\(a) 4Na + O_2 \xrightarrow{t^o} 2Na_2O\\ b) n_{Na} = \dfrac{4,6}{23} = 0,2(mol)\\ n_{O_2} = \dfrac{1}{4}n_{Na} = 0,05(mol)\\ V_{O_2} = 0,05.22,4 = 1,12(lít)\\ c) Na_2O + H_2O \to 2NaOH\\ n_{NaOH} = n_{Na} = 0,2(mol)\\ C\%_{NaOH} = \dfrac{0,2.40}{160}.100\% = 5\%\\ d)\)

\(n_{Na\ thêm} = x(mol)\\ 2Na + 2H_2O \to 2NaOH + H_2\\ n_{NaOH} = n_{Na} = x(mol)\\ n_{H_2} =0,5x(mol)\\ \Rightarrow m_{dd} = 23x + 160 -0,5x.2 = 22x + 160(gam)\\ \Rightarrow C\% = \dfrac{0,2.40 + 40x}{22x + 160}.100\% = 5\% + 5\%\\ \Rightarrow x = \dfrac{40}{189}\\ m_{Na} = \dfrac{40}{189}.23 = 4,87(gam)\)

\(n_{Na}=\dfrac{4.6}{23}=0.2\left(mol\right)\)

\(4Na+O_2\underrightarrow{^{t^0}}2Na_2O\)

\(0.2.....0.05.........0.1\)

\(V_{O_2}=0.05\cdot22.4=1.12\left(l\right)\)

\(Na_2O+H_2O\rightarrow2NaOH\)

\(0.1.......................0.2\)

\(m_{NaOH}=0.2\cdot40=8\left(g\right)\)

\(C\%_{NaOH}=\dfrac{8}{160}\cdot100\%=5\%\)

Để C% tăng thêm 5% 

\(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\)

\(a...............a.......0.5a\)

\(m_{NaOH}=40a\left(g\right)\)

\(m_{dd_{NaOH}}=23a+160-0.5a\cdot2=22a+160\left(g\right)\)

\(C\%_{NaOH}=\dfrac{40a+8}{22a+160}\cdot100\%=5\%\)

\(\Rightarrow a=0\)

=> Sai đề

a) \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)

PTHH: Zn + 2HCl --> ZnCl₂ + H₂

           0,1-->0,2------>0,1-->0,1

=> V_H2 = 0,1.22,4 = 2,24 (l)

m_ZnCl2 = 0,1.136 = 13,6 (g)

b) \(C\%_{dd.HCl}=\dfrac{0,2.36,5}{200}.100\%=3,65\%\)

c) \(n_{O_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

PTHH: 2H₂ + O₂ --t^o--> 2H₂O

Xét tỉ lệ: \(\dfrac{0,1}{2}< \dfrac{0,15}{1}\) => H₂ hết, O₂ dư

PTHH: 2H₂ + O₂ --t^o--> 2H₂O

            0,1--------------->0,1

=> m_H2O = 0,1.18 = 1,8 (g)

Ta có: \(n_{Na}=\dfrac{9,2}{23}=0,4\left(mol\right)\)

\(PTHH:2Na+2H_2O--->2NaOH+H_2\uparrow\)

a. Theo PT: \(n_{H_2}=\dfrac{1}{2}.n_{Na}=\dfrac{1}{2}.0,4=0,2\left(mol\right)\)

\(\Rightarrow V_{H_2}=0,2.22,4=4,48\left(lít\right)\)

b. Theo PT: \(n_{NaOH}=n_{Na}=0,4\left(mol\right)\)

\(\Rightarrow m_{NaOH}=0,4.40=16\left(g\right)\)

Ta có: \(m_{dd_{NaOH}}=9,2+200-0,2.2=208,8\left(g\right)\)

\(\Rightarrow C_{\%_{NaOH}}=\dfrac{16}{208,8}.100\%=7,66\%\)

\(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\\ m_{HCl}=\dfrac{100.18,25}{100}=18,25\left(g\right)\\ n_{HCl}=\dfrac{18,25}{36,5}=0,5\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)  
            0,125                            0,125 (mol ) 
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(l\right)\\ \)   
\(C\%=\dfrac{8,125}{8,125+18,25}.100\%=30,8\%\)
 

Bài 18:

Ta có: \(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)

\(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)

a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

b, Xét tỉ lệ: \(\dfrac{0,125}{1}< \dfrac{0,5}{2}\), ta được HCl dư.

Theo PT: \(n_{H_2}=n_{Zn}=0,125\left(mol\right)\)

\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(g\right)\)

\(m_{H_2}=0,125.2=0,25\left(g\right)\)

c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,125\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Zn}=0,25\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow n_{HCl\left(dư\right)}=0,25\left(mol\right)\)

Có: m _{dd sau pư} = 8,125 + 100 - 0,25 = 107,875 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,125.136}{107,875}.100\%\approx15,76\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,25.36,5}{107,875}.100\%\approx8,46\%\end{matrix}\right.\)

Bạn tham khảo nhé!

`a)PTHH:`

`Zn + 2HCl -> ZnCl_2 + H_2↑`

`0,125`  `0,25`    `0,125`    `0,125`      `(mol)`

`b)n_[Zn] = [ 8,125 ] / 65 = 0,125 (mol)`

`n_[HCl] = [ [ 18,25 ] / 100 . 100 ] / [ 36,5 ] = 0,5 (mol)`

Ta có: `[ 0,125 ] / 1 < [ 0,5 ] / 2`

    `-> Zn` hết, `HCl` dư

 `=> V_[H_2] = 0,125 . 22,4 = 2,8 (l)`

 `=> m_[H_2] = 0,125 . 2 = 0,25 (g)`

`c)m_\text{dd sau p/ứ} = 8,125 + 100 - 0,25 = 107,875 (g)`

`=> C%_[ZnCl_2] = [ 0,125 . 136 ] / [ 107,875 ] . 100 ~~ 15,76%`

`=> C%_[HCl(dư)] = [ ( 0,5 - 0,25 ) . 36,5 ] / [ 107,875 ] . 100 ~~ 8,46%`

\(n_{Na}=\dfrac{2,3}{23}=0,1\left(mol\right)\)

PTHH: 2Na + 2H₂O --> 2NaOH + H₂

            0,1-------------->0,1---->0,05

=> V_H2 = 0,05.22,4 = 1,12 (l)

m_{dd sau pư} = 2,3 + 197,8 - 0,05.2 = 200 (g)

=> \(C\%=\dfrac{0,1.40}{200}.100\%=2\%\)

\(V_{dd}=\dfrac{200}{1,08}=\dfrac{5000}{27}\left(ml\right)=\dfrac{5}{27}\left(l\right)\)

=> \(C_M=\dfrac{0,1}{\dfrac{5}{27}}=0,54M\)

`a)PTHH:`

  `Zn + 2HCl -> ZnCl_2 + H_2`

`0,02`                       `0,02`    `0,02`        `(mol)`

`n_[Zn]=[1,3]/65=0,02(mol)`

`b)V_[H_2]=0,02.22,4=0,448(l)`

`c)C%_[ZnCl_2]=[0,02.136]/[1,3+50-0,02.2].100~~5,31%`

\(n_{Zn}=\dfrac{1,3}{65}=0,02\left(mol\right)\)

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

0,02   0,04         0,02       0,02  ( mol )

\(V_{H_2}=0,02.22,4=0,448\left(l\right)\)

\(C\%_{ZnCl_2}=\dfrac{0,02.136}{1,3+50-0,02.2}.100=5,3\%\)

\(n_{Zn}=\dfrac{1,3}{65}=0,02\left(mol\right)\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\) 
         0,02                 0,02           0,02 
\(V_{H_2}=0,02.22,4=0,448\left(l\right)\\ m_{\text{dd}}=1,3+50-\left(0,02.2\right)=51,26\left(g\right)\\ C\%_{ZnCl_2}=\dfrac{0,02.136}{51,26}.100\%=5,3\%\)

a) Na₂SO₃ + 2HCl --> 2NaCl + SO₂ + H₂O

b) n_HCl = 0,2.1 = 0,2 (mol)

Na₂SO₃ + 2HCl --> 2NaCl + SO₂ + H₂O

_0,1<------0,2------->0,2----->0,1

m_NaCl = 0,2.58,5 = 11,7(g)

V_SO2 = 0,1.22,4 = 2,24 (l)

c) m_Na2SO3 = 0,1.126 = 12,6 (g)

d) \(C_{M\left(NaCl\right)}=\dfrac{0,2}{0,2}=1M\)

\(a) Fe + H_2SO_4 \to FeSO_4 +H_2\\ b) n_{H_2} = n_{Fe} = \dfrac{5,6}{56} = 0,1(mol)\\ V_{H_2} = 0,1.22,4 = 2,24(lít)\\ c) m_{dd\ sau\ pư} = 5,6 + 224,6 - 0,1.2 = 230(gam)\\ n_{FeSO_4} = n_{Fe} = 0,1(mol)\\ C\%_{FeSO_4} = \dfrac{0,1.152}{230}.100\% = 6,61\%\\ d) ZnO + H_2 \xrightarrow{t^o} Zn + H_2O\\ n_{ZnO} = \dfrac{32,4}{81} = 0,4 > n_{H_2} = 0,1 \to ZnO\ dư\\ n_{ZnO\ pư} = n_{H_2} = 0,1(mol)\\ m_{ZnO\ dư} = 32,4 - 0,1.81 = 24,3(gam)\)