Câu 33:
\(n_{C_6H_2Br_3\left(OH\right)}=\dfrac{4,965}{331}=0,015\left(mol\right)\)
PT: \(C_6H_5OH+3Br_2\rightarrow C_6H_2Br_3\left(OH\right)+3HBr\)
Theo PT: \(n_{Br_2}=3n_{C_6H_2Br_3\left(OH\right)}=0,045\left(mol\right)\)
\(\Rightarrow m_{Br_2}=0,045.160=7,2\left(g\right)\)
Đáp án: D
Câu 34:
Ta có: 94nC6H5OH + 32nCH3OH = 15,8 (1)
PT: \(C_6H_5OH+Na\rightarrow C_6H_5ONa+\dfrac{1}{2}H_2\)
\(CH_3OH+Na\rightarrow CH_3ONa+\dfrac{1}{2}H_2\)
Theo PT: \(n_{H_2}=\dfrac{1}{2}n_{C_6H_5ONa}+\dfrac{1}{2}n_{CH_3OH}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{C_6H_5OH}=0,1\left(mol\right)\\n_{CH_3OH}=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\%n_{CH_3OH}=\dfrac{0,2}{0,1+0,2}.100\%\approx66,67\%\)
Đáp án: C
