Coi $m_{dd\ H_2SO_4} = 100(gam)$
$n_{H_2SO_4} = \dfrac{100.24,5\%}{98} = 0,25(mol)$
\(2M_xO_y + 2yH_2SO_4 \to xM_2(SO_4)_{2y/x} + 2yH_2O\)
Theo PTHH :
$n_{oxit} = \dfrac{1}{y}.n_{H_2SO_4} = \dfrac{0,25}{y}(mol)$
$n_{muối} = \dfrac{x}{2y}.n_{H_2SO_4} = \dfrac{0,25x}{2y}(mol)$
Ta có :
$m_{muối} = \dfrac{0,25x}{2y}.(2M + 96.\dfrac{2y}{x}) = \dfrac{0,25Mx}{y} + 24(gam)$
$m_{dd} = \dfrac{0,25}{y}.(Mx + 16y) + 100 = \dfrac{0,25Mx}{y} + 104(gam)$
Suy ra :
\(C\% = \dfrac{ \dfrac{0,25Mx}{y} + 24}{\dfrac{0,25Mx}{y} + 104}.100\% = 32,2\%\)
Suy ra :
Mx/y = 45
Với x = y = 1 thì M = 56(Fe)
Vậy Oxit là FeO