\(1< \dfrac{n_{OH}}{n_{CO_2}}=\dfrac{0,25}{\dfrac{3,36}{22,4}}=1,67< 2\\ Tạo:Na_2CO_3\left(amol\right),NaHCO_3\left(bmol\right)\\ a.2NaOH+CO_2->Na_2CO_3+H_2O\\ NaOH+CO_2->NaHCO_3\\ a+b=\dfrac{3,36}{22,4}=0,15\\ 2a+b=0,25\\ a=0,1;b=0,05\\ m_{Na_2CO_3}=106.0,1=10,6g\\ m_{NaHCO_3}=84.0,05=4,2g\)

a. \(n_{CO_2}=0,02\left(mol\right);n_{Ca\left(OH\right)_2}=0,008\left(mol\right)\Rightarrow n_{OH^-}=0,016\\ Tacó:\dfrac{n_{OH^-}}{n_{CO_2}}=\dfrac{0,016}{0,02}=0,8\Rightarrow ChỉtạoCa\left(HCO_3\right)_2,CO_2dư\\ 2CO_2+Ca\left(OH\right)_2\rightarrow Ca\left(HCO_3\right)_2+H_2O\\ n_{Ca\left(HCO_3\right)_2}=n_{Ca\left(OH\right)_2}=0,016\left(mol\right)\\ \Rightarrow CM_{Ca\left(HCO_3\right)_2}=\dfrac{0,016}{0,4}=0,04M\)

\(b.n_{SO_2}=0,18\left(mol\right);n_{Ba\left(OH\right)_2}=0,2\left(mol\right)\Rightarrow n_{OH^-}=0,4\left(mol\right)\\Tacó:\dfrac{n_{OH^-}}{n_{CO_2}}=\dfrac{0,4}{0,18}=2,22\Rightarrow Ba\left(OH\right) _2dư\\ SO_2+Ba\left(OH\right)_2\rightarrow BaCO_3+H_2O\\ n_{Ba\left(OH\right)_2dư}=0,2-0,18=0,02\left(mol\right)\\ \Rightarrow CM_{Ba\left(OH\right)_2dư}=\dfrac{0,02}{0,2}=0,1M\)

a) \(n_{SO_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

\(n_{NaOH}=0,5.2=1\left(mol\right)\)

PTHH: 2NaOH + SO₂ --> Na₂SO₃ + H₂O

               1------->0,5------>0,5

             Na₂SO₃ + SO₂ + H₂O --> 2NaHSO₃

                0,1<-----0,1--------------->0,2

=> Thu được muối Na₂SO₃, NaHSO₃

\(\left\{{}\begin{matrix}m_{Na_2SO_3}=0,4.126=50,4\left(g\right)\\n_{NaHSO_3}=0,2.104=20,8\left(g\right)\end{matrix}\right.\)

b) \(\left\{{}\begin{matrix}C_{M\left(Na_2SO_3\right)}=\dfrac{0,4}{0,5}=0,8M\\C_{M\left(NaHSO_3\right)}=\dfrac{0,2}{0,5}=0,4M\end{matrix}\right.\)

nCO2=0,12(mol)

nNaOH=0,2(mol)

Ta có: 1< nNaOH/nCO2=0,2/0,12=1,667<2

=> Sp thu được hỗn hợp 2 muối Na2CO3 và NaHCO3

Đặt nCO2(1), (2) lần lượt là a, b(mol) (a,b>0)

PTHH: 2 NaOH + CO2 -to-> Na2CO3 + H2O (1)

2a_________a_________a(mol)

NaOH + CO2 -> NaHCO3 (2)

b_____b______b(mol)

Từ (1), (2) ta có hpt:

\(\left\{{}\begin{matrix}2a+b=0,2\\a+b=0,12\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,08\\b=0,04\end{matrix}\right.\)

Vddsau=VddNaOH=0,2(l)

=> CMddNaHCO3= 0,04/0,2=0,2(M)

CMddNa2CO3=0,08/0,2=0,4(M)

\(n_{CO_2}=0,12mol\\ n_{NaOH}=0,2mol\\ T=\frac{n_{NaOH}}{n_{CO_2}}=\frac{0,2}{0,12}=1,66// \to Na2CO_3; NaHCO_3// 2NaOH+CO_2 \to Na_2CO_3\\ NaoH+CO_2 \to NaHCO_3\\ n_{Na_2CO_3}=a(mol)\\ n_{NaHCO_3}=b(mol)\\ n_{NaOH}=2a+b=0,2(1)\\ n_{CO_2}=a+b=0,12(2)\\ (1)(2)\\ a=0,08; b=0,04\\ CM_{Na_2CO_3}=\frac{0,08}{0,2}=0,4(mol)\\ CM_{NaHCO_3}=\frac{0,04}{0,2}=0,2(mol)\\ \)

\(n_{SO_2}=\dfrac{3}{14}\left(mol\right);n_{KOH}=0,3\left(mol\right)\)

Lập tỉ lệ : \(\dfrac{n_{KOH}}{n_{SO_2}}=\dfrac{0,3}{\dfrac{3}{14}}=1,4\)

=> Thu được 2 muối sau phản ứng

\(SO_2+KOH\rightarrow KHSO_3\)

\(SO_2+2KOH\rightarrow K_2SO_3+H_2O\)

Gọi x,y là số mol KHSO3, K2SO3

\(\left\{{}\begin{matrix}x+y=\dfrac{3}{14}\\x+2y=0,3\end{matrix}\right.\)

=> \(x=\dfrac{9}{70};y=\dfrac{3}{35}\)

=> \(m_{KHSO_3}=\dfrac{108}{7}\left(g\right);m_{K_2SO_3}=\dfrac{474}{35}\left(g\right)\)

b) \(V=\dfrac{84}{1,15}=\dfrac{1680}{23}\left(ml\right)=\dfrac{42}{575}\left(l\right)\)

=> \(CM_{KHSO_3}=\dfrac{\dfrac{9}{70}}{\dfrac{42}{575}}=1,76M\)

\(CM_{K_2SO_3}=\dfrac{\dfrac{3}{35}}{\dfrac{42}{575}}=1,17M\)

Ta có: \(n_{SO_2}=\dfrac{16,8}{22,4}=0,75\left(mol\right)\)

\(m_{H_2SO_4}=300.78,4\%=235,2\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{235,2}{98}=2,4\left(mol\right)\)

PT: \(2Fe+6H_2SO_{4\left(đ\right)}\underrightarrow{t^o}Fe_2\left(SO_4\right)_3+3SO_2+6H_2O\)

____0,5____1,5________0,25______0,75 (mol)

\(\Rightarrow n_{H_2SO_4\left(dư\right)}=2,4-1,5=0,9\left(mol\right)\)

Ta có: m _{dd sau pư} = m_Fe + m _{dd H2SO4} - m_SO2 

                             = 0,5.56 + 300 - 0,75.64 = 280 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{H_2SO_4\left(dư\right)}=\dfrac{0,9.98}{280}.100\%=31,5\%\\C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0,25.400}{280}.100\%\approx35,7\%\end{matrix}\right.\)

Bạn tham khảo nhé!