giúp mình với, mình sắp thi rồi

\(n_{Na_2CO_3}=\dfrac{360.21,2\%}{100\%.106}=0,72(mol)\\ n_{H_2SO_4}=2,5.0,2=0,5(mol)\\ PTHH:Na_2CO_3+H_2SO_4\to Na_2SO_4+H_2O+CO_2\uparrow\\ a,\text {Vì }\dfrac{n_{Na_2CO_3}}{1}>\dfrac{n_{H_2SO_4}}{1} \text {nên }Na_2CO_3\text { dư}\\ \Rightarrow n_{CO_2}=n_{H_2SO_4}=0,5(mol)\\ \Rightarrow V_{CO_2}=0,5.22,4=11,2(l)\\\)

\(b,A:Na_2SO_4\\ n_{Na_2SO_4}=n_{H_2SO_4}=0,5(mol)\\ m_{dd_{H_2SO_4}}=200.1,1=220(g);V_{dd_{Na_2CO_3}}=\dfrac{360}{1,2}=300(ml)=0,3(l)\\ \Rightarrow C\%_{Na_2SO_4}=\dfrac{0,5.142}{360+200-0,5.44}.100\%=13,2\%\\ C_{M_{Na_2SO_4}}=\dfrac{0,5}{0,3+0,2}=1M\)

\(n_{MgCO_3}=\dfrac{16,8}{84}=0,2mol\\ a.MgCO_3+H_2SO_4->MgSO_4+H_2O+CO_2\\ 2NaOH+H_2SO_{\text{4 }}->Na_2SO_4+2H_2O\\ b.n_{H_2SO_4dư}=\dfrac{1}{2}n_{NaOH}=\dfrac{1}{2}.80.0,1:40=0,1mol\\ n_{H_2SO_4\left(MgCO_3\right)}=0,2mol\\ c.C\%=\dfrac{98.0,3}{200}.100\%=14,7\%\\ V=0,2.22,4=4,48L\\ d.m_{ddsau}=200+16,8-44.0,2+80=288g\\ C\%_{Na_2SO_4}=\dfrac{40.0,1}{288}.100\%=1,39\%\\ C\%_{MgSO_4}=\dfrac{120.0,2}{288}.100\%=8,33\%\)

\(n_{MgCO_3}=\dfrac{16,8}{84}=0,2\left(mol\right)\)

\(n_{NaOH}=\dfrac{80}{40}=2\left(mol\right)\)

PTHH :

\(MgCO_3+H_2SO_4\rightarrow MgSO_4+H_2O+CO_2\uparrow\)

0,2              0,2                                         0,2 

\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)

2                 1                 1

Vậy có 0,2 mol H2SO4 phản ứng với MgCO3 

       có 1 mol H2SO4 phản ứng với NaOH 

\(m_{H_2SO_4}=1,2.98=117,6\left(g\right)\)

\(c,C\%_{H_2SO_4}=\dfrac{117,6}{200}.100\%=58,8\%\)

\(V_{CO_2}=0,2.22,4=4,48\left(l\right)\)

\(d,m_{Na_2SO_4}=1.142=142\left(g\right)\)

\(m_{ddNaOH}=\dfrac{80.100}{10}=800\left(g\right)\)

\(m_{ddH_2SO_4dư}=1.98:58,8\%\approx166,67\left(g\right)\)

\(m_{ddNa_2SO_4}=800+166,67=966,67\left(g\right)\)

\(C\%_{Na_2SO_4}=\dfrac{142}{966,67}.100\%\approx14,69\%\)

\(n_{SO_3}=\dfrac{200}{80}=2,5\left(mol\right)\)

m_{dd H2SO4 17%} = 1000.1,12 = 1120 (g)

=> \(m_{H_2SO_4}=\dfrac{1120.17}{100}=190,4\left(g\right)\)

PTHH: SO₃ + H₂O --> H₂SO₄

             2,5------------>2,5

=> m_{H2SO4(sau pư)} = 2,5.98 + 190,4 = 435,4 (g)

m_{dd sau pư} = 200 + 1120 = 1320 (g)

\(C\%_{dd.H_2SO_4.sau.pư}=\dfrac{435,4}{1320}.100\%=32,985\%\)

\(n_{NaOH}=0,2.1=0,2\left(mol\right)\\ n_{H_2SO_4}=0,3.1,5=0,45\left(mol\right)\)

\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)

0,2------->0,1--------->0,1

Xét \(\dfrac{0,2}{2}< \dfrac{0,45}{1}\Rightarrow\) \(H_2SO_4\)dư

Trong dung dịch D có:

\(\left\{{}\begin{matrix}n_{H_2SO_4}=0,45-0,1=0,35\left(mol\right)\\n_{Na_2SO_4}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}CM_{H_2SO_4}=\dfrac{0,35}{0,5}=0,7M\\CM_{Na_2SO_4}=\dfrac{0,1}{0,5}=0,2M\end{matrix}\right.\)

b

\(Ca\left(OH\right)_2+H_2SO_4\rightarrow CaSO_4+2H_2O\)

0,35<---------0,35

\(V_{Ca\left(OH\right)_2}=\dfrac{0,35.74}{1,2}=\dfrac{259}{12}\approx21,58\left(ml\right)\\ \Rightarrow V_{dd.Ca\left(OH\right)_2}=\dfrac{\dfrac{259}{12}.100\%}{10\%}=\dfrac{1295}{6}\approx215,83\left(ml\right)\)

\(n_{SO_3}=\dfrac{200}{80}=2,5mol\\ m_{H_2SO_4}=200\cdot0,1=20g\\ SO_3+H_2O->H_2SO_4\\ C\%=\dfrac{20+2,5\cdot98}{200+200}\cdot100\%=66,25\text{%}\)

m_{dung dịch H2SO4} = 500.1,2 

=> m_H2SO4 = 600.24,5% 

PTHH : SO₃ + H₂O -> H₂SO₄

n_SO3 =\(\dfrac{m}{80}\) mol

Theo PTHH => n_H2SO4 = m/80 (mol) => m_H2SO4 = 1,225m(g)

=> ΣmH2SO4=1,225m+ΣmH2SO4=1,225m+147 (g)

m_{dung dịch} = m + 600 (g)

Theo bài ra ta có hệ :

\(\dfrac{1,225m+147}{m+600}\).100%=49%

=>m=200g

ptpu : Mg+H2SO4 ---> MgSO4 + H2 (1)

a) nMg=4,8/24= 0,2 (mol)

từ (1)=> n h2so4 =n mg = nmg2so4=nh2= 0,2 (mol)

=> mddH2SO4 = 0,2x98/0,245= 80(g)

m dd sau pư= 80+4,8-0,2x2=84,4(g)

m MgSO4= 0,2x(24+96)= 24(g)

=> C%MgSO4=24/84,4x100=28,43%

b) v dung dịch sau pư = 84,4/1,2=70(ml)

CMmgso4= n/v

T Số = 0,2/0,07= 2,86 M