PTHH: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

              a_______a_______a_____a    (mol)

            \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)

                2b______3b__________b_____3b    (mol)

Ta lập HPT: \(\left\{{}\begin{matrix}56a+27\cdot2b=11\\a+3b=0,2\cdot2=0,4\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,1\cdot56}{11}\cdot100\%\approx50,91\%\\\%m_{Al}=49,09\%\end{matrix}\right.\)

Theo các PTHH: \(\left\{{}\begin{matrix}n_{H_2}=0,4\left(mol\right)\\n_{FeSO_4}=0,1\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,4\cdot22,4=8,96\left(l\right)\\C_{M_{FeSO_4}}=\dfrac{0,1}{0,2}=0,5\left(M\right)\\C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\end{matrix}\right.\) 

a) nH2SO4=0,4(mol)

Đặt: nFe=x(mol); nAl=y(mol) (x,y>0)

PTHH: Fe + H2SO4 -> FeSO4 + H2

x________x______x______x(mol)

2Al + 3 H2SO4 -> Al2(SO4)3 + 3 H2

y____1,5y_______0,5y_______1,5y(mol)

Ta có hpt:

\(\left\{{}\begin{matrix}56x+27y=11\\x+1,5y=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)

=> mFe=0,1.56=5,6(g)

=>%mFe=(5,6/11).100=50,909%

=>%mAl= 49,091%

b) V(H2,đktc)=0,4.22,4=8,96(l)

c) nAl2(SO4)3= 0,5y=0,5.0,2=0,1(mol)

nFeSO4=x=0,1(mol)

Vddsau=VddH2SO4=0,2(l)

=>CMddAl2(SO4)3= 0,1/0,2=0,5(M)

CMddFeSO4=0,1/0,2=0,5(M)

\(a) Fe + 2HCl \to FeCl_2\\ b) n_{HCl} = \dfrac{182,5.5\%}{36,5} = 0,25(mol)\\ n_{FeCl_2} = n_{H_2} = n_{Fe} = \dfrac{1}{2}n_{HCl} = 0,125(mol)\\ \Rightarrow m_{Fe} = 0,125.56 = 7(gam) ; V = 0,125.22,4 = 2,8(lít)\\ c) m_{dd\ sau\ phản\ ứng} = m_{Fe} + m_{dd\ HCl} - m_{H_2} = 7 + 182,5 - 0,125.2 = 189,25(gam)\\ C\%_{FeCl_2} = \dfrac{0,125.127}{189,25}.100\% = 8,39\%\)

a,

\(m_{HCl}=18,25\left(g\right)\)

\(\rightarrow n_{HCl}=0,5\left(mol\right)\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(\rightarrow n_{Fe}=n_{FeCl2}=n_{H2}=0,25\left(mol\right)\)

\(\rightarrow m=14\left(g\right)\)

\(\rightarrow V=5,6\left(l\right)\)

b,

\(m_{dd_{spu}}=14+182,5-0,25.2=196\left(g\right)\)

c,

\(m_{FeCl2}=31,75\left(g\right)\)

\(\rightarrow C\%_{FeCl_2}=\frac{31,75.100}{196}=16,2\%\)

n_Mg = 0,1(mol)

PTHH: Mg + 2HCl --> MgCl₂ +H₂

n_Mg = n_MgCl2= n_H2 = 0,1(mol)

=> m_muối = 9,5(g) 

_VH2 = 2,24(l)

b) CM_HCl = 0,2/0,1=2(M)

Fe+2HCl->FeCl₂+H₂

0,125--0,25---0,125-0,125

m _HCl=9,125 g=>n _HCl=\(\dfrac{9,125}{26,5}\)=0,25 mol

=>m Fe=0,125.56=7g

=>V_H2=0,125.22,4=2,8l

=>C%_FeCl2=\(\dfrac{0,125.127}{7+182,5-0,25}\).100=8,388%

\(a)n_{Fe}=\dfrac{5,6}{56}=0,1mol\\ n_{HCl}=0,5.1=0,5mol\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ \Rightarrow\dfrac{0,1}{1}< \dfrac{0,5}{2}\Rightarrow HCl.dư\\ Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1         0,2          0,1          0,1

\(m_{HCl\left(dư\right)}=\left(0,5-0,2\right).36,5=10,95g\\ b)m_{FeCl_2}=0,1.127=12,7g\\ c)V_{H_2}=0,1.22,4=2,24l\\ d)C_{\%HCl\left(dư\right)}=\dfrac{10,95}{200}\cdot100=5,475\%\\ C_{\%HCl\left(pư\right)}=\dfrac{0,2.36,5}{200}\cdot100=3,65\%\)