a)

$Fe + 2HCl \to FeCl_2 + H_2$
$FeO + 2HCl \to FeCl_2 + H_2O$

b)

Theo PTHH : $n_{Fe} = n_{H_2} = \dfrac{3,36}{22,4} = 0,15(mol)$
$m_{Fe} = 0,15.56 = 8,4(gam)$
$m_{FeO} = 12 - 8,4 = 3,6(gam)$

$n_{FeO} =0,05(mol)$
Theo PTHH : $n_{HCl} = 2n_{Fe} + 2n_{FeO} = 0,4(mol)$

$V_{dd\ HCl} = \dfrac{0,4}{2} = 0,2(lít)$

c) $Fe + CuSO_4 \to FeSO_4 + Cu$

$n_{Cu} = n_{Fe} = 0,15(mol) \Rightarrow m_{chất\ rắn} = m_{FeO} + m_{Cu}$

$= 3,6 + 0,15.64 = 13,2(gam)$

PTHH: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

              a_______a_______a_____a    (mol)

            \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)

                2b______3b__________b_____3b    (mol)

Ta lập HPT: \(\left\{{}\begin{matrix}56a+27\cdot2b=11\\a+3b=0,2\cdot2=0,4\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,1\cdot56}{11}\cdot100\%\approx50,91\%\\\%m_{Al}=49,09\%\end{matrix}\right.\)

Theo các PTHH: \(\left\{{}\begin{matrix}n_{H_2}=0,4\left(mol\right)\\n_{FeSO_4}=0,1\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,4\cdot22,4=8,96\left(l\right)\\C_{M_{FeSO_4}}=\dfrac{0,1}{0,2}=0,5\left(M\right)\\C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\end{matrix}\right.\) 

a) nH2SO4=0,4(mol)

Đặt: nFe=x(mol); nAl=y(mol) (x,y>0)

PTHH: Fe + H2SO4 -> FeSO4 + H2

x________x______x______x(mol)

2Al + 3 H2SO4 -> Al2(SO4)3 + 3 H2

y____1,5y_______0,5y_______1,5y(mol)

Ta có hpt:

\(\left\{{}\begin{matrix}56x+27y=11\\x+1,5y=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)

=> mFe=0,1.56=5,6(g)

=>%mFe=(5,6/11).100=50,909%

=>%mAl= 49,091%

b) V(H2,đktc)=0,4.22,4=8,96(l)

c) nAl2(SO4)3= 0,5y=0,5.0,2=0,1(mol)

nFeSO4=x=0,1(mol)

Vddsau=VddH2SO4=0,2(l)

=>CMddAl2(SO4)3= 0,1/0,2=0,5(M)

CMddFeSO4=0,1/0,2=0,5(M)

=> KL M là Kali (M=39, n=1)

Đáp án D

Đáp án : A

Trong 53,75g X có x mol Sn ; y mol Fe ; z mol Al

=> t(119x + 56y + 27z) = 53,75g

X + Cl₂ -> SnCl₄ ; FeCl₃ ; AlCl₃

⇒ t 4 x + 3 y + 3 z = 2 n C l 2 = 2 , 25   m o l

(Trong 0,4 mol lượng chất gấp t lần)

=> 9(119x + 56y + 27z) = 215(4x + 3y + 3z)

=> 211x – 141y – 402z = 0⁽¹⁾

=> x + y + z = 0,4 mol⁽²⁾

n H 2  = x + y + 1,5z = 31/70 (mol) ⁽³⁾

Từ (1,2,3) => z = 0,0857 mol

=> m_Al = 2,314g

\(4.\)

\(n_{H_2}=\dfrac{3.36}{22.4}=0.15\left(mol\right)\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(0.15.....0.3....................0.15\)

\(m_{Fe}=0.15\cdot56=8.4\left(g\right)\)

\(C_{M_{HCl}}=\dfrac{0.3}{0.5}=0.6\left(M\right)\)

\(5.\)

\(Đặt:n_{Fe}=a\left(mol\right),n_{Al}=b\left(mol\right)\)

\(m_{hh}=56a+27b=8.3\left(g\right)\left(1\right)\)

\(n_{H_2}=\dfrac{5.6}{22.4}=0.25\left(mol\right)\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(\Rightarrow a+1.5b=0.25\left(2\right)\)

\(\left(1\right),\left(2\right):a=b=0.1\)

\(\%Fe=\dfrac{5.6}{8.3}\cdot100\%=67.47\%\)

\(\%Al=32.53\%\)

a)

$R + 2HCl \to RCl_2 + H_2$
$Zn + 2HCl \to ZnCl_2 + H_2$

b)$n_{H_2} = \dfrac{6,72}{22,4} = 0,3(mol)$

Gọi $n_R = a(mol) \Rightarrow n_{Zn} = 2a(mol)$

$\Rightarrow a + 2a = 0,3 \Rightarrow a = 0,1$
$\RIghtarrow 0,1.R + 0,2.65 = 18,6$

$\Rightarrow R = 56(Fe)$

$n_{FeCl_2} = n_{Fe} = 0,1(mol) ; n_{ZnCl_2} = n_{Zn} = 0,2(mol)$
$m_{FeCl_2} = 0,1.127 = 12,7(gam)$
$n_{ZnCl_2} = 0,2.161  =32,2(gam)$

$n_{HCl} = 2n_{H_2} = 0,3(mol) \Rightarrow V_{dd\ HCl} = \dfrac{0,3}{1,5} = 0,2(lít)$

c) Kim loại R là Fe

Gọi x,y lần lượt là số mol của Al,Fe

\(n_{H_2}=\frac{V}{22,4}=\frac{5,6}{22,4}=0,2\left(mol\right)\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(y--2y--y---y\)     ( mol )

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(x--3x--x---1,5x\)  ( mol )

Ta có hệ:\(\hept{\begin{cases}1,5x+y=0,2\\27x+56y=18,3\end{cases}}\)

Sai đề hử ta ???

a) Fe + 2HCl --> FeCl₂ + H₂

b) \(n_{HCl}=\dfrac{36,5.30}{100.36,5}=0,3\left(mol\right)\)

PTHH: Fe + 2HCl --> FeCl₂ + H₂
_____0,15<-0,3-------------->0,15

=> \(\%Fe=\dfrac{0,15.56}{8,8}.100\%=95,45\%\)

=> \(\%Cu=\dfrac{8,8-0,15.56}{8,8}.100\%=4,55\%\)

c) V_H2 = 0,15.22,4 = 3,36(l)