Ta có: \(n_{CaCO_3}=\dfrac{25}{100}=0,25\left(mol\right)\)
\(m_{HCl}=50.18,25\%=9,125\left(g\right)\Rightarrow n_{HCl}=\dfrac{9,125}{36,5}=0,25\left(mol\right)\)
PT: \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
Xét tỉ lệ: \(\dfrac{0,25}{1}>\dfrac{0,25}{2}\), ta được CaCO3.
Theo PT: \(n_{CaCO_3\left(pư\right)}=n_{CaCl_2}=n_{CO_2}=\dfrac{1}{2}n_{HCl}=0,125\left(mol\right)\)
Ta có: m dd sau pư = mCaCO3 (pư) + m dd HCl - mCO2 = 0,125.100 + 50 - 0,125.44 = 57 (g)
\(\Rightarrow C\%_{CaCl_2}=\dfrac{0,125.111}{57}.100\%\approx24,34\%\)