\(a,\left\{{}\begin{matrix}n_{O_2}=1.30\%=0,3\left(mol\right)\\n_{CO_2}=1.20\%=0,2\left(mol\right)\\n_T=1-0,3-0,2=0,5\left(mol\right)\end{matrix}\right.\)

\(b,m_{O_2}=0,3.32=9,6\left(g\right)\)

\(c,m_{hh}=\dfrac{9,6}{49,48\%}=19,4\left(g\right)\\ m_{CO_2}=0,2.44=8,8\left(g\right)\\ \rightarrow m_T=19,4-9,6-8,8=1\left(g\right)\\ \rightarrow M_T=\dfrac{1}{0,5}=2\left(\text{g/mol}\right)\\ \rightarrow T:H_2\)

a. %V (ở cùng điều kiện) cũng là %n

\(Tacó:\%V_T=100-30-20=50\%\\ Trong1molhỗnhợp:\\ n_{O_2}=1.30\%=0,3\left(mol\right)\\ n_{CO_2}=1.20\%=0,2\left(mol\right)\\ n_T=1.50\%=0,5\left(mol\right)\\ b.m_{O_2}=0,3.32=9,6\left(g\right)\\ c.\%m_{O_2}tronghỗnhợplà49,48\%\\ Trong1molhỗnhợp:m_{hh}=\dfrac{9,6}{49,48\%}=19,4\left(g\right)\\ m_{CO_2}=0,2.44=8,8\left(g\right)\\ \Rightarrow m_T=19,4-9,6-8,8=1\left(g\right)\\ \Rightarrow M_T=\dfrac{1}{0,5}=2\\ \Rightarrow TlàH_2\)

a) \(M_X=19.2=38\left(g/mol\right)\)

`=>` \(d_{X/kk}=\dfrac{38}{29}=1,310345\)

b) \(m_X=0,4.38=15,2\left(g\right)\)

Gọi \(\left\{{}\begin{matrix}n_{O_2}=x\left(mol\right)\\n_{CO_2}=y\left(mol\right)\end{matrix}\right.\)

`=>` \(\left\{{}\begin{matrix}32x+44y=15,2\\x+y=0,4\end{matrix}\right.\Leftrightarrow x=y=0,2\)

\(m_Y=0,1.28+15,2=18\left(g\right)\)

`=>` \(\left\{{}\begin{matrix}\%m_{N_2}=\dfrac{0,1.28}{18}.100\%=15,56\%\\\%m_{O_2}=\dfrac{0,2.32}{18}.100\%=35,56\%\\\%m_{CO_2}=100\%-15,56\%-35,56\%=48,88\%\end{matrix}\right.\)

b) \(M_{hh}=4.10=40\left(g/mol\right)\)

Gọi \(n_{NO_2}=a\left(mol\right)\)

`=>` \(\left\{{}\begin{matrix}m_{hh}=18+46a\left(g\right)\\n_{hh}=0,5+0,1+a=0,6+a\left(mol\right)\end{matrix}\right.\)

`=>` \(M_{hh}=\dfrac{m_{hh}}{n_{hh}}=\dfrac{18+46a}{0,6+a}=40\)

`=> a = 1`

`=> V_{NO_2(đktc)} = 1.22,4 = 22,4 (l)`

a. Gọi x, y lần lượt là số mol của CH₄ và CO₂

Ta có: \(n_A=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)

Theo đề, ta có:

- x + y = 0,4 (1)

- 16x + 44y = 9,2 (2)

Từ (1) và (2), ta có HPT: 

\(\left\{{}\begin{matrix}x+y=0,4\\16x+44y=9,2\end{matrix}\right.\)

Giải ra, ta được: 

 x = 0,3, y = 0,1

=> \(m_{CH_4}=0,3.16=4,8\left(g\right);m_{CO_2}=0,1.44=4,4\left(g\right)\)

b. Ta có: \(\overline{M_A}=\dfrac{4,8+4,4}{0,3+0,1}=23\left(g\right)\)

=> \(d_{\dfrac{A}{O_2}}=\dfrac{\overline{M_A}}{M_{O_2}}=\dfrac{23}{32}=0,71875\left(lần\right)\)

Gọi a,b lần lượt là số mol của O₂ và O₃

=> \(\dfrac{32a+48b}{a+b}=22.2=44\)

\(\Leftrightarrow32a+48b=44a+44b\)

\(\Leftrightarrow12a=4b\)

=> b=3a

=> %VO₂ = \(\dfrac{a}{a+3a}.100\%=25\%\), %VO₃ = 75%

b) Thể tích O₂ trong 2,24 lít khí là: 25%.2,24 = 0,56 lít

thể tích O₃ = 1,68 lít

=> nO₂ = \(\dfrac{0,56}{22,4}=0,025mol\Rightarrow mO_2=0,8g\)

\(nO_3=\dfrac{1,68}{22,4}=0,075mol\Rightarrow mO_3=0,075.48=3,6g\)

\(Coi: n_{Cl_2} = 1(mol) \to n_{O_2} = 2(mol)\\ \%V_{Cl_2} = \dfrac{1}{1+2}.100\% = 33,33\%\\ \%V_{O_2} = 100\% -33,33\% = 66,67\%\\ M_A = \dfrac{1.71+2.32}{1+2}=45(g/mol)\\ d_{A/H_2} = \dfrac{45}{2} = 22,5\)

\(\text{Trong 6,72 lít khí A : }m_A = 45.\dfrac{6,72}{22,4}=13,5(gam)\)

Áp dụng quy tắc đường chéo:

\(a.\\ \Rightarrow\dfrac{V_{Cl_2}}{V_{O_2}}=\dfrac{15,6}{23,4}=\dfrac{2}{3}\\ \Rightarrow\left\{{}\begin{matrix}\%V_{Cl_2}=40\%\\\%V_{O_2}=60\%\end{matrix}\right.\)

\(b.\) 

Ta có: \(\dfrac{n_{Cl_2}}{n_{O_2}}=\dfrac{2}{3}\Leftrightarrow\dfrac{m_{Cl_2}}{m_{O_2}}=\dfrac{71.2}{32.3}=\dfrac{71}{48}\Leftrightarrow48m_{Cl_2}-71m_{O_2}=0\)

Mặt khác: \(m_{Cl_2}+m_{O_2}=5,95\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Cl_2}=3,55\left(g\right)\\m_{O_2}=2,4\left(g\right)\end{matrix}\right.\)

a)

$n_{Cl_2} :  n_{O_2} = 1 : 2$

Suy ra : 

$\%V_{Cl_2} = \dfrac{1}{1 + 2}.100\% = 33,33\%$
$\%V_{O_2} = \dfrac{2}{1 + 2}.100\% = 66,67\%$

b)

Coi $n_{Cl_2} = 1 (mol) \Rightarrow n_{O_2} = 2(mol)$
$\%m_{Cl_2} = \dfrac{1.71}{1.71 + 2.32}.100\% = 52,59\%$
$\%m_{O_2} = 100\% -52,59\% = 47,41\%$

c)

$M_A = \dfrac{71.1 + 32.2}{1 + 2} = 45(g/mol)$
$d_{A/B} = \dfrac{45}{28} = 1,607$