Câu 1:
\(C_2H_4+H_2O\underrightarrow{t^o,xt}C_2H_5OH\)
\(C_2H_5OH+O_2\underrightarrow{^{mengiam}}CH_3COOH+H_2O\)
\(CH_3COOH+C_2H_5OH⇌CH_3COOC_2H_5+H_2O\) (xt: H2SO4 đặc, to)
(4) \(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
Câu 2:
a, \(n_{C_2H_4}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
PT: \(C_2H_4+H_2O\underrightarrow{^{t^o,xt}}C_2H_5OH\)
Theo PT: \(n_{C_2H_5OH}=n_{C_2H_4}=0,4\left(mol\right)\Rightarrow m_{C_2H_5OH}=0,4.46=18,4\left(g\right)\)
b, \(V_{C_2H_5OH}=\dfrac{18,4}{0,8}=23\left(ml\right)\)
⇒ Độ rượu = \(\dfrac{23}{23+150}.100\approx13,3^o\)
c, \(n_{CH_3COOH}=\dfrac{120}{60}=2\left(mol\right)\)
PT: \(CH_3COOH+C_2H_5OH⇌CH_3COOC_2H_5+H_2O\) (xt: H2SO4 đặc, to)
Xé tỉ lệ: \(\dfrac{2}{1}>\dfrac{0,4}{1}\), ta được CH3COOH dư.
Theo PT: \(n_{CH_3COOC_2H_5\left(LT\right)}=n_{C_2H_5OH}=0,4\left(mol\right)\)
Mà: H = 95%
\(\Rightarrow n_{CH_3COOH\left(TT\right)}=0,4.95\%=0,38\left(mol\right)\)
\(\Rightarrow m_{CH_3COOC_2H_5\left(TT\right)}=0,38.88=33,44\left(g\right)\)