PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)

               a_____2a_______a                 (mol)

            \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

               b_____2b_______b                  (mol)

Ta lập HPT: \(\left\{{}\begin{matrix}2a+2b=0,5\cdot0,4=0,2\\136a+127b=10,52\end{matrix}\right.\) (Hệ có nghiệm âm)

*Bạn xem lại đề !!

Fe + 2 HCl -> FeCl2+ H2

x____2x____x_____x(mol)

Zn +2 HCl -> ZnCl2 + H2

y____2y____y______y(mol)

Ta có: nHCl(tổng)= 0,2 (mol)

<=> 2x+2y=0,2 (1)

Mặt khác: m(muối)= 10,52(g)

<=> 127x+ 136y=10,52 (2)

Từ (1), (2) ta có hpt: {2x+2y=0,2127x+136y=10,52{2x+2y=0,2127x+136y=10,52

Bấm ra có nghiệm âm??

Đọc tiếp

Fe + 2 HCl -> FeCl2+ H2

x____2x____x_____x(mol)

Zn +2 HCl -> ZnCl2 + H2

y____2y____y______y(mol)

Ta có: nHCl(tổng)= 0,2 (mol)

<=> 2x+2y=0,2 (1)

Mặt khác: m(muối)= 10,52(g)

<=> 127x+ 136y=10,52 (2)

Từ (1), (2) ta có hpt: \(\left\{{}\begin{matrix}2x+2y=0,2\\127x+136y=10,52\end{matrix}\right.\)

Bấm ra có nghiệm âm??

a)

n Fe = a(mol) ; n Zn = b(mol)

Fe + 2HCl → FeCl2 + H2

a.........2a...........a...................(mol)

Zn + 2HCl → ZnCl2 + H2

b.........2b.............b.........................(mol)

n HCl = 2a + 2b = 0,5.0,4 = 0,2(mol)

m muối = 127a + 136b = 10,52(gam)

=> a = 0,342 ; b = -0,243 < 0

=> Sai đề

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

Gọi \(n_{Fe}=x\left(mol\right);n_{Zn}=y\left(mol\right)\)

 \(Tacó:\left\{{}\begin{matrix}127x+136y=10,43\\2x+2y=0,5.0,4=0,2\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}x=0,35\\y=-0,25\end{matrix}\right.\)

Xem lại đề !

\(n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

0,1                                   0,1   ( mol )

( Cu không tác dụng với dd axit HCl )

\(m_{Fe}=0,1.56=5,6g\)

\(\rightarrow m_{Cu}=12-5,6=6,4g\)

\(\rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{5,6}{12}.100=46,66\%\\\%m_{Cu}=100\%-46,66\%=53,34\%\end{matrix}\right.\)

a) \(n_{AlCl_3}=\dfrac{6,675}{133,5}=0,05\left(mol\right)\)

PTHH: 2Al + 6HCl --> 2AlCl₃ + 3H₂

          0,05<-----------0,05---->0,075

=> \(\%Al=\dfrac{0,05.27}{14,15}.100\%=9,54\%\)

=> \(\%Cu=\dfrac{14,15-0,05.27}{14,15}.100\%=90,46\%\)

b) \(V_{H_2}=0,075.22,4=1,68\left(l\right)\)

c) \(n_{Cu}=\dfrac{14,15-0,05.27}{64}=0,2\left(mol\right)\)

PTHH: 4Al + 3O₂ --t^o--> 2Al₂O₃

          0,05->0,0375

           2Cu + O₂ --t^o--> 2CuO 

            0,2-->0,1

=> \(V_{O_2}=\left(0,1+0,0375\right).22,4=3,08\left(l\right)\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\\ m_{AlCl_3}=6,675\left(mol\right)\\ n_{AlCl_3}=\dfrac{6,675}{133,5}=0,05\left(mol\right)\\ \Rightarrow n_{Al}=n_{AlCl_3}=0,05\left(mol\right)\\ \Rightarrow m_A=0,05.27=1,35\left(g\right);m_{Cu}=14,15-1,35=12,8\left(g\right)\\ \%m_{Cu}=\dfrac{12,8}{14,15}.100\approx90,459\%\\ \Rightarrow\%m_{Al}\approx9,541\%\\ b,n_{Cu}=\dfrac{12,8}{64}=0,2\left(mol\right)\\ n_{H_2}=\dfrac{3}{2}.n_{Al}=\dfrac{3}{2}.0,05=0,075\left(mol\right)\\ \Rightarrow V=V_{H_2\left(đktc\right)}=0,075.22,4=1,68\left(l\right)\\ 4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\\ 2Cu+O_2\rightarrow\left(t^o\right)2CuO\\ n_{O_2}=\dfrac{3}{4}.n_{Al}+\dfrac{1}{2}.n_{Cu}=\dfrac{3}{4}.0,05+\dfrac{1}{2}.0,2=0,0875\left(mol\right)\)

\(\Rightarrow V_{O_2\left(đktc\right)}=0,0875.22,4=1,96\left(l\right)\)