Bài 1: Sửa đề: 1,53g hỗn hợp 2 kim loại

Khí sinh ra: H₂

Gọi nAl = x, nMg = y

=> 27x + 24y = 1,53 (1)

Bảo toàn e

3x + 2y = 2.\(\dfrac{1,68}{22,4}=0,15mol\)(2)

Từ (1) + (2) => x = 0,03, y = 0,03 

%mAl = \(\dfrac{0,03.27}{1,53}.100\%=52,94\%\)

%mMg = 47,06%

Gọi n_Na = a, n_Al=b trong 13,25g hh

=> 23a + 27b = 13,25 (l)

2Na + H₂SO₄ \(\rightarrow\) Na₂SO₄ + H₂

a --------------------------------> 0,5a (mol)

2Al + 3H₂SO₄ \(\rightarrow\) Al₂(SO₄)₃ + 3H₂

b ------------------------------------> 1,5b (mol)

=> 0,5a + 1,5b = \(\frac{9,52}{22,4}\) = 0,425 (ll)

Từ (l) và (ll) => \(\begin{cases}a=0,4\\b=0,15\end{cases}\)

a) m_Na = 0,4 . 23 = 9,2 (g)

m_Al = 4,05 (g)

b) %^mNa = \(\frac{9,2}{13,25}\) . 100% = 69,43%

%^mAl= 30,57%

\(A.Mg+H_2SO_4\rightarrow MgSO_4+H_2\\ B.n_{H_2}=\dfrac{1,12}{22,4}=0,05mol\\ Mg+H_2SO_4\rightarrow MgSO_4+H_2\)

0,05      0,05           0,05           0,05

\(\%m_{Mg}=\dfrac{0,05.24}{6,4}\cdot100=18,75\%\\ \%m_{Cu}=100-18,75=81,25\%\\ C.m_{ddH_2SO_4}=\dfrac{0,05.98}{20}\cdot100=24,5g\)

a) Pt : \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\uparrow\)

Theo Pt : \(n_{Mg}=n_{H2SO4}=n_{MgSO4}=n_{H2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)

b)  \(\%m_{Mg}=\dfrac{0,05.24}{6,4}.100\%=18,75\%\)

\(\%m_{Cu}=100\%-18,75\%=81,25\%\)

c) \(m_{H2SO4}=0,05.98=4,9\left(g\right)\)

\(\Rightarrow m_{ddH2SO4}=\dfrac{4.100\%}{20\%}=20\left(g\right)\)

 Chúc bạn học tốt

Mg+2HCl->MgCl2+H2

x x

2Al+6HCl->2AlCl3+3H2

y 3/2 y

mMg+mAl=23.4

->24x+27y=23.4

nH2=1.2(mol)

x+3/2 y=1.2

x=0.3(mol)->mMg=7.2(g)

y=0.6(mol)_>mAl=16.2(g)

Bạn tự tính % nhé ^^

a)\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)

PTHH: 2Al + 3H₂SO₄ → Al₂(SO₄)₃ + 3H₂

Mol:       x                                                     1,5x

PTHH: Mg + H₂SO₄ → MgSO₄ + H₂

Mol:      y                                                 y

Ta có: \(\left\{{}\begin{matrix}27x+24y=5,1\\1,5x+y=0,25\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)

\(\%m_{Al}=\dfrac{0,1.27.100\%}{5,1}=52,94\%;\%m_{Mg}=100-52,94=47,06\%\)

b) 

PTHH: 2Al + 3H₂SO₄ → Al₂(SO₄)₃ + 3H₂

Mol:      0,1      0,15                  0,05                            

PTHH: Mg + H₂SO₄ → MgSO₄ + H₂

Mol:     0,1       0,1                 0,1

\(m_{ddH_2SO_4}=\dfrac{\left(0,1+0,15\right).98.100}{9,8}=250\left(g\right)\)

m_{dd sau pứ} = 5,1+250-0,15.2 = 254,8(g)

\(C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{0,05.342.100\%}{254,8}=6,71\%\)

\(C\%_{ddMgSO_4}=\dfrac{0,1.120.100\%}{254,8}=4,71\%\)

\(n_{H_2}=\dfrac{V_{H_2}}{22,4}=\dfrac{20,16}{22,4}=0,9mol\)

Gọi \(\left\{{}\begin{matrix}n_{Al}=x\\n_{Mg}=y\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Al}=27x\\m_{Mg}=24y\end{matrix}\right.\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

 x                                      \(\dfrac{3}{2}x\)    ( mol )

\(Mg+2HCl\rightarrow MgCl_2+H_2\)

  y                                     y ( mol )

Ta có:

\(\left\{{}\begin{matrix}27x+24y=19,8\\\dfrac{3}{2}x+y=0,9\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,6\end{matrix}\right.\)

\(\Rightarrow m_{Al}=0,2.27=5,4g\)

\(\Rightarrow m_{Mg}=0,6.24=14,4g\)

\(\%m_{Al}=\dfrac{5,4}{19,8}.100=27,27\%\)

\(\%m_{Mg}=100\%-27,27\%=72,73\%\)

\(n_{H2}=\dfrac{22,4}{22,4}=1\left(mol\right)\)

a) Pt : \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2|\)

             2            3                 1                3

             a          0,6                                 1,5a

             \(Mg+H_2SO_4\rightarrow MgSO_4+H_2|\)

               1          1                 1            1

               b          0,4                            1b

b) Gọi a là số mol của Al

           b là số mol của Mg

\(m_{Al}+m_{Mg}=20,4\left(g\right)\)

⇒ \(n_{Al}.M_{Al}+n_{Mg}.M_{Mg}=20,4g\)

⇒ 27a + 24b = 20,4g (1)

The phương trình : 1,5a + 1b = 1(2)

Từ(1),(2), ta có hệ phương trình :

      27a + 24b = 20,4g

        1,5a + 1b = 1

       ⇒ \(\left\{{}\begin{matrix}a=0,4\\b=0,4\end{matrix}\right.\)

\(m_{Al}=0,4.27=10,8\left(g\right)\)

\(m_{Mg}=0,4.24=9,6\left(g\right)\)

c) \(n_{H2SO4\left(tổng\right)}=0,6+0,4=1\left(mol\right)\)

\(V_{ddH2SO4}=\dfrac{1}{0,2}=5\left(l\right)\)

 Chúc bạn học tốt

Gọi số mol Zn, AL là a, b (mol)

=> 65a + 27b = 3,79 (1)

\(n_{H_2}=\dfrac{1,792}{22,4}=0,08\left(mol\right)\) 

PTHH: Zn + H₂SO₄ --> ZnSO₄ + H₂

            a---->a------------------->a

            2Al + 3H₂SO₄ --> Al₂(SO₄)₃ + 3H₂

             b---->1,5b-------------------->1,5b

=> a + 1,5b = 0,08 (2)

(1)(2) => a = 0,05; b = 0,02

=> \(\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,05.65}{3,79}.100\%=85,752\%\\\%m_{Al}=\dfrac{0,02.27}{3,79}.100\%=14,248\%\end{matrix}\right.\)

\(n_{H_2SO_4}=a+1,5b=0,08\left(mol\right)\)

=> \(m_{H_2SO_4}=0,08.98=7,84\left(g\right)\)

Zn + H2SO4 -> ZnSO4 + H2

a -> a

2Al + 3H2SO4 -> Al2(SO4)3 + 3H2

b -> 1.5b

HPT: 65a+27b=3.79

a + 1.5b = 1.792/22.4= 0.08

Giải HPT ta được a=0.05 b=0.02
mZn = 0.05*65=3.25 (g)

mAl= 0.02*27=0.54 (g)

\(\left\{{}\begin{matrix}n_{Zn}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\) \(\Rightarrow65x+27y=3,79\left(1\right)\)

\(n_{H_2}=\dfrac{1,792}{22,4}=0,08\)

\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)

x        x                                x

\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

y          1,5y                                 1,5y

\(\Rightarrow x+1,5y=0,08\left(2\right)\)

Từ \(\left(1\right),\left(2\right)\Rightarrow\left\{{}\begin{matrix}x=0,05\\y=0,02\end{matrix}\right.\)

\(\%m_{Zn}=\dfrac{0,05\cdot65}{3,79}\cdot100\%=85,75\%\)

\(\%m_{Al}=100\%-85,75\%=14,25\%\)

\(\Sigma n_{H_2SO_4}=x+1,5y=0,05+1,5\cdot0,02=0,08mol\)

\(\Rightarrow m_{H_2SO_4}=0,08\cdot98=7,84g\)