a) Gọi số mol Mg, Fe là a, b (mol)

=> 24a + 56b = 11,84

\(n_{HCl}=\dfrac{146.14\%}{36,5}=0,56\left(mol\right)\)

PTHH: Mg + 2HCl --> MgCl₂ + H₂

            a--->2a--------->a----->a

           Fe + 2HCl --> FeCl₂ + H₂

            b-->2b-------->b------>b

=> 2a + 2b = 0,56

=> a = 0,12; b = 0,16

=> \(\left\{{}\begin{matrix}\%Mg=\dfrac{0,12.24}{11,84}.100\%=24,324\%\\\%Fe=\dfrac{0,16.56}{11,84}.100\%=75,676\%\end{matrix}\right.\)

b) \(n_{H_2}=a+b=0,28\left(mol\right)\)

=> \(V_{H_2}=0,28.22,4=6,272\left(l\right)\)

c) m_{dd sau pư} = 11,84 + 146 - 0,28.2 = 157,28 (g)

=> \(\left\{{}\begin{matrix}C\%_{MgCl_2}=\dfrac{0,12.95}{157,28}.100\%=7,25\%\\C\%_{FeCl_2}=\dfrac{0,16.127}{157,28}.100\%=12,92\%\end{matrix}\right.\)

\(n_{Fe}=a\left(mol\right),n_{Mg}=b\left(mol\right)\)

\(m_{hh}=56a+24b=10.16\left(g\right)\)

\(n_{H_2}=\dfrac{5.6}{22.4}=0.25\left(mol\right)\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(Mg+2HCl\rightarrow MgCl_2+H_2\)

\(n_{H_2}=a+b=0.25\left(mol\right)\left(2\right)\)

\(\left(1\right),\left(2\right):a=0.13,b=0.12\)

\(m_{Fe}=0.13\cdot56=7.28\left(g\right)\)

\(m_{Mg}=0.12\cdot24=2.88\left(g\right)\)

\(n_{HCl}=2\cdot n_{H_2}=2\cdot0.25=0.5\left(mol\right)\)

\(C_{M_{HCl}}=\dfrac{0.5}{0.5}=1\left(M\right)\)

Câu 1 

\(3Cl_2+2Fe\underrightarrow{t^o}2FeCl_3\)

\(n_{Cl_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

\(n_{Fe}=\dfrac{0,3.2}{3}=0,2\left(mol\right)\) \(\Rightarrow m_{Fe}=0,2.56=11,2\left(g\right)\)

Câu 2

\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)

Gọi x và y lần lượt là số mol Fe và Mg

Bảo toàn e ta có \(2x+2y=2.0,25\) (1) 

\(m_{hh}=56x+24y=10,16\left(g\right)\) (2) 

Từ (1) và (2) => \(\left\{{}\begin{matrix}x=0,13\\y=0,12\end{matrix}\right.\)

a. \(\%m_{Fe}=\dfrac{0,13.56}{10,16}.100\%=71,65\%\)

\(\%m_{Mg}=100\%-71,65\%=28,35\%\)

b. Ta có \(n_{HCl}=n_{H^+}=2n_{H_2}=0,5\left(mol\right)\)

\(CM_{HCl}=\dfrac{0,5}{0,5}=1\left(M\right)\)

\(a,n_{H_2}=\dfrac{2,576}{22,4}=0,115\left(mol\right)\\ Đặt:n_{Mg}=a\left(mol\right);n_{Al}=b\left(mol\right)\left(a,b>0\right)\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ \Rightarrow\left\{{}\begin{matrix}95a+133,5b=10,475\\a+1,5b=0,115\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,04\\b=0,05\end{matrix}\right.\\ \%m_{Mg}=\dfrac{0,04.24}{0,04.24+0,05.27}.100\approx41,558\%\Rightarrow\%m_{Al}\approx58,442\%\\ b,n_{HCl}=2.n_{H_2}=2.0,115=0,23\left(mol\right)\\ \Rightarrow x=C\%_{ddHCl}=\dfrac{0,23.36,5}{100}.100=8,395\%\)

\(n_{Mg}=x(mol);n_{Fe}=y(mol)\\ \Rightarrow 24x+56y=4(1)\\ n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ Mg+2HCl\to MgCl_2+H_2\\ Fe+2HCl\to FeCl_2+H_2\\ \Rightarrow x+y=0,1(2)\\ (1)(2)\Rightarrow x=y=0,05(mol)\\ \Rightarrow \%_{Fe}=\dfrac{0,05.56}{4}.100\%=70\%\\ \Rightarrow \%_{Mg}=100\%-70\%=30\%\)

a) Gọi số mol Zn, Fe là a, b (mol)

=> 65a + 56b = 8,56 (1)

\(n_{H_2}=\dfrac{3,136}{22,4}=0,14\left(mol\right)\)

PTHH: Zn + 2HCl --> ZnCl₂ + H₂

           a--->2a-------->a----->a

            Fe + 2HCl --> FeCl₂ + H₂

           b----->2b------->b------>b

=> a + b = 0,14 (2)

(1)(2) => a = 0,08; b = 0,06 

=> \(\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,08.65}{8,56}.100\%=60,748\%\\\%m_{Fe}=\dfrac{0,06.56}{8,56}.100\%=39,252\%\end{matrix}\right.\)

b) 

n_KOH = 0,2.0,1 = 0,02 (mol)

PTHH: KOH + HCl --> KCl + H₂O

           0,02-->0,02

=> n_HCl = 0,02 + 2a + 2b = 0,3 (mol)

=> \(C_{M\left(HCl\right)}=xM=\dfrac{0,3}{0,15}=2M\)

c) m = 0,08.136 + 0,06.127 = 18,5(g)