\(n_{Na_2S}=n_{NaHS}=a\left(mol\right)\)
\(n_{NaOH}=2a+a=3a=0.03\left(mol\right)\)
\(\Rightarrow a=0.01\)
\(V=\left(0.01+0.01\right)\cdot22.4=0.448\left(l\right)\)
TH2 : NaOH dư
\(n_{NaOH\left(dư\right)}=n_{Na_2S}=a\left(mol\right)\)
\(2NaOH+H_2S\rightarrow Na_2S+2H_2O\)
\(2a........a.........a\)
\(n_{NaOH\left(dư\right)}=0.03-2a=a\left(mol\right)\)
\(\Rightarrow a=0.03\)
\(V=0.672\left(l\right)\)
nNaOH= 0,03(mol)
PTHH: 2 NaOH + H2S -> Na2S + + 2 H2O
2x_____________x_____x(mol)
NaOH + H2S -> NaHS + H2O
x________x_____x(mol)
nNa2S=nNaHS=x(mol)
2x+x=0,03 <=>x=0,01
=> V(H2S,đktc)=2x.22,4=0,448(l)= 448(ml)
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