Sửa đề : 11.2 g sắt

\(n_{Fe}=\dfrac{11.2}{56}=0.2\left(mol\right)\)

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

\(0.2....0.2.................0.2\)

\(m_{FeSO_4}=0.2\cdot152=30.4\left(g\right)\)

\(C_{M_{H_2SO_4}}=\dfrac{0.2}{0.05}=4\left(M\right)\)

\(m_{Fe}=\dfrac{11}{56}=0.19\left(mol\right)\)

\(Fe+H_2SO_4->FeSO_4+H_2\)

0.19   0.19            0.19              (mol)

\(m_{FeSO_4}=0.19\cdot152=28.28\left(g\right)\)

\(Cm=\dfrac{0.19}{0.05}=3.8M\)

nFe=11.256=0.2(mol)

mFeSO4=0,2⋅152=30,4(g)

\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)

PTHH: Fe₂O₃ + 3H₂SO₄ --> Fe₂(SO₄)₃ + 3H₂O

______0,05------>0,15--------->0,05

=> m_H2SO4 = 0,15.98 = 14,7(g)

=> \(C\%\left(H_2SO_4\right)=\dfrac{14,7}{100}.100\%=14,7\%\)

\(C\%\left(Fe_2\left(SO_4\right)_3\right)=\dfrac{0,05.400}{8+100}.100\%=18,52\%\)

PTHH: Fe₂(SO₄)₃ + 6NaOH --> 2Fe(OH)₃\(\downarrow\) + 3Na₂SO₄

________0,05----------------------->0,1

=> mFe(OH)₃ = 0,1.107=10,7(g)

a) Vì: m_A < 400 (g) nên phải có khí thoát ra → muối có dạng MHSO₄ và khí là: CO₂

b)

c) Tác dụng được với: MgCO₃, Ba(HSO₃)₂, Al₂O₃, Fe(OH)₂, Fe, Fe(NO₃)₂

Pt: 2NaHSO₄ + MgCO₃ → Na₂SO₄ + MgSO₄ + CO₂↑ + H₂O

2NaHSO₄ + Ba(HSO₃)₂ → BaSO₄ + Na₂SO₄ + SO₂↑ + 2H₂O

6NaHSO₄ + Al₂O₃ → 3Na₂SO₄ + Al₂(SO₄)₃ + 3H₂O

2NaHSO₄ + Fe(OH)₂ → Na₂SO₄ + FeSO₄ + 2H₂O

2NaHSO₄ + Fe → Na₂SO₄ + FeSO₄ + H₂↑

12NaHSO₄ + 9Fe(NO₃)₂ → 5Fe(NO₃)₃ + 2Fe₂(SO₄)₃ + 6Na₂SO₄ + 3NO↑ + 6H₂O

PTHH: \(CaCl_2+Na_2CO_3\rightarrow2NaCl+CaCO_3\downarrow\)

            \(NaCl+AgNO_3\rightarrow NaNO_3+AgCl\downarrow\)

A là dd NaCl

B là CaCO₃

C là dd NaNO₃

D là AgCl

Ta có: \(n_{AgCl}=\dfrac{57,4}{143,5}=0,4\left(mol\right)=n_{NaCl}\)

\(\Rightarrow n_{CaCO_3}=0,2\left(mol\right)=n_{Na_2CO_3}\) \(\Rightarrow\left\{{}\begin{matrix}m_{NaCl}=0,4\cdot58,5=23,4\left(g\right)\\m_{CaCO_3}=0,2\cdot100=20\left(g\right)\\m_{ddNa_2CO_3}=\dfrac{0,2\cdot106}{16\%}=132,5\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{ddA}=m_{ddCaCl_2}+m_{ddNa_2CO_3}-m_{CaCO_3}=290,1\left(g\right)\)

\(\Rightarrow C\%_{NaCl}=\dfrac{23,4}{290,1}\cdot100\%\approx8,07\%\)

\(n_{FeCl_3}=\dfrac{48,75}{162,5}=0,3(mol)\\ 3NaOH+FeCl_3\to Fe(OH)_3\downarrow+3NaCl\\ \Rightarrow n_{Fe(OH)_3}=0,3(mol);n_{NaOH}=n_{NaCl}=0,9(mol)\\ a,m_{Fe(OH)_3}=0,3.107=32,1(g)\\ b,m_{dd_{NaOH}}=\dfrac{0,9.40}{10\%}=360(g)\\ c,C\%_{NaCl}=\dfrac{0,9.58,5}{360+48,75-32,1}.100\%=13,98\%\\ \)

\(d,2Fe(OH)_3+3H_2SO_4\to Fe_2(SO_4)_3+6H_2O\\ \Rightarrow n_{H_2SO_4}=0,45(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,45.98}{20\%}=220,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{220,5}{1,14}=193,42(ml)\)

\(a.n_{CO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ a.Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\\ 0,25.......0,25............0,25..........0,25\left(mol\right)\\ C_{MddCa\left(OH\right)_2}=\dfrac{0,25}{0,1}=2,5\left(M\right)\\ b.m_{\downarrow}=m_{CaCO_3}=100.0,25=25\left(g\right)\)

Bài 10:

PTHH: \(Na_2CO_3+BaCl_2\rightarrow2NaCl+BaCO_3\downarrow\)

a) Ta có: \(n_{Na_2CO_3}=\dfrac{200\cdot10,6\%}{106}=0,2\left(mol\right)=n_{BaCO_3}\)

\(\Rightarrow m_{BaCO_3}=0,2\cdot197=39,4\left(g\right)\)

b) Theo PTHH: \(n_{BaCl_2}=n_{BaCO_3}=0,2mol\)

\(\Rightarrow C\%_{BaCl_2}=\dfrac{0,2\cdot208}{120}\cdot100\%\approx34,67\%\)

c) Theo PTHH: \(n_{NaCl}=2n_{BaCl_2}=0,4mol\) \(\Rightarrow m_{NaCl}=0,4\cdot58,5=23,4\left(g\right)\)

Mặt khác: \(m_{dd}=m_{ddNa_2CO_3}+m_{ddBaCl_2}-m_{BaCO_3}=280,6\left(g\right)\)

\(\Rightarrow C\%_{NaCl}=\dfrac{23,4}{280,6}\cdot100\%\approx8,34\%\)

Bài 11 và bài 12 tương tự bài 10