2Al + 6HCl -> 2AlCl₃ + 3H₂ (1)

ZnO + 2HCl -> ZnCl₂ + H₂O (2)

a) n_H2= 13,44/22.4=0.6(mol) -> mH2=0,6.2=1,2(g)

Theo PTHH: n_Al = 2/3 n_H2 = 2/3 . 0,6= 0,4(mol) -> m_Al = 0,4 . 27=10,8(g)

-> m_ZnO = 27-10,8= 16,2(g)

b) n_ZnO = 16,2/81=0,2(mol)

Theo PTHH (2): nHCl = 2nZnO=2.0,2=0,4(mol)

Theo PTHH (1) : nHCl=2nH₂=2.0,6=1,2(mol)

-> \(\Sigma\)nHCl = 0,4+1,2=1,6(mol)

-> mHCl = 1,6.36,5= 58,4(g)

-> mdd_HCl = 58,4.100/29,2= 200(g)

c) Theo PTHH (1): nAlCl₃ = 2/3 nH₂ = 2/3 . 0,6=0,4(mol)                                         -> mAlCl3=0,4.133,5=53,4(g)

mdd sau phản ứng= m_A + mddHCl - mH2 =27+200-1,2 =225,8(g)

-> C% AlCl3 = 53,4.100%/225,8 = 20,88%

Theo PTHH (2) nZnCl2 =nZnO= 0,2(mol)-> mZnCl2=0,2.136=27,2(g)

-> C% ZnCl2= 27,2.100%/255,8=10,63%

\(n_{Fe}=\dfrac{2,8}{56}=0,05\left(mol\right)\)

PTHH :

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

0,05   0,1           0,05      0,05 

\(V_{H_2}=0,05.22,4=1,12\left(l\right)\)

\(V_{HCl}=\dfrac{n}{C_M}=\dfrac{0,1}{1}=0,1\left(l\right)\)

\(m_{FeCl_2}=0,05.127=6,35\left(g\right)\)

nH2 = 2.24/22.4 = 0.1 (mol) 

Zn + 2HCl => ZnCl2 + H2 

ZnO + 2HCl => ZnCl2 + H2O 

nZn = nH2 = 0.1 (mol) 

=> mZn = 6.5 g

mZnO = 14.6 - 6.5 = 8.1 (g) 

nZnO = 0.1 (mol)  

%Zn = 6.5/14.6 * 100% = 44.52%

%ZnO = 55.48%

nHCl = 0.1*2 + 0.1*2= 0.4 (mol) 

Vdd HCl = 0.4 / 0.5 = 0.8 l 

Tiếp bài của creeper nhé:

c. Ta có: \(n_{ZnO}=\dfrac{4,86}{81}=0,06\left(mol\right)\)

Theo PT₍₁₎: \(n_{HCl}=2.n_{ZnO}=2.0,06=0,12\left(mol\right)\)

Theo PT₍₂₎: \(n_{HCl}=2.n_{Zn}=2.0,1=0,2\left(mol\right)\)

=> \(n_{HCl}=0,12+0,2=0,32\left(mol\right)\)

=> \(m_{HCl}=0,32.36,5=11,68\left(g\right)\)

Ta có: \(C_{\%_{HCl}}=\dfrac{11,68}{m_{dd_{HCl}}}.100\%=12\%\)

=> \(m_{dd_{HCl}}=\dfrac{292}{3}\left(g\right)\)

Theo đề, ta có: 

\(D=\dfrac{\dfrac{292}{3}}{V_{dd_{HCl}}}=1,2\)(g/ml)

=> \(V_{dd_{HCl}}=81,1\left(ml\right)\)

\(n_{H2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\)

Pt : \(2Al+6HCl\rightarrow2AlCl_3+3H_2|\)

        2           6              2           3

        a          0,6                       1,5a

    \(Fe+2HCl\rightarrow FeCl_2+H_2|\)

      1         2                       1b

      b       0,8

a) Gọi a là số mol của Al

           b là số mol của Fe

\(m_{Al}+m_{Fe}=27,8\left(g\right)\)

⇒ \(n_{Al}.M_{Al}+n_{Fe}.M_{Fe}=27,8g\)

  ⇒ 27a + 56b = 27,8g(1)

Theo phương trình : 1,5a + 1b = 0,7(2)

Từ(1),(2), ta có hệ phương trình : 

          27a + 56b = 27,8

           1,5a + 1b = 0,7

           ⇒ \(\left\{{}\begin{matrix}a=0,2\\b=0,4\end{matrix}\right.\)

    \(m_{Al}=0,2.27=5,4\left(g\right)\)

    \(m_{Fe}=0,4.56=22,4\left(g\right)\)

b) ⁰/₀Al = \(\dfrac{5,4.100}{27,8}=19,42\)⁰/₀

    ⁰/₀Fe = \(\dfrac{22,4.100}{27,8}=80,58\)⁰/₀

c) \(n_{HCl\left(tổng\right)}=0,6+0,8=1,4\left(g\right)\)

⇒ \(m_{HCl}=1,4.36,5=51,1\left(g\right)\)

 Chúc bạn học tốt

a.\(n_{H_2}=\dfrac{V_{H_2}}{22,4}=\dfrac{8,96}{22,4}=0,4mol\)

Gọi \(\left\{{}\begin{matrix}n_{Fe}=x\\n_{Zn}=y\end{matrix}\right.\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

 x                                      x ( mol )

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

 y                                        y   ( mol )

Ta có:

\(\left\{{}\begin{matrix}56x+65y=25,55\\x+y=0,4\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,05\\y=0,35\end{matrix}\right.\)

\(\Rightarrow m_{Fe}=0,05.56=2,8g\)

\(\Rightarrow m_{Zn}=0,35.65=22,75g\)

\(\%m_{Fe}=\dfrac{2,8}{25,55}.100=10,95\%\)

\(\%m_{Zn}=100\%-10,95\%=89,05\%\)

b.\(n_{HCl}=2.0,05+2.0,35=0,8mol\)

\(C_M=\dfrac{n}{V}\Rightarrow V=\dfrac{n}{C_M}=\dfrac{0,8}{2}=0,4l\)

\(1)n_{H_2}=\dfrac{3,36}{22,4}=0,15(mol)\\ Mg+2HCl\to MgCl_2+H_2\\ Fe+2HCl\to FeCl_2+H_2\)

Từ giả thiết và theo PT: 

\(\begin{cases} 24n_{Mg}+56n_{Fe}=5,2\\ n_{Mg}+n_{Fe}=0,15 \end{cases}\\ \Rightarrow n_{Mg}=0,1(mol);n_{Fe}=0,05(mol)\)

\(\Rightarrow \begin{cases} \%m_{Mg}=\dfrac{0,1.24}{5,2}.100\%=46,15\%\\ \%m_{Fe}=100-46,15=53,85\% \end{cases}\\ 2)\Sigma n_{HCl}=2n_{H_2}=0,3(mol)\\ \Rightarrow V_{dd_{HCl}}=\dfrac{0,3}{1}=0,3(l)=300(ml)\)