Đáp án C

Vì số mol của FeO bằng số mol của Fe₂O₃ nên ta coi hỗn hợp là Fe₃O₄
Ta có:

Fe₃O₄ +4H₂SO₄ → FeSO₄ +Fe₂(SO₄)₃ +4H₂O
0,02                          0,02

Trong 100 ml X sẽ có 0,01 mol FeSO₄ nên:

10FeSO₄ + 2KMnO₄ + 8H₂SO₄ → 5Fe₂(SO₄)₃ + K₂SO₄ + 2MnSO₄ + 8H₂O

→ n_KMnO4 = 0,02 mol → V_KMnO4 = 0,02/0,1 = 0,2 l

a) \(n_{H_2}=\dfrac{0,8}{2}=0,4\left(mol\right)\)

PTHH: 2A + H₂SO₄ --> A₂SO₄ + H₂

           0,8<-------------------------0,4

=> \(M_A=\dfrac{18,4}{0,8}=23\left(Na\right)\)

b) 

PTHH: 2Na + H₂SO₄ --> Na₂SO₄ + H₂

                          0,4<--------0,4<----0,4

=> \(C_{M\left(ddH_2SO_4\right)}=\dfrac{0,4}{0,5}=0,8M\)

\(C_{M\left(ddNa_2SO_4\right)}=\dfrac{0,4}{0,5}=0,8M\)

\(n_{K_2O}=\dfrac{23.5}{94}=0.25\left(mol\right)\)

\(K_2O+H_2O\rightarrow2KOH\)

\(0.25...................0.5\)

\(C_{M_{KOH}}=\dfrac{0.5}{0.5}=1\left(M\right)\)

\(2KOH+H_2SO_4\rightarrow K_2SO_4+H_2O\)

\(0.5............0.25............0.25\)

\(m_{dd_{H_2SO_4}}=\dfrac{0.25\cdot98}{20\%}=122.5\left(g\right)\)

\(V_{dd_{H_2SO_4}}=\dfrac{122.5}{1.14}=107.5\left(ml\right)=0.1075\left(l\right)\)

\(C_{M_{K_2SO_4}}=\dfrac{0.25}{0.1075+0.5}=0.4\left(M\right)\)

nK2O = 23,5 : 94 = 0,25 (mol)
Vdd = 500ml = 0,5l

PT K2O + H2O ==> 2KOH
TPT 1 1 2 (mol)
TĐB: 0,25 --> 0,5 (mol)

a) C_{M KOH} = 0,5 : 0,5 = 1(M)

b) PT: H2SO4 + 2KOH ==> K2SO4 + 2H2O
TPT: 1 2 1 2 (mol)

a.

\(n_{K_2O}=\dfrac{m}{M}=\dfrac{23,5}{94}=0,25\left(mol\right)\\ PT:\\ K_2O+H_2O\rightarrow2KOH\)

Theo pt: \(n_{KOH}=2n_{K_2O}=0,5\left(mol\right)\)

\(\Rightarrow C_{M\left(KOH\right)}=\dfrac{n}{V}=\dfrac{0,5}{0,5}=1\left(M\right)\)

b.

\(PT:\\ 2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)(2)

Theo pt, \(n_{H_2SO_4}=\dfrac{1}{2}n_{KOH}=0,25\left(mol\right)\)

\(\Rightarrow V_{ddH_2SO_4}=\dfrac{m_{dd}}{D}=\dfrac{n.M:C\%}{D}=\dfrac{0,25.98:20\%}{1,14}=\)107,46(ml)

c.

dd spư có chất tan là K₂SO₄

Theo pt (2), \(n_{K_2SO_4}=\dfrac{1}{2}n_{KOH}=0,25\left(mol\right)\)

=> C_M = \(\dfrac{n}{V}=\dfrac{0,25}{0,107}=2,336\left(M\right)\)

a, Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

PT: \(M+H_2SO_4\rightarrow MSO_4+H_2\)

Theo PT: \(n_M=n_{H_2}=0,2\left(mol\right)\)

\(\Rightarrow M_M=\dfrac{11,2}{0,2}=56\left(g/mol\right)\)

→ M là Fe.

b, Theo PT: \(n_{FeSO_4}=n_{H_2SO_4\left(pư\right)}=n_{H_2}=0,2\left(mol\right)\)

⇒ n_{H2SO4 dư} = 0,5.1 - 0,2 = 0,3 (mol)

\(\Rightarrow\left\{{}\begin{matrix}C_{M_{H_2SO_4\left(dư\right)}}=\dfrac{0,3}{0,5}=0,6\left(M\right)\\C_{M_{FeSO_4}}=\dfrac{0,2}{0,5}=0,4\left(M\right)\end{matrix}\right.\)

c, Ta có: \(n_{FeSO_4.7H_2O}=n_{FeSO_4}=0,2\left(mol\right)\)

\(\Rightarrow m_{FeSO_4.7H_2O}=0,2.278=55,6\left(g\right)\)

a) Ta có: \(n_{NaCl}=\dfrac{5,85}{58,5}=0,1\left(mol\right)\)

\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,1}{0,5}=0,2\left(M\right)=\left[Na^+\right]=\left[Cl^-\right]\)

b) Ta có: \(n_{Ba\left(OH\right)_2}=\dfrac{34,2}{171}=0,2\left(mol\right)\) 

\(\Rightarrow C_{M_{Ba\left(OH\right)_2}}=\dfrac{0,2}{0,5}=0,4\left(M\right)\) \(\Rightarrow\left\{{}\begin{matrix}\left[Ba^{2+}\right]=0,4\left(M\right)\\\left[OH^-\right]=0,8\left(M\right)\end{matrix}\right.\)

c) Ta có: \(n_{H_2SO_4}=0,025\cdot2=0,05\left(mol\right)\)

\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,05}{0,125+0,025}\approx0,33\left(M\right)\) \(\Rightarrow\left\{{}\begin{matrix}\left[H^+\right]=0,66\left(M\right)\\\left[SO_4^{2-}\right]=0,33\left(M\right)\end{matrix}\right.\)