\(S_{85^oC}=\dfrac{m_{CuSO_4\left(dd.ở.85^oC\right)}}{1877-m_{CuSO_4\left(dd.ở.85^oC\right)}}.100=87,7\left(g\right)\)
=> \(m_{CuSO_4\left(dd.ở.85^oC\right)}=877\left(g\right)\)
=> \(m_{H_2O\left(dd.ở.85^oC\right)}=1877-877=1000\left(g\right)\)
Gọi số mol CuSO4.5H2O là a (mol)
=> \(n_{CuSO_4\left(tách.ra\right)}=a\left(mol\right)\)
=> \(m_{CuSO_4\left(dd.ở.25^oC\right)}=877-160a\left(g\right)\)
\(n_{H_2O\left(tách.ra\right)}=5a\left(mol\right)\)
=> \(m_{H_2O\left(dd.ở.25^oC\right)}=1000-18.5a=1000-90a\left(g\right)\)
\(S_{25^oC}=\dfrac{877-160a}{1000-90a}.100=40\left(g\right)\)
=> a = \(\dfrac{477}{124}\left(mol\right)\)
=> \(m_{CuSO_4.5H_2O}=\dfrac{477}{124}.250=\dfrac{59625}{62}\left(g\right)\)