1)\(n_{CO_2}\)=0,673:22,4=0,03(mol)

Gọi x;y là số mol CaCO₃;MgCO₃

=>m_hh(bđ)=\(m_{CaCO_3}+m_{MgCO_3}\)=100x+84y=2,84(1)

Ta có PTHH:

CaCO₃+2HCl->CaCl₂+CO₂+H₂O(1)

x......................................x.....................(mol)

MgCO₃+2HCl->MgCl₂+CO₂+H₂O(2)

y........................................y................(mol)

Theo PTHH(1);(2):\(n_{CO_2}\)=x+y=0,03(2)

Giải PT(1);(2)=>\(\left\{{}\begin{matrix}x=0,02\\y=0,01\end{matrix}\right.\)

=>\(\%m_{CaCO_3}\)=\(\dfrac{100.0,02}{2,84}\).100%=70,4%

=>\(\%m_{MgCO_3}\)=100%-70,4%=29,6%

nNaOH=0.01(mol)

2NaOH+SO2->Na2SO3+H2O

0.01 0.005

V=0.112(l)

2)nHCl=0.5(mol)

MgO+2HCl->MgCl2+H2O

x 2x

Fe2O3+6HCl->2FeCl3+3H2O

y 6y

Theo bài ra:40x+160y=12

2x+6y=0.5

x=0.1(mol) mMgO=4(g)

y=0.05(mol) mFe2O3=8(g)

a)

$n_{HCl} = \dfrac{250.14,6\%}{36,5} = 1(mol)$
$Na_2CO_3 + 2HCl \to 2NaCl + CO_2 + H_2O$

$n_{CO_2} = \dfrac{1}{2}n_{HCl} = 0,5(mol)$
$V_{CO_2} = 0,5.22,4 = 11,2(lít)$

b)

Sau phản ứng : 

$m_{dd} = 55 + 250  -0,5.44 = 283(gam)$
$n_{Na_2CO_3} = n_{CO_2} = 0,5(mol) \Rightarrow m_{Na_2SO_4} = 55 - 0,5.106 = 2(gam)$

$n_{NaCl} =n_{HCl}  = 1(mol)$
$C\%_{NaCl} = \dfrac{1.58,5}{283}.100\% = 20,67\%$

$C\%_{Na_2SO_4} = \dfrac{2}{283}.100\% = 0,71\%$

a) \(Na_2CO_3+2HCl\rightarrow2NaCl+CO_2+H_2O\)

\(n_{HCl}=\dfrac{250.14,6\%}{36,5}=1\left(mol\right)\)

\(TheoPT:n_{CO_2}=\dfrac{1}{2}n_{HCl}=0,5\left(mol\right)\)

=> \(V_{CO_2}=0,5.22,4=11,2\left(l\right)\)

b) \(C\%_{NaCl}=\dfrac{0,5.58,5}{55+250-0,5.44}.100=10,34\%\)

\(m_{Na_2SO_4}=55-0,5.106=2\left(g\right)\)

=> \(C\%_{Na_2SO_4}=\dfrac{2}{55+250-0,5.44}.100=0,7\%\)

\(n_{HCl}=\dfrac{250.14,6\%}{36,5}=1\left(mol\right)\\ Na_2CO_3+2HCl\rightarrow2NaCl+CO_2+H_2O\\ n_{Na_2CO_3}=n_{CO_2}=\dfrac{1}{2}=0,5\left(mol\right)\\V_{CO_2\left(đktc\right)}=0,5.22,4=11,2\left(l\right)\\ m_{Na_2CO_3}=106.0,5=53\left(g\right)\\ m_{Na_2SO_4}=55-53=2\left(g\right)\\ n_{NaCl}=n_{HCl}=1\left(mol\right)\\ m_{NaCl}=1.58,5=58,5\left(g\right)\\ m_{ddsau}=250+55-0,5.44=283\left(g\right)\\ C\%_{ddNaCl}=\dfrac{58,5}{283}.100\approx20,671\%\\ C\%_{ddNa_2SO_4}=\dfrac{2}{283}.100\approx0,707\%\)

Gọi x,y,z lần lượt là số mol của Al,Mg,Zn

PT: 

2Al + 6HCl--->2AlCl3 + 3H2

x-------3x----------------------1,5x   mol

Mg + 2HCl--->MgCl2 + H2

y-----2y----------------------y    mol

Zn + 2HCl--->ZnCl2 + H2

z----2z--------------------z      mol

b.

Số mol H2: nH2=16,352/22,4=0,73 mol

1,5x+y+z=0,73

27x = 24y =>x=8y/9

=>7y/3 +z =0,73 (*)

27x + 24y + 65z=19,6

27x = 24y

=> 48y + 65z =19,6 (**)

Từ (*),(**)

=>y=0,27 => mMg =6,48 g

z=0,1=>mZn = 6,5 g

x=0,24=>mAl =6,48g

c.

nHCl =2nH2

=>nHCl =2.0,73=1,46 mol

=>V dd=1,46/2=0,73(l)

a) Gọi n Zn = a(mol) ; n ZnO =  b(mol)

=> 65a + 81b = 14,6(1)

$Zn + 2HCl \to ZnCl_2 + H_2$
$ZnO + 2HCl \to ZnCl_2 + H_2O$

n ZnCl2 = a + b = 27,2/136 = 0,2(2)

Từ (1)(2) suy ra : a = b = 0,1

%m Zn = 0,1.65/14,6  .100% = 44,52%
%m ZnO = 100% -44,52% = 55,45%

b)

n HCl = 2n Zn + 2n ZnO = 0,4(mol)

m dd HCl = 0,4.36,5/7,3% = 200(gam)

Fe + 2HCl -> FeCl2 + H2

          0.2                     0.1

FeO + 2HCl -> FeCl2 + H2O

 0.1       0.2

a.\(nH2=\dfrac{2.24}{22.4}=0.1mol\)

\(\%mFe=\dfrac{0.1\times56\times100}{12.8}=43.8\%\)

\(\%mFeO=100-43.8=56.2\%\)

b.\(nFeO=\dfrac{12.8-\left(0.1\times56\right)}{56+16}=0.1mol\)

\(V_{HCl}=\dfrac{0.2+0.2}{2}=0.2l\)