a) CaCl2 + 2AgNO3 => Ca(NO3)2 + 2AgCl

Ag⁺ + Cl^- => AgCl 

b) Không phản ứng 

c) Fe2(SO4)3 + 6KOH => 2Fe(OH)3 + 3K2SO4 

Fe³⁺ + 3OH^- => Fe(OH)3 

d) Na2SO3 + 2HCl => 2NaCl + SO2 + H2O 

SO₃^2- + 2H⁺ => SO₂ + H₂O

a) \(n_{NaOH}=0,2.1=0,2\left(mol\right)\); \(n_{HNO_3}=0,2.0,5=0,1\left(mol\right)\)

\(NaOH+HNO_3\rightarrow NaNO_3+H_2O\)

0,2.............0,1

Lập tỉ lệ : \(\dfrac{0,2}{1}>\dfrac{0,1}{1}\) => Sau phản ứng NaOH dư

Dung dịch D gồm NaNO3 và NaOH dư

\(n_{NaNO_3}=n_{HNO_3}=0,1\left(mol\right)\)

\(n_{NaOH\left(pứ\right)}=n_{HNO_3}=0,1\left(mol\right)\)

\(n_{NaOH\left(dư\right)}=0,2-0,1=0,1\left(mol\right)\)

Ion trong dung dịch D : Na+ , NO3-, OH-

\(\left[Na^+\right]=\dfrac{0,1+0,1}{0,2}=1M\)

\(\left[NO_3^-\right]=\dfrac{0,1}{0,2}=0,5M\)

\(\left[OH^-\right]=\dfrac{0,1}{0,2}=0,5M\)

b)Trong dung dịch D chỉ có NaOH dư phản ứng

 \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\)

0,1................0,05

=> \(V_{H_2SO_4}=\dfrac{0,05}{1}=0,05\left(l\right)\)

Tách ra lần bài đi em !

\(n_{KOH}=0.1\cdot1=0.1\left(mol\right)\)

\(n_{H_2SO_4}=0.3\cdot0.5=0.15\left(mol\right)\)

\(2KOH+H_2SO_4\rightarrow K_2SO_4+H_2O\)

\(0.1..........0.05...............0.05\)

Dung dịch D : 0.05 (mol) K₂SO₄ , 0.1 (mol) H₂SO₄

\(\left[K^+\right]=\dfrac{0.05\cdot2}{0.1+0.3}=0.25\left(M\right)\)

\(\left[H^+\right]=\dfrac{0.1\cdot2}{0.1+0.3}=0.5\left(M\right)\)

\(\left[SO_4^{2-}\right]=\dfrac{0.05+0.1}{0.1+0.3}=0.375\left(M\right)\)

\(2NaOH+H_2SO_4\rightarrow K_2SO_4+H_2O\)

\(0.2..................0.1\)

\(V_{dd_{NaOH}}=\dfrac{0.2}{1}=0.2\left(l\right)\)

\(n_{KOH}=0.1\cdot1=0.1\left(mol\right)\)

\(n_{HCl}=0.1\cdot0.5=0.05\left(mol\right)\)

\(KOH+HCl\rightarrow KCl+H_2O\)

\(0.05.......0.05.......0.05\)

Dung dịch D : 0.05 (mol) KOH , 0.05 (mol) KCl

\(\left[K^+\right]=\dfrac{0.05+0.05}{0.1+0.1}=0.5\left(M\right)\)

\(\left[Cl^-\right]=\dfrac{0.05}{0.2}=0.25\left(M\right)\)

\(\left[OH^-\right]=\dfrac{0.05}{0.2}=0.25\left(M\right)\)

\(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)

\(0.05.........0.025\)

\(V_{dd_{H_2SO_4}}=\dfrac{0.025}{1}=0.025\left(l\right)\)

Câu 1 : 

\(a.\)

\(CaCl_2+2AgNO_3\rightarrow Ca\left(NO_3\right)_2+2AgCl\)

\(Ag^++Cl^-\rightarrow AgCl\)

\(b.\) 

\(c.\)

\(Fe_2\left(SO_4\right)_3+6KOH\rightarrow2Fe\left(OH\right)_3+3K_2SO_4\)

\(Fe^{3+}+3OH^-\rightarrow Fe\left(OH\right)_3\)

\(d.\)

\(Na_2SO_3+2HCl\rightarrow2NaCl+SO_2+H_2O\)

\(SO_3^{2-}+2H^+\rightarrow SO_2+H_2O\)

Câu 2 : 

\(a.\)

\(MgCl_2+Na_2CO_3\rightarrow MgCO_3+2NaCl\)

\(Mg^{2+}+CO_3^{2-}\rightarrow MgCO_3\)

\(b.\) 

\(c.\)

\(FeCl_3+3KOH\rightarrow Fe\left(OH\right)_3+3NaCl\)

\(Fe^{3+}+3OH^-\rightarrow Fe\left(OH\right)_3\)

\(d.\)

\(Na_2CO_3+H_2SO_4\rightarrow Na_2SO_4+CO_2+H_2O\)

\(CO_3^{2-}+2H^+\rightarrow CO_2+H_2O\)

Những câu còn lại em tách ra 1 2 bài gì đó đi nha !

Đáp án C. Vì chỉ rõ các ion nào đã tác dụng với nhau làm cho phản ứng xảy ra.

a)

$KOH + HCl \to KCl + H_2O$

$n_{KOH} = 0,3(mol) < n_{HCl} = 1,05(mol)$ nên HCl dư

$n_{HCl\ dư} = 1,05 -0 ,3 = 0,75(mol)$
$n_{KCl} = n_{KOH} = 0,3(mol)$

$V_{dd} = 0,3+ 0,7 = 1(lít)$
Suy ra : 

$[K^+] = \dfrac{0,3}{1} = 0,3M$
$[Cl^-] = \dfrac{0,75 + 0,3}{1} = 1,05M$
$[H^+] = \dfrac{0,75}{1} = 0,75M$

b)

$Ba(OH)_2 + 2HCl \to BaCl_2 + 2H_2O$
$n_{Ba(OH)_2} = \dfrac{1}{2}n_{HCl} = 0,375(mol)$

$V_{Ba(OH)_2} = \dfrac{0,375}{1,5} = 0,25(lít)$

\(n_{KOH}=0.3\cdot1=0.3\left(mol\right)\)

\(n_{HCl}=0.7\cdot1.5=1.05\left(mol\right)\)

\(KOH+HCl\rightarrow KCl+H_2O\)

\(0.3...........0.3..........0.3\)

Dung dịch D gồm : 0.3 (mol) KCl , 0.75 (mol) HCl dư

\(\left[K^+\right]=\dfrac{0.3}{0.3+0.7}=0.3\left(M\right)\)

\(\left[Cl^-\right]=\dfrac{0.3+0.75}{0.3+0.7}=1.05\left(M\right)\)

\(\left[H^+\right]=\dfrac{0.75}{0.3+0.7}=0.75\left(M\right)\)

\(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)

\(0.375..................0.75\)

\(V_{dd_{Ba\left(OH\right)_2}}=\dfrac{0.375}{1.5}=0.25\left(l\right)\)