Bài 4 : 

\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)

a) Pt : \(Zn+2HCl\rightarrow ZnCl_2+H_2|\)

            1          2              1          1

          0,2        0,4           0,2        0,2

b) \(n_{H2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)

\(V_{H2\left(dktc\right)}=0,2.22,4=4,48\left(l\right)\)

c) \(n_{HCl}=\dfrac{0,2.2}{1}=0,4\left(mol\right)\)

⇒ \(m_{HCl}=0,4.36,5=14,6\left(g\right)\)

\(C_{ddHCl}=\dfrac{14,6.100}{100}=14,6\)⁰/₀

d) \(n_{ZnCl2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)

⇒ \(m_{ZnCl2}=0,2.136=27,2\left(g\right)\)

\(m_{ddspu}=13+100-\left(0,2.2\right)=112,6\left(g\right)\)

\(C_{ZnCl2}=\dfrac{27,2.100}{112,6}=24,16\)⁰/₀

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Bài 3 : 

\(n_{Mg}=\dfrac{12}{24}=0,5\left(mol\right)\)

a) Pt : \(Mg+H_2SO_4\rightarrow MgSO_4+H_2|\)

            1            1                1           1

          0,5          0,5            0,5          0,5

b) \(n_{H2}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)

\(V_{H2\left(dktc\right)}=0,5.22,4=11,2\left(l\right)\)

c) \(n_{H2SO4}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)

⇒ \(m_{H2SO4}=0,5.98=49\left(g\right)\)

\(C_{ddH2SO4}=\dfrac{49.100}{200}=24,5\)⁰/₀

d) \(n_{MgSO4}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)

⇒ \(m_{MgSO4}=0,5.120=60\left(g\right)\)

\(m_{ddspu}=12+200-\left(0,5.2\right)=211\left(g\right)\)

\(C_{MgSO4}=\dfrac{60.100}{211}=28,44\)⁰/₀

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Mg+H2SO4->MgSO4+H2

0,5----0,5--------0,5--------0,5

n Mg=12\24=0,5 mol

=>VH2=0,5.22,4=11,2l

=>m H2SO4=0,5.98=49 g

=>C% =49\200.100=24,5g

=>m dd=12+200-0,5.2=211g

=>C%=0,4.120\211.100=22,74885%

PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

a) Ta có: \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)=n_{H_2}\) \(\Rightarrow V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\)

b) Theo PTHH: \(n_{HCl}=2n_{Fe}=0,4\left(mol\right)\)

\(\Rightarrow C\%_{HCl}=\dfrac{0,4\cdot36,5}{200}\cdot100\%=7,3\%\)

b) Theo PTHH: \(n_{FeCl_2}=n_{H_2}=0,2\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}m_{FeCl_2}=0,2\cdot127=25,4\left(g\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{Fe}+m_{ddHCl}-m_{H_2}=210,8\left(g\right)\)

\(\Rightarrow C\%_{FeCl_2}=\dfrac{25,4}{210,8}\cdot100\%\approx12,05\%\)

2Al+6HCl-->2AlCl₃+3H₂

0,3----0,9---------0,3------0,45

=>n _Al=8,1\17=0,3 mol

=>V_H2=0,45.22,4=10,08l

=>m _HCl=0,9.26,5=32,85g

=>m_AlCl3=0,3.133,5=40,05g

C2 :Bảo Toàn khối lượng 

=>m _AlCl3=40,05g

B nha

a. 2Al + 6HCl -> 2AlCl₃ + 3H₂

b. n_Al = \(\dfrac{8.1}{27}=0,3\left(mol\right)\)=> \(n_{H_2}=\dfrac{3}{2}.0,3=0,45\left(mol\right)\)

\(V_{H_2}=0,45.22,4=10,08\left(mol\right)\)

c. \(n_{HCl}=3n_{Al}=3.0,3=0,9\left(mol\right)=>m_{HCl}=0,9.36,5=32,85\left(g\right)\)

Vậy m = 32,85

\(Đặt:\)

\(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\)

\(n_{H_2}=\dfrac{6.72}{22.4}=0.3\left(mol\right)\)

\(Mg+2HCl\rightarrow MgCl_2+H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\)

\(m_{hh}=24x+56y=13.6\left(g\right)\\ n_{H_2}=x+y=0.3\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}x=0.1\\y=0.2\end{matrix}\right.\)

\(\%Mg=\dfrac{0.1\cdot24}{13.6}\cdot100\%=17.64\%\\ \%Fe=100-17.64=82.36\%\)

\(n_{HCl}=2n_{H_2}=2\cdot0.3=0.6\left(mol\right)\)

\(V_{HCl}=\dfrac{0.6}{2}=0.3\left(l\right)\)

\(m_Y=m_{MgCl_2}+m_{FeCl_2}=0.1\cdot95+0.2\cdot127=34.9\left(g\right)\)

a, \(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)

 \(m_{HCl}=109,5.10\%=10,95\left(g\right)\Rightarrow n_{HCl}=\dfrac{10,95}{36,5}=0,3\left(mol\right)\)

PTHH: 2Al + 6HCl → 2AlCl₃ + 3H₂

Mol:      0,1      0,3         0,1       0,15

Ta có: \(\dfrac{0,1}{2}=\dfrac{0,3}{6}\) ⇒ Al hết, HCl hết

\(V_{H_2}=0,15.22,4=3,36\left(l\right)\)

b, \(m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\)

c, m_{dd sau pứ} = 2,7 + 109,5 - 0,15.2 = 111,9 (g)

\(C\%_{ddAlCl_3}=\dfrac{13,35.100\%}{111,9}=11,93\%\)

PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)

Ta có: \(\left\{{}\begin{matrix}n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\n_{HCl}=\dfrac{109,5\cdot10\%}{36,5}=0,3\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,1}{2}=\dfrac{0,3}{6}\) \(\Rightarrow\) Al và HCl đều p/ứ hết

\(\Rightarrow\left\{{}\begin{matrix}n_{AlCl_3}=0,1\left(mol\right)\\n_{H_2}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{AlCl_3}=0,1\cdot133,5=13,35\left(g\right)\\V_{H_2}=0,15\cdot22,4=3,36\left(l\right)\\m_{H_2}=0,15\cdot2=0,3\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{Al}+m_{ddHCl}-m_{H_2}=111,9\left(g\right)\)

\(\Rightarrow C\%_{AlCl_3}=\dfrac{13,35}{111,9}\cdot100\%\approx11,93\%\)

nAl = 5.4/27 = 0.2 (mol) 

2Al + 6HCl => 2AlCl3 + 3H2 

0.2........0.6.........0.2.........0.3

VH2 = 0.3*22.4 = 6.72 (l) 

mAlCl3 = 0.2*133.5 = 26.7 (g)