1) \(Fe_2O_3+3H_2-t^0>2Fe+3H_2O\)

\(2Fe+3Cl_2-t^0->2FeCl_3\)

\(FeCl_3+3NaOH->Fe\left(OH\right)3+3NaCl\)

\(n_{NaOH}=0,5\left(mol\right)\) \(n_{H2SO4}=0,27\left(mol\right)\)

\(2NaOH+H_2SO_4->Na_2SO_4+2H_2O\)

0,5....................0,25...............0,25

\(\dfrac{0,5}{2}< \dfrac{0,27}{1}\) => H2SO4 dư

\(m_{Na_2SO_4}=0,25.142=35,5\left(g\right)\)

a) \(n_{NaOH}=0,2.1=0,2\left(mol\right);n_{H_2SO_4}=0,15.2=0,3\left(mol\right)\)

PTHH: 2NaOH + H₂SO₄ → Na₂SO₄ + 2H₂O

Mol:         0,2                            0,1

Ta có: \(\dfrac{0,2}{2}< \dfrac{0,3}{1}\) ⇒ NaOH hết, H₂SO₄ dư

\(m_{Na_2SO_4}=0,1.142=14,2\left(g\right)\)

b) V_{dd sau pứ} = 0,2 + 0,15 = 0,35 (l)

\(C_{M_{ddNa_2SO_4}}=\dfrac{0,1}{0,35}=\dfrac{2}{7}\approx0,2857M\)

\(C_{M_{ddH_2SO_4dư}}=\dfrac{0,3-0,1}{0,35}=\dfrac{4}{7}\approx0,57M\)

\(n_{CaCO_3}=\dfrac{20}{100}=0,2(mol)\\ PTHH:CaCO_3+H_2SO_4\to CaSO_4+H_2O+CO_2\uparrow\\ a,n_{CO_2}=n_{CaCO_3}=0,2(mol)\\ \Rightarrow V=V_{CO_2(đktc)}=0,2.22,4=4,48(l)=4480(ml)\\ b,m_{NaOH}=\dfrac{40.10\%}{100\%}=4(g)\\ \Rightarrow n_{NaOH}=\dfrac{4}{40}=0,1(mol)\\ PTHH:CO_2+2NaOH\to Na_2CO_3+H_2O\)

Vì \(\dfrac{n_{CO_2}}{1}>\dfrac{n_{NaOH}}{2}\) nên \(CO_2\) dư

\(\Rightarrow n_{Na_2CO_3}=\dfrac{1}{2}n_{NaOH}=0,05(mol)\\ \Rightarrow m_{Na_2CO_3}=0,05.106=5,3(g)\)

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\(n_{NaOH}=0,3.1=0,3\left(mol\right)\)

PTHH: 2NaOH + H₂SO₄ → Na₂SO₄ + 2H₂O

Mol:       0,3                                 0,15

\(m_{Na_2SO_4}=0,15.142=21,3\left(g\right)\)

\(nMg=\dfrac{12}{24}=0,5\left(mol\right)\)

\(nH_2SO_4=\dfrac{29,4}{98}=0,3\left(mol\right)\)

\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)

  1         1                 1            1     (mol)

 0,3        0,3          0,3           0,3     (mol)

LTL : 0,5/1  > 0,3/1 

=> Mg dư , H2SO4 đủ

\(VH_2=0,3.22,4=6,72\left(l\right)\)

m muối là mMgSO4

=> \(m\left(muối\right)=mMgSO_4=0,3.120=36\left(g\right)\)

n_H2 = 6.72 / 22.4 = 0.3 (mol) 

Mg + H₂SO₄ => MgSO₄ + H₂

0.3.......0.3.............0.3........0.3

m_Mg = 0.3 * 24 = 7.2 (g) 

m_H2SO4 = 0.3 * 98 = 29.4 (g) 

m_ddH2SO4  = 29.4 * 100 / 19.6 = 150 (g) 

m_MgSO4 = 0.3 * 120 = 36 (g) 

Đáp án D

Ta thấy khi cho  Br 2  vào dung dịch 2 muối S 4 +  thì toàn bộ  S 4 +  sẽ bị oxi hoá lên  S 6 +  ( SO 4 2 - )do đó :

n SO 2 = n SO 4 2 - = 0,15

=> m BaSO 4  = 0,15.233 = 34,95g

\(n_{NaOH}=\dfrac{10}{40}=0,25\left(mol\right);n_{HNO_3}=\dfrac{10}{63}\left(mol\right)\)

\(NaOH+HNO_3\rightarrow NaNO_3+H_2O\)

Lập tỉ lệ : \(0,25>\dfrac{10}{63}\)=> Sau phản ứng NaOH dư

Dung dịch sau phản ứng gồm NaOH dư và NaNO3

\(n_{NaOH\left(dư\right)}=0,25-\dfrac{10}{63}=\dfrac{23}{252}\left(mol\right)\\ \Rightarrow m_{NaOH\left(dư\right)}=\dfrac{23}{252}.40=3,65\left(g\right)\)

\(n_{NaNO_3}=n_{HNO_3}=\dfrac{10}{63}\left(mol\right)\\ \Rightarrow m_{NaNO_3}=\dfrac{10}{63}.85=13,49\left(g\right)\)

Ta có:

\(n_{NaOH}=\dfrac{10}{40}=0,25\left(mol\right)\\ n_{HNO_3}=\dfrac{10}{63}\left(mol\right)\)

\(PTHH:\)

\(NaOH+HNO_3\rightarrow NaNO_3+H_2O\)

Ta thấy:

\(n_{NaOH}>n_{HNO_3}\left(0,25>\dfrac{10}{63}\right)\) \(nên\) \(NaOH\) \(dư\)

Theo phương trình ta có:

\(n_{NaOH\left(p.ư\right)}=n_{NaNO_3}=n_{HNO_3}=\dfrac{10}{63}\left(mol\right)\)

\(\Rightarrow n_{NaOH\left(dư\right)}=0,25-\dfrac{10}{63}=\dfrac{23}{252}\left(mol\right)\)

Nên sau phản ứng:

\(m_{NaNO_3}=\dfrac{10}{63}.85=13,49\left(gam\right)\\ \)

\(m_{NaOH\left(dư\right)}=\dfrac{23}{252}.40=3,65\left(gam\right)\)