\(n_{H_2SO_4}=0.1\cdot2=0.2\left(mol\right)\)

\(m_{dd_{H_2SO_4}}=100\cdot1.2=120\left(g\right)\)

\(n_{BaCl_2}=0.1\cdot1=0.1\left(mol\right)\)

\(m_{dd_{BaCl_2}}=100\cdot1.32=132\left(g\right)\)

\(BaCl_2+H_2SO_4\rightarrow BaSO_4+2HCl\)

\(0.1................0.1.........0.1...............0.2\)

\(\Rightarrow H_2SO_4dư\)

\(m_{BaSO_4}=0.1\cdot233=23.3\left(g\right)\)

\(V_{dd}=0.1+0.1=0.2\left(l\right)\)

\(C_{M_{H_2SO_4\left(dư\right)}}=\dfrac{0.2-0.1}{0.2}=0.5\left(M\right)\)

\(C_{M_{HCl}}=\dfrac{0.2}{0.2}=1\left(M\right)\)

\(m_{\text{dung dịch sau phản ứng}}=120+132-23.3=228.7\left(g\right)\)

\(C\%_{H_2SO_4\left(dư\right)}=\dfrac{0.1\cdot98}{228.7}\cdot100\%=4.28\%\)

\(C\%_{HCl}=\dfrac{0.2\cdot36.5}{228.7}\cdot100\%=3.2\%\)

Giúp mình với 

a)

$BaCl_2 + H_2SO_4 \to BaSO_4 + 2HCl$
$n_{BaCl_2} = 0,1 < n_{H_2SO_4} = 0,2$ nên $H_2SO_4$ dư

$n_{BaSO_4} = n_{BaCl_2} = 0,1(mol)$
$m_{BaSO_4} = 0,1.233 = 23,3(gam)$

b)

A gồm :

$HCl : 0,1.2 = 0,2(mol)$
$H_2SO_4\ dư : 0,2 - 0,1 = 0,1(mol)$
$V_{dd} = 0,1 + 0,1= 0,2(lít)$

$C_{M_{HCl}} = \dfrac{0,2}{0,2} = 1M$
$C_{M_{H_2SO_4}} = \dfrac{0,1}{0,2} = 0,5M$

c)

$2NaOH + H_2SO_4 \to Na_2SO_4 + 2H_2O$
$n_{NaOH} = 2n_{H_2SO_4\ dư} = 0,2(mol)$
$m_{dd\ NaOH} = \dfrac{0,2.40}{15\%} = 53,33(gam)$

câu này dễ mà ta có kldd chứa 12 g bacl2 là 12*100/20=60 gam

khối lượng dd = klrdd * ml

60=12*mldd

=>cần lấy 5 mldd

Ta có PT hóa học sau:   H₂SO₄ + BaCl₂ → 2HCl + BaSO₄

\(nBaCl_2=\dfrac{70}{1000}.1=0,07mol\)

\(C_{MBaCl_2}=\dfrac{0,07}{0,07}=1M\)

a) \(n_{BaCl_2}=0,02.0,025=0,0005\left(mol\right)\)

PTHH: CuSO₄ + BaCl₂ ---> BaSO₄ + CuCl₂

           0,0005<-0,0005

\(\rightarrow m_{ddA}=0,0005.160=0,08\left(g\right)\)

\(\rightarrow C\%_{CuSO_4}=\dfrac{0,08}{20}.100\%=0,4\%\)

b) Áp dụng sơ đồ đường chéo:

\(\dfrac{m_{ddA}}{m_{CuSO_4}}=\dfrac{100-1}{1-0,4}=165\\ \rightarrow\left\{{}\begin{matrix}m_{ddA}=\dfrac{165}{165+1}.480=477\left(g\right)\\m_{CuSO_4}=480-477=3\left(g\right)\end{matrix}\right.\)

c) \(C\%_{CuSO_4\left(CuSO_4.5H_2O\right)}=\dfrac{160}{250}.100\%=64\%\)

Áp dụng sơ đồ đường chéo:

\(\dfrac{m_{ddA}}{m_{CuSO_4.5H_2O}}=\dfrac{64-1}{1-0,4}=\dfrac{105}{1}\\ \rightarrow\left\{{}\begin{matrix}m_{ddA}=\dfrac{105}{105+1}.480=475,5\left(g\right)\\m_{CuSO_4.5H_2O}=480-475,5=4,5\left(g\right)\end{matrix}\right.\)

\(m_{dd.BaCl_2}=400.1,003=401,2\left(g\right)\)

=> \(n_{BaCl_2}=\dfrac{401,2.5,2\%}{208}=0,1003\left(mol\right)\)

\(m_{dd.H_2SO_4}=100.1,14=114\left(g\right)\)

=> \(n_{H_2SO_4}=\dfrac{114.20\%}{98}=\dfrac{57}{245}\left(mol\right)\)

PTHH: BaCl₂ + H₂SO₄ --> BaSO₄ + 2HCl

Xét tỉ lệ: \(\dfrac{0,1003}{1}< \dfrac{\dfrac{57}{245}}{1}\) => BaCl₂ hết, H₂SO₄ dư

PTHH: BaCl₂ + H₂SO₄ --> BaSO₄ + 2HCl

          0,1003->0,1003-->0,1003-->0,2006

m_{dd sau pư} = 401,2 + 114 - 0,1003.233 = 491,8301 (g)

\(\left\{{}\begin{matrix}C\%_{H_2SO_4\left(dư\right)}=\dfrac{98\left(\dfrac{57}{245}-0,1003\right)}{491,8301}.100\%=2,637\%\\C\%_{HCl}=\dfrac{0,2006.36,5}{491,8301}.100\%=1,489\%\end{matrix}\right.\)

mddBaCl2 = 1,003 . 400 = 401,2 (g) mBaCl2 = 401,2 . 5,2% = 20,8624 (g)

nBaCl2 = 20,8624/208 = 0,1003 (mol)

mddH2SO4 = 1,14.100 = 114 (g) mH2SO4 = 114 . 20% = 22,8 (g)

nH2SO4 = 22,8/98 (mol)

PTHH: BaCl2 + H2SO4 -> BaSO4 + 2HCl

Bđ: 0,1003 22,8/98

Pư: 0,1003 -> 0,1003 -> 0,1003 -> 0,2006 (mol)

Sau: 0 0,132 0,1003 0,2006 (mol)

Dung dịch sau phản ứng chứa: 

mH2SO4 dư = 22,8 - 0,1003.98 = 12,9706 (g)

mHCl = 0,2006.36,5 = 7,3219 (g)

Khối lượng dd sau pư: mdd sau pư = mddBaCl2 + mddH2SO4 - mBaSO4

                                                        = 401,2 + 114 - 0,1003.233 = 491,8301 (g)

Nồng độ phần trăm: 

C% H2SO4 = (12,9706/491,8301).100% ≈ 2,64%

C% HCl = (7,3219/491,8301).100% ≈ 1,49%

Câu 2 : 

$n_{HCl} = 0,2.1 + 0,3.1,5 = 0,65(mol)$
$V_{dd} = 0,2 + 0,3 = 0,5(mol)$
$C_{M_{HCl}} = \dfrac{0,65}{0,5} =1,3M$

Câu 3 : 

Gọi $m_{H_2O\ cần\ thêm} =a (gam)$

Sau khi thêm : 

$m_{NaOH} = 100.35\% = 35(gam)$
$m_{dd} = 100 + a(gam)$

Suy ra:  $\dfrac{35}{100 + a}.100\% = 20\%$

Suy ra: a = 75(gam)

Câu 4 : 

Gọi $V_{dd\ HCl\ 2M} =a (lít) ; V_{dd\ HCl\ 3M} = b(lít)$

Ta có : 

$a + b = 4$
$2a + 3b = 4.2,75$

Suy ra a = 1(lít) ; b = 3(lít)