\(m_{CH_3COOH}=12\%.100=12\left(g\right)\\ n_{CH_3COOH}=\dfrac{12}{60}=0,2\left(mol\right)\)

PTHH: CH₃COOH + NaOH ---> CH₃COONa + H₂O

               0,2--------->0,2------------>0,2

\(m_{NaOH}=0,2.40=8\left(g\right)\\ m_{ddNaOH}=\dfrac{8}{8,4\%}=\dfrac{2000}{21}\left(g\right)\\ m_{ddCH_3COONa}=\dfrac{2000}{21}+100=\dfrac{4100}{21}\left(g\right)\\ m_{CH_3COONa}=0,2.82=16,4\left(g\right)\\ C\%_{CH_3COONa}=\dfrac{16,4}{\dfrac{4100}{21}}.100\%=8,4\%\)

`=>` Gợi ý:

`CH3COOH + NaHCO3 => CH3COONa + CO2 + H2O`

`m<sub>CH3COOH</sub> = 100x12/100 = 12` (g)

`==> n<sub>CH3COOH</sub> = m/M = 12/60 = 0.2` (mol)

Theo pt: `=> n<sub>NaHCO3</sub> = 0.2` (mol)

`==> m<sub>NaHCO3</sub> = n.M = 0.2x84 =16.8` (g)

`==> m<sub>dd NaHCO3</sub> = 16.8x100/8.4 = 200` (g)

Ta có: `n<sub>CH3COONa</sub> = 0.2` (mol)

\(a,n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\)

PTHH: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)

           0,05---->0,1------>0,1

\(\rightarrow x=C\%_{HCl}=\dfrac{0,1.36,5}{200}.100\%=1,825\%\)

\(b,\) PTHH: \(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2\downarrow+2NaCl\)

                 0,05----->0,1-------->0,05----------->0,1

\(\rightarrow m_{ddNaOH}=\dfrac{0,1.40}{10\%}=40\left(g\right)\\ \rightarrow m_{dd\left(sau.pư\right)}=40+200+4-0,05.98=239,1\left(g\right)\)

\(\rightarrow C\%_{NaCl}=\dfrac{0,1.58,5}{239,1}.100\%=2,45\%\)

\(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\\ pthh:CuO+HCl\rightarrow CuCl_2+H_2O\)
          0,05     0,05      0,05        0,05 
\(x=C\%_{HCl}=\dfrac{0,05.36,5}{200}.100\%=0,9125\%\\ pthh:CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\) 
      
 

Mỗi phần chứa 0,02 mol X

Phần 1:

n X   :   n H C l   =   1   :   1 → X có 1 nhóm  N H 2

Phần 2:

_{n X   :   n N a O H}  = 1 : 1 → X có 1 nhóm COOH

Mà  n m u ố i   =   n X   =   0 , 02   →   M m u ố i   =   111

→ M_X = 111 – 22 = 89

X là  H 2 N C H ( C H 3 ) C O O H

Đáp án cần chọn là: A

a)

$CuO + H_2SO_4 \to CuSO_4 + H_2O$

$n_{H_2SO_4} = n_{CuO} = \dfrac{1,6}{80} = 0,02(mol)$
$C\%_{H_2SO_4} = \dfrac{0,02.98}{100}.100\% = 1,96\%$

b)

$2NaOH + H_2SO_4 \to Na_2SO_4 + 2H_2O$
$n_{NaOH} = 2n_{H_2SO_4} = 0,04(mol)$
$m_{NaOH} = 0,04.40 = 1,6(gam)$

c)

$Cu + 2H_2SO_4 \to CuSO_4 + SO_2 + 2H_2O$

Cu dư nên $n_{SO_2} = \dfrac{1}{2}n_{H_2SO_4} = 0,05(mol)$
$V_{SO_2} = 0,05.22,4 = 1,12(lít)$

\(a)n_{MnO_2}=\dfrac{69,6}{87}=0,8mol\\ MnO_2+4HCl\xrightarrow[nhẹ]{đun}MnCl_2+Cl_2+H_2O\)

0,8            3,2               0,8            0,8             0,8

\(V_A=V_{Cl_2}=0,8.22,4=17,92l\\ b)Cl_2+2NaOH\rightarrow NaCl+NaClO+H_2O\)

    0,8       1,6               0,8         0,8

\(V_{ddNaOH}=\dfrac{1,6}{1}=1,6l\\ C_{M_{NaCl}}=\dfrac{0,8}{1,6}=0,5M\\ C_{M_{NaClO}}=\dfrac{0,8}{1,6}=0,5M\)

nNaOH = 4/40 = 0.1 (mol)

PTHH: NaOH + HCl -> NaCl + H2O

Từ PTHH: nNaCl = nHCl = nNaOH = 0.1 (mol)

a) mNaCl = 0.1*(23+35.5) = 5.85(g)

b) mHCl = 0.1*(1+35.5) = 3.65(g)

C%ddHCl = 3.65/100 * 100% = 3.65%

$a\big)$

$n_{CH_3COOH}=\dfrac{100}{1000}.1=0,1(mol)$

$CH_3COOH+NaOH\to CH_3COONa+H_2O$

Theo PT: $n_{NaOH}=n_{CH_3COOH}=0,1(mol)$

$\to C\%_{NaOH}=\dfrac{0,1.40}{50}.100\%=80\%$

$b\big)$

$n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1(mol)$

$2CH_3COOH+Na_2CO_3\to 2CH_3COONa+CO_2+H_2O$

Theo PT: $\begin{cases} n_{CO_2}=n_{Na_2CO_3}=0,1(mol)\\ n_{CH_3COONa}=2n_{Na_2CO_3}=0,2(mol) \end{cases}$

$\to C\%_{CH_3COONa}=\dfrac{0,2.82}{60+10,6-0,1.44}.100\%\approx 24,77\%$

n_NaOH = 0,1.2 = 0,2 (mol)

PTHH: CH₃COOH + NaOH --> CH₃COONa + H₂O

                0,2<--------0,2

=> \(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,2}{0,15}=\dfrac{4}{3}M\)

nNaOH = 0,1 . 2 = 0,2 (mol)

PTHH: CH3COOH + NaOH -> CH3COONa + H2O

nCH3COOH = nNaOH = 0,2 (mol)

CM(CH3COOH) = 0,2/0,15 = 1,33M