\(n_{Na_2O}=\dfrac{6.2}{62}=0.1\left(mol\right)\)
\(n_{HCl}=\dfrac{91.25\cdot10\%}{36.5}=0.25\left(mol\right)\)
\(Na_2O+2HCl\rightarrow2NaCl+H_2O\)
\(TC:\dfrac{0.1}{1}< \dfrac{0.25}{2}\Rightarrow HCldư\)
\(m_{NaCl}=0.1\cdot2\cdot58.5=11.7\left(g\right)\)
\(m_{dd}=6.2+91.25=97.45\left(g\right)\)
\(C\%_{NaCl}=\dfrac{11.7}{97.45}\cdot100\%=12\%\)
\(C\%_{HCl\left(dư\right)}=\dfrac{\left(0.25-0.2\right)\cdot36.5}{97.45}\cdot100\%=1.87\%\)
nNa2O=0,1(mol)
PTHH: Na2O + H2O -> 2 NaOH
-> nNaOH=0,2(mol)
nHCl=9,125(mol)->nHCl=0,25(mol)
PTHH: NaOH + HCl -> NaCl + H2O
Vì 0,25/1 > 0,2/1
=> NaOH hết, HCl dư, tính theo nNaOH
-> nNaCl=nHCl(p.ứ)=nNaOH=0,2(mol)
=>mNaCl=58,5.0,2= 11,7(g)
mHCl(dư)=0,05.36,5= 1,825(g)
mddsau=0,2.40+ 91,25= 99,25(g)
=>C%ddHCl(dư)=(1,825/99,25).100=1,839%
C%ddNaCl=(11,7/99,25).100=11,788%
