Gọi a=nCu; b=nZn

Ta có 64a+65b=15,75 (1)

Zn+H2ZO4-> ZnSO4+H2

b.                                     b

 b=nH2= 3,36/22,4=0,15mol

mZn= 0,15.65= 9,75g

mCu=15,75-9,75=6(g)

%mZn=9,75.100%/15,75 =61,9%

%mCu=6.100%/15,75*38,1%

\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

PTHH: Fe + H₂SO₄ --> FeSO₄ + H₂

_____0,15<--------------0,15<---0,15

=> m_Fe = 0,15.56 = 8,4 (g)

=> m_Cu = 11,6 - 8,4 = 3,2 (g)

\(\left\{{}\begin{matrix}\%Fe=\dfrac{8,4}{11,6}.100\%=72,414\%\\\%Cu=\dfrac{3,2}{11,6}.100\%=27,586\%\end{matrix}\right.\)

m_FeSO4 = 0,15.152 = 22,8 (g)

\(n_{H_2}=\dfrac{3,36}{22,4}0,15(mol)\\ a,PTHH:Fe+H_2SO_4\to FeSO_4+H_2\\ b,n_{Fe}=n_{H_2}=0,15(mol)\\ \Rightarrow \%_{Fe}=\dfrac{0,15.56}{14,8}.100\%=56,76\%\\ \Rightarrow \%_{Cu}=100\%-56,76\%=43,24\%\\ c,n_{H_2SO_4}=0,15(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,15.98}{20\%}=73,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{73,5}{1,4}=52,5(l)\)

a) \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

PTHH: 2Al + 3H₂SO₄ --> Al₂(SO₄)₃ + 3H₂

           0,1<----------------------------0,15

=> \(\%m_{Al}=\dfrac{0,1.27}{7,5}.100\%=36\%\)

\(\%m_{Cu}=100\%-36\%=64\%\)

b) \(n_{Cu}=\dfrac{7,5-0,1.27}{64}=0,075\left(mol\right)\)

PTHH: Cu + 2H₂SO₄ --> CuSO₄ + SO₂ + 2H₂O

          0,075------------------------>0,075

            2Al + 6H₂SO₄ --> Al₂(SO₄)₃ + 3SO₂ + 6H₂O

              0,1----------------------------->0,15

=> V_SO2 = (0,075 + 0,15).22,4 = 5,04 (l)

PTHH: 

\(Zn+H_2SO_4--->ZnSO_4+H_2\)

\(Cu+H_2SO_4--\times-->\)

a. Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

Theo PT: \(n_{Zn}=n_{H_2}=0,1\left(mol\right)\)

\(\Rightarrow m_{Zn}=0,1.65=6,5\left(g\right)\)

\(\Rightarrow\%_{m_{Zn}}=\dfrac{6,5}{19,3}.100\%=33,7\%\)

\(\%_{m_{Cu}}=100\%-33,7\%=66,3\%\)

b. Theo PT: \(n_{H_2SO_4}=n_{Zn}=0,1\left(mol\right)\)

Đổi 200ml = 0,2 lít

\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,1}{0,2}=0,5M\)

c. Ta có: \(V_{dd_{ZnSO_4}}=V_{dd_{H_2SO_4}}=0,2\left(lít\right)\)

Theo PT: \(n_{ZnSO_4}=n_{Zn}=0,1\left(mol\right)\)

\(\Rightarrow C_{M_{ZnSO_4}}=\dfrac{0,1}{0,2}=0,5M\)

ta co cu khong pu voi h2so4 zn td tao ra khi la h2,viet pt tinh mol suy he pt tinh mol cua zn tinh khoi luong zn lay hh ban dau - khoi luong zn tim duoc khoi luong cu .b)tu khi suy he pt tinh mol muoi roi tinh khoi luong

a) PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)

b) Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)=n_{Zn}\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,1\cdot65}{6,5+2,16}\cdot100\%\approx75,06\%\\\%m_{Ag}=24,94\%\end{matrix}\right.\)

c) Theo PTHH: \(n_{H_2SO_4}=n_{Zn}=0,1\left(mol\right)\) \(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,1}{0,5}=0,2\left(M\right)\)

d) PTHH: \(2Ag+2H_2SO_{4\left(đ\right)}\xrightarrow[]{t^o}Ag_2SO_4+SO_2\uparrow+2H_2O\)

Ta có: \(n_{SO_2}=\dfrac{1}{2}n_{Ag}=\dfrac{1}{2}\cdot\dfrac{2,16}{108}=0,01\left(mol\right)\) \(\Rightarrow V_{SO_2}=0,01\cdot22,4=0,224\left(l\right)\)

\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

PTHH: 

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

0,2     0,2               0,2       0,2

\(a,\%m_{Fe}=\dfrac{0,2.56}{20}.100\%=56\%\)

\(\%m_{Cu}=100\%-56\%=44\%\)

\(b,C_{M\left(H_2SO_4\right)}=\dfrac{0,2}{0,1}=2\left(M\right)\)

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

  \(1\)          \(1\)                             \(1\)

  \(0,2\)        \(0,2\)                      \(0,2\)

\(n_{H_2}=\dfrac{V}{22,4}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

\(m_{Fe}=n.M=0,2.56=11,2\left(g\right)\)

\(^0/_0Fe=\dfrac{11,2}{20}.100^0/_0=56^0/_0\)

\(^0/_0Cu=100^0/_0-56^0/_0=44^0/_0\)

\(C_{M_{H_2SO_4}}=\dfrac{n}{V_{dd}}=\dfrac{0,2}{0,1}=2M\)

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