a, \(\left[Na^+\right]=0,1\)

\(\left[K^+\right]=0,1\)

\(\left[OH^-\right]=0,2\)

\(\left[SO_4^{2-}\right]=0,2\)

\(\left[H^+\right]=0,4\)

b, \(n_{H^+}=0,1.0,4=0,04\left(mol\right)\)

\(n_{OH^-}=0,1.0,2=0,02\left(mol\right)\)

\(H^++OH^-\rightarrow H_2O\)

\(\Rightarrow n_{H^+dư}=0,02\left(mol\right)\)

\(\Rightarrow\left[H^+\right]=\dfrac{0,02}{200}=10^{-4}\)

\(\Rightarrow pH=4\)

$n_{NaOH} = n_{KOH} = 0,1.0,1 = 0,01(mol)$
$n_{H_2SO_4} = 0,02(mol)$

              OH^- + H⁺ → H₂O

       Bđ : 0,01...0,04..................(mol)

      Pư : 0,01...0,01...................(mol)

Sau pư :   0......0,03...................(mol)

$V_{dd} = 0,1 + 0,1 = 0,2(lít)$

Vậy : 

 $[K^+] = [Na^+] = \dfrac{0,01}{0,2} = 0,05M$
$[H^+] = \dfrac{0,03}{0,2} = 0,15M$
$[SO_4^{2-}] = \dfrac{0,02}{0,2} = 0,1M$

b)

$pH = -log(0,15) = 0,824$

\(a,n_{Na_2SO_4}=0,2\cdot0,2=0,04\left(mol\right);n_{Ba\left(OH\right)_2}=0,2\cdot0,1=0,02\left(mol\right)\\ PTHH:Na_2SO_4+Ba\left(OH\right)_2\rightarrow2NaOH+BaSO_4\downarrow\\ TL:....1.....1......2......1\left(mol\right)\\ BR:.......0,02.....0,02......0,04......0,02\left(mol\right)\)

Vì \(\dfrac{n_{Na_2SO_4}}{1}>\dfrac{n_{Ba\left(OH\right)_2}}{1}\) nên \(Na_2SO_4\) dư, \(Ba\left(OH\right)_2\) hết

\(b,C_{M_{NaOH}}=\dfrac{0,04}{0,2+0,2}=0,1M\)

a)
$BaCl_2 + Na_2SO_4 \to BaSO_4 + 2NaCl$

$n_{BaCl_2} = 0,01 = n_{Na_2SO_4} = 0,01 \Rightarrow $ Vừa đủ

$n_{BaSO_4} = n_{Na_2SO_4} = 0,01(mol)$
$m_{BaSO_4} = 0,01.233 = 0,233(gam)$
b)

$n_{NaCl} = 2n_{Na_2SO_4} = 0,02(mol)$
$V_{dd} = 0,1 + 0,2 = 0,3(lít)$
$C_{M_{NaCl}} = \dfrac{0,02}{0,3} = 0,067M$

c)

$[Na^+] = [Cl^-] = C_{M_{NaCl}} = 0,067M$

\(n_{BaCl_2}=0.1\cdot0.1=0.01\left(mol\right)\)

\(n_{Na_2SO_4}=0.2\cdot0.05=0.01\left(mol\right)\)

\(BaCl_2+Na_2SO_4\rightarrow BaSO_4+2NaCl\)

\(0.01..........0.01............0.01..............0.02\)

\(m_{BaSO_4}=0.01\cdot233=2.33\left(g\right)\)

\(C_{M_{NaCl}}=\dfrac{0.01}{0.1+0.2}=0.03\left(M\right)\)

\(\left[Na^+\right]=\left[Cl^-\right]=0.03\left(M\right)\)

Bài 1:

Ta có: \(n_{OH^-}=n_{Na^+}=n_{NaOH}=0,2.0,4=0,08\left(mol\right)\)

\(n_{H^+}=n_{Cl^-}=n_{HCl}=0,4.0,3=0,12\left(mol\right)\)

PT ion: \(OH^-+H^+\rightarrow H_2O\)

_____0,08_____0,12 (mol)

⇒ n_{OH^- (dư)} = 0,04 (mol)

\(\Rightarrow\left\{{}\begin{matrix}\left[Na^+\right]=\frac{0,08}{0,6}\approx0,133M\\\left[Cl^-\right]=\frac{0,12}{0,6}=0,2M\\\left[OH^-\right]=\frac{0,04}{0,6}\approx0,066M\end{matrix}\right.\)

Câu 2:

Ta có: \(\Sigma n_{K^+}=n_{KCl}+2n_{K_2SO_4}=0,2.1,5+0,3.2.2=1,5\left(mol\right)\)

\(n_{Cl^-}=n_{KCl}=0,2.1,5=0,3\left(mol\right)\)

\(n_{SO_4^{2-}}=0,3.2=0,6\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\left[K^+\right]=\frac{1,5}{0,5}=3M\\\left[Cl^-\right]=\frac{0,3}{0,5}=0,6M\\\left[SO_4^{2-}\right]=\frac{0,6}{0,5}=1,2M\end{matrix}\right.\)

Bạn tham khảo nhé!

\(n_{NaCl}=0,1.0,2=0,02\left(mol\right)\)

\(m_{Na_2CO_3}=0,1.0,3=0,03\left(mol\right)\)

\(\left\{{}\begin{matrix}n_{Na^+}=0,02+0,03.2=0,08\left(mol\right)\\n_{Cl^-}=0,02\left(mol\right)\\n_{CO_3^{2-}}=0,03\left(mol\right)\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}C_{M\left(Na^+\right)}=\dfrac{0,08}{0,2+0,3}=0,16M\\C_{M\left(Cl^-\right)}=\dfrac{0,02}{0,2+0,3}=0,04M\\C_{M\left(CO_3^{2-}\right)}=\dfrac{0,03}{0,2+0,3}=0,06M\end{matrix}\right.\)

\(n_{KOH}=0.1\cdot1=0.1\left(mol\right)\)

\(n_{H_2SO_4}=0.3\cdot0.5=0.15\left(mol\right)\)

\(2KOH+H_2SO_4\rightarrow K_2SO_4+H_2O\)

\(0.1..........0.05...............0.05\)

Dung dịch D : 0.05 (mol) K₂SO₄ , 0.1 (mol) H₂SO₄

\(\left[K^+\right]=\dfrac{0.05\cdot2}{0.1+0.3}=0.25\left(M\right)\)

\(\left[H^+\right]=\dfrac{0.1\cdot2}{0.1+0.3}=0.5\left(M\right)\)

\(\left[SO_4^{2-}\right]=\dfrac{0.05+0.1}{0.1+0.3}=0.375\left(M\right)\)

\(2NaOH+H_2SO_4\rightarrow K_2SO_4+H_2O\)

\(0.2..................0.1\)

\(V_{dd_{NaOH}}=\dfrac{0.2}{1}=0.2\left(l\right)\)