a) \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

PTHH: Mg + 2HCl --> MgCl₂ + H₂

_____0,1<-0,2------<0,1<---0,1

=> m_MgCl2 = 0,1.95 = 9,5 (g)

b) \(C_{M\left(HCl\right)}=\dfrac{0,2}{0,2}=1M\)

Gọi x, y lần lượt là số mol của Zn và Fe

Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

a. PTHH:

Zn + 2HCl ---> ZnCl₂ + H₂ (1)

Fe + 2HCl ---> FeCl₂ + H₂ (2)

Theo PT₍₁₎: \(n_{H_2}=n_{Zn}=x\left(mol\right)\)

Theo PT₍₂₎: \(n_{H_2}=n_{Fe}=y\left(mol\right)\)

=> x + y = 0,3 (*)

Theo đề, ta có: 65x + 56y = 17,7 (**)

Từ (*) và (**), ta có HPT:

\(\left\{{}\begin{matrix}x+y=0,3\\65x+56y=17,7\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)

=> \(m_{Zn}=0,1.65=6,5\left(g\right)\)

=> \(\%_{m_{Zn}}=\dfrac{6,5}{17,7}.100\%=36,72\%\)

\(\%_{m_{Fe}}=100\%-36,72\%=63,28\%\)

b. Ta có: \(n_{hh_{Zn,Fe}}=0,1+0,2=0,3\left(mol\right)\)

Theo PT_{(1, 2)}: \(n_{HCl}=2.n_{hh}=2.0,3=0,6\left(mol\right)\)

=> \(m_{HCl}=0,6.36,5=21,9\left(g\right)\)

=> \(C_{\%_{HCl}}=\dfrac{21,9}{200}.100\%=10,95\%\)

\(a,Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right);n_{HCl}=2.0,2=0,4\left(mol\right)\\ m_{ZnCl_2}=136.0,2=27,2\left(g\right);C_{MddHCl}=\dfrac{0,4}{0,1}=4\left(M\right)\\ b,Zn+CuSO_4\rightarrow ZnSO_4+Cu\\ n_{CuSO_4}=\dfrac{20.10\%}{160}=0,0125\left(mol\right);n_{Zn}=0,2\left(mol\right)\\ Vì:\dfrac{0,0125}{1}< \dfrac{0,2}{1}\Rightarrow Zn.dư\\ n_{Zn\left(p.ứ\right)}=n_{ZnSO_4}=n_{CuSO_4}=0,0125\left(mol\right)\\m_{Zn\left(p.ứ\right)}=0,0125.65=0,8125\left(g\right)\\ m_{ddsau}=m_{Zn\left(p.ứ\right)}+m_{ddCuSO_4}=0,8125+20=20,8125\left(g\right)\\ C\%_{ddZnSO_4}=\dfrac{0,0125.161}{20,8125}.100\approx9,67\%\)

mHCl= 3,65%.400= 14,6(g) => nHCl=14,6/36,5=0,4(mol)

a) PTHH: Mg +2 HCl -> MgCl2 + H2

0,2__________0,4_____0,2____0,2(mol)

V(H2,đktc)=0,2.22,4=4,48(l)

b)mMg=0,2.24=4,8(g)

c) mMgCl2= 0,2.95=19(g)

mddMgCl2= 400+4,8 - 0,2.2= 404,4(g)

=> C%ddMgCl2= (19/404,4).100=4,698%

\(n_{Zn}=\dfrac{13}{65}=0.2\left(mol\right)\)

\(n_{HCl}=\dfrac{182.5\cdot10}{100\cdot36.5}=0.5\left(mol\right)\)

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(0.2......0.4..........0.2........0.2\)

\(n_{HCl\left(dư\right)}=0.5-0.4=0.1\left(mol\right)\)

\(m_{HCl\left(dư\right)}=0.1\cdot36.5=3.65\left(g\right)\)

\(V_{H_2}=0.2\cdot22.4=4.48\left(l\right)\)

\(m_{\text{dung dịch sau phản ứng}}=13+182.5-0.2\cdot2=195.1\left(g\right)\)

\(C\%_{HCl\left(dư\right)}=\dfrac{3.65}{195.1}\cdot100\%=1.87\%\)

\(C\%_{ZnCl_2}=\dfrac{0.2\cdot136}{195.1}\cdot100\%=13.94\%\)

a, \(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)

 \(m_{HCl}=109,5.10\%=10,95\left(g\right)\Rightarrow n_{HCl}=\dfrac{10,95}{36,5}=0,3\left(mol\right)\)

PTHH: 2Al + 6HCl → 2AlCl₃ + 3H₂

Mol:      0,1      0,3         0,1       0,15

Ta có: \(\dfrac{0,1}{2}=\dfrac{0,3}{6}\) ⇒ Al hết, HCl hết

\(V_{H_2}=0,15.22,4=3,36\left(l\right)\)

b, \(m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\)

c, m_{dd sau pứ} = 2,7 + 109,5 - 0,15.2 = 111,9 (g)

\(C\%_{ddAlCl_3}=\dfrac{13,35.100\%}{111,9}=11,93\%\)

PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)

Ta có: \(\left\{{}\begin{matrix}n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\n_{HCl}=\dfrac{109,5\cdot10\%}{36,5}=0,3\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,1}{2}=\dfrac{0,3}{6}\) \(\Rightarrow\) Al và HCl đều p/ứ hết

\(\Rightarrow\left\{{}\begin{matrix}n_{AlCl_3}=0,1\left(mol\right)\\n_{H_2}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{AlCl_3}=0,1\cdot133,5=13,35\left(g\right)\\V_{H_2}=0,15\cdot22,4=3,36\left(l\right)\\m_{H_2}=0,15\cdot2=0,3\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{Al}+m_{ddHCl}-m_{H_2}=111,9\left(g\right)\)

\(\Rightarrow C\%_{AlCl_3}=\dfrac{13,35}{111,9}\cdot100\%\approx11,93\%\)

\(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\\ m_{HCl}=\dfrac{100.18,25}{100}=18,25\left(g\right)\\ n_{HCl}=\dfrac{18,25}{36,5}=0,5\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)  
            0,125                            0,125 (mol ) 
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(l\right)\\ \)   
\(C\%=\dfrac{8,125}{8,125+18,25}.100\%=30,8\%\)
 

Bài 18:

Ta có: \(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)

\(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)

a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

b, Xét tỉ lệ: \(\dfrac{0,125}{1}< \dfrac{0,5}{2}\), ta được HCl dư.

Theo PT: \(n_{H_2}=n_{Zn}=0,125\left(mol\right)\)

\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(g\right)\)

\(m_{H_2}=0,125.2=0,25\left(g\right)\)

c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,125\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Zn}=0,25\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow n_{HCl\left(dư\right)}=0,25\left(mol\right)\)

Có: m _{dd sau pư} = 8,125 + 100 - 0,25 = 107,875 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,125.136}{107,875}.100\%\approx15,76\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,25.36,5}{107,875}.100\%\approx8,46\%\end{matrix}\right.\)

Bạn tham khảo nhé!

`a)PTHH:`

`Zn + 2HCl -> ZnCl_2 + H_2↑`

`0,125`  `0,25`    `0,125`    `0,125`      `(mol)`

`b)n_[Zn] = [ 8,125 ] / 65 = 0,125 (mol)`

`n_[HCl] = [ [ 18,25 ] / 100 . 100 ] / [ 36,5 ] = 0,5 (mol)`

Ta có: `[ 0,125 ] / 1 < [ 0,5 ] / 2`

    `-> Zn` hết, `HCl` dư

 `=> V_[H_2] = 0,125 . 22,4 = 2,8 (l)`

 `=> m_[H_2] = 0,125 . 2 = 0,25 (g)`

`c)m_\text{dd sau p/ứ} = 8,125 + 100 - 0,25 = 107,875 (g)`

`=> C%_[ZnCl_2] = [ 0,125 . 136 ] / [ 107,875 ] . 100 ~~ 15,76%`

`=> C%_[HCl(dư)] = [ ( 0,5 - 0,25 ) . 36,5 ] / [ 107,875 ] . 100 ~~ 8,46%`

\(pthh:Mg+2HCl--->MgCl_2+H_2\uparrow\)

Ta có: \(\left\{{}\begin{matrix}n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\n_{HCl}=\dfrac{\dfrac{109,5.10\%}{100\%}}{36,5}=0,3\left(mol\right)\end{matrix}\right.\)

a. Ta thấy: \(\dfrac{0,2}{1}>\dfrac{0,3}{2}\)

Vậy Mg dư

Theo pt: \(n_{H_2}=\dfrac{1}{2}.0,3=0,15\left(mol\right)\)

\(\Rightarrow m_{H_2}=0,15.2=0,3\left(g\right)\)

b. \(m_{dd_{sau.PỨ}}=4,8+109,5-0,3=114\left(g\right)\)

c. Theo pt: \(n_{MgCl_2}=0,15\left(mol\right)\)

\(\Rightarrow C_{\%_{MgCl_2}}=\dfrac{0,15.95}{114}.100\%=12,5\%\)

n Mg=\(\dfrac{4,8}{24}\)=0,2 mol

m HCl=\(\dfrac{109,5.10}{100}\)=10,95g

=>n HCl=\(\dfrac{10,95}{36,5}\)=0,3 mol

Mg + 2HCl -> MgCl₂ + H₂

0,15---0,3---------0,15----0,15 mol

=>HCl phản ứng hết, Mg dư

=> m_Mg = 0,15.24 = 3,6 (g)

=> m = 0,15.2 = 0,3 (g)

m= m_Mg + m_ddHCl- m = 3,6 + 109,5 - 0,3 = 112,8 (g)

c)

 m= 0,15.95 = 14,25 (g)

->C%_ddMgCl2=\(\dfrac{14,25}{112,8}\)_.100=12,63%