2CH3COOH + Zn -- > (CH3COOH)2Zn + H2

nH2 = 2,24 / 22,4 = 0,1 (mol)

=> nCH3COOH = 0,2 (mol)

mZn = 0,1. 65 = 6,5 (g)

mH2 = 0,1.2 = 0,2 (g)

mdd  = 300 + 6,5 - 0,2 = 306,3 (g)

mCH3COOH = 0,2 . 60 = 12 (g)

=> C%CH3COOH = ( 12.100 ) / 306,3 = 4%

m(CH3COO)2Zn = 0,1 . 183 = 18,3 (g)

=> (18,3.100) / 306,3 = 6%

nKOH = 0,5.0,3 = 0,15 mol 

CH3COOH + KOH → CH3COOK + H2O

   0,15            0,15         0,15                   mol

a) C_{M CH3COOH} = 0,15/0,2 =0,75M

b) Thể tích của dung dịch thu được sau phản ứng: 500 ml

C_{M CH3COOK} = 0,15/0,5 = 0,3M

c) Phản ứng lên men giấm

C2H5OH + O2 → CH3COOH + H2O

0,15                          0,15

→ mC2H5OH = 0,15.46 = 6,9 gam

\(n_{KOH}=0,5\cdot0,3=0,15mol\)

\(CH_3COOH+KOH\rightarrow CH_3COOK+H_2O\)

0,15                     0,15          0,15            0,15

a)\(C_{M_{CH_3COOH}}=\dfrac{0,15}{0,2}=0,75M\)

b)\(C_{M_{CH_3COOK}}=\dfrac{0,15}{0,2+0,3}=0,3M\)

a) Na₂CO₃ + 2CH₃COOH --> 2CH₃COONa + CO₂ + H₂O

b) \(n_{CH_3COOH}=\dfrac{25.6\%}{60}=0,025\left(mol\right)\)

PTHH: Na₂CO₃ + 2CH₃COOH --> 2CH₃COONa + CO₂ + H₂O

              0,0125<-----0,025------------>0,025------>0,0125

=> \(m_{Na_2CO_3}=0,0125.106=1,325\left(g\right)\)

c) \(m_{dd.sau.pư}=1,325+25-0,0125.44=25,775\left(g\right)\)

\(C\%_{dd.CH_3COONa}=\dfrac{0,025.82}{25,775}.100\%=7,95\%\)

m CH3COOH=1,5g=>n=0,025 mol

2CH3COOH+Na2CO3->2CH3COONa+H2O+CO2

0,025--------------0,0125----------0,025

=>m Na2CO3=0,0125.106=1,325g

=>mdd=25g

c) 

C% =\(\dfrac{0,025.82}{25+25}100=4,1\%\)

$a\big)$

$n_{CH_3COOH}=\dfrac{100}{1000}.1=0,1(mol)$

$CH_3COOH+NaOH\to CH_3COONa+H_2O$

Theo PT: $n_{NaOH}=n_{CH_3COOH}=0,1(mol)$

$\to C\%_{NaOH}=\dfrac{0,1.40}{50}.100\%=80\%$

$b\big)$

$n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1(mol)$

$2CH_3COOH+Na_2CO_3\to 2CH_3COONa+CO_2+H_2O$

Theo PT: $\begin{cases} n_{CO_2}=n_{Na_2CO_3}=0,1(mol)\\ n_{CH_3COONa}=2n_{Na_2CO_3}=0,2(mol) \end{cases}$

$\to C\%_{CH_3COONa}=\dfrac{0,2.82}{60+10,6-0,1.44}.100\%\approx 24,77\%$

Ta có nFe=7,2/72=0,1(mol)

Feo+H2SO4=>FeSO4+H2

a, nFeSO4=nFeO=0,1(mol)

=>mFeSO4=0,1.152=15,2(g)

b, ta có nH2SO4=0,1(mol)

=>Cm(H2SO4)=0,1/0,25=0,4(M)

PTHH: \(CH_3COOH+KHCO_3\rightarrow CH_3COOK+H_2O+CO_2\uparrow\)

a) Ta có: \(n_{CH_3COOH}=\dfrac{200\cdot24\%}{60}=0,8\left(mol\right)=n_{KHCO_3}\)

\(\Rightarrow m_{ddKHCO_3}=\dfrac{0,8\cdot100}{16,8\%}\approx476.2\left(g\right)\)

b) Theo PTHH: \(n_{CH_3COOK}=0,8\left(mol\right)=n_{CO_2}\)

\(\Rightarrow\left\{{}\begin{matrix}m_{CH_3COOK}=0,8\cdot98=78,4\left(g\right)\\m_{CO_2}=0,8\cdot44=35,2\left(g\right)\end{matrix}\right.\)

 Mặt khác: \(m_{dd}=m_{ddCH_3COOH}+m_{ddKHCO_3}-m_{CO_2}=641\left(g\right)\)

\(\Rightarrow C\%_{CH_3COOK}=\dfrac{78,4}{641}\cdot100\%\approx12,23\%\)

\(n_{FeO}=\dfrac{10.8}{72}=0.15\left(mol\right)\)

\(FeO+2HCl\rightarrow FeCl_2+H_2O\)

\(0.15.......0.3.............0.15\)

\(m_{HCl}=0.3\cdot36.5=10.95\left(g\right)\)

\(C\%HCl=\dfrac{10.95}{100}\cdot100\%=10.95\%\)

\(m_{dd}=10.8+100=110.8\left(g\right)\)

\(m_{FeCl_2}=0.15\cdot127=19.05\left(g\right)\)

\(C\%FeCl_2=\dfrac{19.05}{110.8}\cdot100\%=17.19\%\)

C%HCl=10.95100⋅100%=10.95%C%HCl=10.95100⋅100%=10.95%

mdd=10.8+100=110.8(g)mdd=10.8+100=110.8(g)

mFeCl2=0.15⋅127=19.05(g)mFeCl2=0.15⋅127=19.05(g)

a, \(n_{CH_3COOH}=\dfrac{15}{60}=0,25\left(mol\right)\)

PT: \(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)

Theo PT: \(n_{CH_3COONa}=n_{CH_3COOH}=0,25\left(mol\right)\)

\(\Rightarrow a=m_{CH_3COONa}=0,25.82=20,5\left(g\right)\)

b, \(m_{dd}=\dfrac{15}{2\%}=750\left(g\right)\)

\(n_{CH_3COOH}=\dfrac{15}{60}=0,25\left(mol\right)\\ NaOH+CH_3COOH\rightarrow CH_3COONa+H_2O\\a, n_{CH_3COONa}=n_{CH_3COOH}=0,25\left(mol\right)\\ a=m_{CH_3COONa}=0,25.82=20,5\left(g\right)\\ b,m_{ddCH_3COOH}=\dfrac{15.100}{2}=750\left(g\right)\)

\(n_{H_2SO_4}=\dfrac{150.9,8\%}{98}=0,15\left(mol\right)\\ H_2SO_4+Na_2CO_3\rightarrow Na_2SO_4+H_2O+CO_2\\ n_{Na_2CO_3}=n_{H_2SO_4}=0,15\left(mol\right)\\ \Rightarrow m_{ddNa_2CO_3}=\dfrac{0,15.106}{10,6\%}=150\left(g\right)\\ n_{CO_2}=n_{H_2SO_4}=0,15\left(mol\right)\\ m_{ddsaupu}=150+150-0,15.44=293,4\left(g\right)\\ n_{Na_2SO_4}=n_{H_2SO_4}=0,15\left(mol\right)\\ C\%_{Na_2SO_4}=\dfrac{0,15.142}{293,4}.100=7,26\%\)