a, PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

Theo PT: \(n_{HCl}=2n_{H_2}=0,6\left(mol\right)\)

\(\Rightarrow m_{HCl}=0,6.36,5=21,9\left(g\right)\)

b, Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,2\left(mol\right)\)

\(\Rightarrow m_{Al}=0,2.27=5,4\left(g\right)\)

nH₂=6.72/22,4=0,3(mol)
PTHH: 2Al +   6HCl --> 2AlCl₃ + 3H₂
bài ra:  0,2 <-- 0,6  <--   0,2   <-- 0,3  /mol
a) mHCl = 0,6.36,5=21,9(g)
b) mAl = 0.2.24 = 4,8(g)
 

\(PTHH:2Al+6HCl->2AlCl_3+3H_2\)

              0,2<--0,6<----------0,2<------0,3    (mol)

\(n_{H_2\left(dktc\right)}=\dfrac{V}{22,4}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

\(m_{HCl}=n\cdot M=0,6\cdot\left(1+35,5\right)=21,9\left(g\right)\)

\(m_{AlCl_3}=n\cdot M=0,2\cdot\left(27+35,5\cdot3\right)=26,7\left(g\right)\)

a, PT: 

Ta có: nAl=23nH2=0,2(mol)

⇒mAl=0,2.27=5,4(g)

a, PT: 

Ta có: nAl=23nH2=0,2(mol)

⇒mAl=0,2.27=5,4(g)

Bài 1:

\(n_{H_2SO_4}=\dfrac{300.19,6\%}{98}=0,6\left(mol\right);n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\ PTHH:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ Vì:\dfrac{0,1}{2}< \dfrac{0,6}{3}\Rightarrow H_2SO_4dư\\ n_{Al_2\left(SO_4\right)_3}=\dfrac{3n_{Al}}{2}=\dfrac{3.0,1}{2}=0,15\left(mol\right)\\ a,m_{Al_2\left(SO_4\right)_3}=342.0,15=51,3\left(g\right)\\ b,m_{ddsau}=m_{Al}+m_{ddH_2SO_4}-m_{H_2}=2,7+300-\dfrac{3}{2}.0,1.2=302,4\left(g\right)\\ c,C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{51,3}{302,4}.100\%\approx16,964\%\\ n_{H_2SO_4\left(dư\right)}=0,6-\dfrac{3}{2}.0,1=0,45\left(mol\right)\\ C\%_{ddH_2SO_4\left(dư\right)}=\dfrac{0,45.98}{302,4}.100\%\approx14,583\%\)

Bài 2:

\(PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ Đặt:n_{Al}=a\left(mol\right);n_{Mg}=b\left(mol\right)\left(a,b>0\right)\\ Hpt:\left\{{}\begin{matrix}27a+24b=7,8\\1,5a+b=\dfrac{8,96}{22,4}=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\\ \%m_{Al}=\dfrac{0,2.27}{7,8}.100\%\approx69,231\%\Rightarrow\%m_{Mg}\approx100\%-69,231\%\approx30,769\%\)

a,\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right);n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

PTHH: Fe + 2HCl → FeCl₂ + H₂

Mol:    0,15     0,3

Ta có: \(\dfrac{0,2}{1}>\dfrac{0,15}{1}\) ⇒ H₂ pứ hết,Fe dư

\(V_{H_2}=3,36\left(l\right)\) (đề cho)

b, ko tính đc k/lg dd ,chỉ tính đc thể tích dd

\(V_{ddHCl}=\dfrac{0,2}{1}=0,2\left(l\right)=200\left(ml\right)\)

\(n_{H_2}=\dfrac{14,874}{24,79}=0,6\left(mol\right)\)

PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)

        0,6        1,2                    0,6 (mol)

a, m_Fe = 0,6.56 = 33,6 (g)

b, m_HCl = 1,2.36,5 = 43,8 (g)

\(a,n_{H_2}=\dfrac{14,874}{24,79}=0,6mol\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{H_2}=n_{Fe}=0,6mol\\ m_{Fe}=0,6.56=33,6g\\ b.n_{HCl}=0,6.2=1,2mol\\ m_{HCl}=1,2.36,5=43,8g\)

Sửa: \(14,7\%\)

\(n_{H_2SO_4}=\dfrac{200.14,7\%}{100\%.98}=0,3(mol)\\ a,PTHH:2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ \Rightarrow n_{H_2}=0,3(mol)\\ \Rightarrow V_{H_2}=0,3.22,4=6,72(l)\\ b,n_{Al}=\dfrac{2}{3}n_{H_2SO_4}=0,2(mol)\\ \Rightarrow m_{Al}=0,2.27=5,4(g)\\ c,n_{Al_2(SO_4)_3}=\dfrac{1}{2}n_{Al}=0,1(mol)\\ \Rightarrow C\%_{Al_2(SO_4)_3}=\dfrac{0,1.342}{200+5,4-0,3.2}.100\%=16,7\%\\ c,m_{Al_2(SO_4)_3}=0,1.342=34,2(g)\)

Bài 1:

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2\\ n_{Al}=\dfrac{2}{3}.0,3=0,2\left(mol\right)\\ \Rightarrow m_{Al}=0,2.27=5,4\left(g\right)\\ \%m_{Al}=\dfrac{5,4}{26,82}.100\approx20,134\%\\\Rightarrow \%m_{Al_2O_3}\approx79,866\%\\ b,n_{Al_2O_3}=\dfrac{26,82-5,4}{102}=0,21\left(mol\right)\\ n_{HCl}=6.0,21+2.0,3=1,86\left(mol\right)\\ V_{ddHCl}=\dfrac{1,86}{2}=0,93\left(l\right)=930\left(ml\right)\\ m_{ddHCl}=930.1,12=1041,6\left(g\right)\\ n_{AlCl_3}=2.0,21+0,2=0,62\left(mol\right)\\ C\%_{ddAlCl_3}=\dfrac{0,62.133,5}{1041,6-0,3.2}.100\approx7,951\%\)

2)

a) Gọi KL và oxit của nó là M và MO

n_HCl = 4.0,25 = 1 (mol)

\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

PTHH: M + 2HCl --> MCl₂ + H₂

          0,3<-0,6<--------------0,3

            MO + 2HCl --> MCl₂ + H₂O

          0,2<---0,4

=> 0,3.M_M + 0,2.(M_M + 16) = 31,2

=> M_M = 56 (g/mol)

=> Kim loại là Sắt (Fe)

b) 

\(\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,3.56}{31,2}.100\%=53,85\%\\\%m_{FeO}=\dfrac{0,2.72}{31,2}.100\%=46,15\%\end{matrix}\right.\)

Bài 2:

Đặt A là kim loại cần tìm

\(a,A+2HCl\rightarrow ACl_2+H_2\left(1\right)\\ AO+2HCl\rightarrow ACl_2+H_2O\left(2\right)\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{HCl\left(ban.đầu\right)}=0,25.4=1\left(mol\right)\\ n_{HCl\left(1\right)}=2.n_{H_2}=0,6\left(mol\right)\\ n_{HCl\left(2\right)}=1-0,6=0,4\left(mol\right)\\ n_{AO}=\dfrac{0,4}{2}=0,2\left(mol\right)\\ n_A=n_{H_2}=0,3\left(mol\right)\\ Vì:m_{hhđầu}=31,2\\ \Leftrightarrow m_A+m_{AO}=31,2\\ \Leftrightarrow0,3.M_A+0,2.\left(M_A+16\right)=31,2\\ \Leftrightarrow M_A=56\left(\dfrac{g}{mol}\right)\\ \Rightarrow A:Sắt\left(Fe=56\right)\\ b,\%m_{Fe}=\dfrac{0,3.56}{31,2}.100\approx53,846\%\\ \Rightarrow\%m_{FeO}\approx46,154\%\)