\left\{{}\begin{matrix}n_{H_2SO_4}=0,45-0,1=0,35\left(mol\right)\\n_{Na_2SO_4}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}CM_{H_2SO_4}=\dfrac{0,35}{0,5}=0,7M\\CM_{Na_2SO_4}=\dfrac{0,1}{0,5}=0,2M\end{matrix}\right.\)

b

\(Ca\left(OH\right)_2+H_2SO_4\rightarrow CaSO_4+2H_2O\)

0,35<---------0,35

\(V_{Ca\left(OH\right)_2}=\dfrac{0,35.74}{1,2}=\dfrac{259}{12}\approx21,58\left(ml\right)\\ \Rightarrow V_{dd.Ca\left(OH\right)_2}=\dfrac{\dfrac{259}{12}.100\%}{10\%}=\dfrac{1295}{6}\approx215,83\left(ml\right)\)

a)

m dd = m H2SO4 + m H2O = 19,6 + 180,4 = 200(gam)

=> C% H2SO4 = 19,6/200  .100%  = 9,8%

b)

m HCl = 150.2,65% = 3,975 gam

n HCl = 3,975/36,5 = 0,11(mol)

=> CM HCl = 0,11/2 = 0,055M

c)

m dd H2SO4 = 2,45/96% = 2,552(gam)

=> V dd H2SO4 = m/D = 2,552/1,84 = 1,387(ml)