CTHH cần tìm : $R_2O_3$
Coi $n_{H_2SO_4} = 3(mol)$
R2O3 + 3H2SO4 → R2(SO4)3 + 3H2O
1..............3..................1..................................(mol)
Ta có :
$m_{dd\ H_2SO_4} = \dfrac{3.98}{10\%} = 2940(gam)$
$m_{dd\ sau\ pư} = 2R + 16.3 + 2940 = 2R + 2988(gam)$
Suy ra :
$C\% = \dfrac{2R + 96.3}{2R + 2988}.100\% = 12,9\%$
$\Rightarrow R = 56(Fe)$
Vậy oxit là $Fe_2O_3$
Gọi công thức oxit là A2O3
PTHH: \(A_2O_3+3H_2SO_4\rightarrow A_2\left(SO_4\right)_3+3H_2O\)
Giả sử \(n_{A_2O_3}=1\left(mol\right)=n_{A_2\left(SO_4\right)_3}\) \(\Rightarrow n_{H_2SO_4}=3\left(mol\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{3\cdot98}{10\%}=2940\left(g\right)\)
Mặt khác: \(m_{dd\left(sau.p/ứ\right)}=m_{A_2O_3}+m_{ddH_2SO_4}=2A+2988\left(g\right)\)
\(\Rightarrow C\%_{A_2\left(SO_4\right)_3}=\dfrac{2A+288}{2A+2988}=0,129\) \(\Rightarrow A=56\) (Sắt)
Vậy CT oxit cần tìm là Fe2O3