Bài 15:
a) Zn + 2 HCl -> ZnCl2 + H2
2 Al+ 6 HCl -> 2 AlCl3 + 3 H2
Al2O3 + 6 HCl -> 2 AlCl3 + 3 H2O
Al(OH)3 +3 HCl -> AlCl3 +3 H2O
Fe3O4 + 8 HCl -> FeCl2 +2 FeCl3 +4 H2O
Fe +2 HCl -> FeCl2 + H2
Fe(OH)3 +3 HCl -> FeCl3 + 3 H2O
CaCO3 +2 HCl -> CaCl2 + CO2 + H2O
AgNO3 + HCl -> AgCl + HNO3
Bài 15b)
Ba(OH)2 + H2SO4 -> BaSO4 +2 H2O
BaCl2 + H2SO4 -> BaSO4 + 2 HCl
Cu(OH)2 + H2SO4 -> CuSO4 + 2 H2O
CuO + H2SO4 -> CuSO4 + H2O
Fe2O3 + 3 H2SO4 -> Fe2(SO4)3 +3 H2O
Fe + H2SO4 -> FeSO4 + H2
Fe(OH)2 + H2SO4 -> FeSO4 + 2 H2O
2 Fe(OH)3 + 3 H2SO4 -> Fe2(SO4)3 + 6 H2O
2Al + 3 H2SO4 -> Al2(SO4)3 + 3 H2
Al2O3 + 3 H2SO4 -> Al2(SO4)3 +3 H2O
Câu 14:
a) Đặt nZn=a(mol); nFe=b(mol) (a,b >0)
nH2SO4 = 0,5(mol); nH2=0,3(mol)
Vì: 0,5/1 > 0,3/1 => H2SO4 dư, hỗn hợp kim loại dùng hết
PTHH: Zn + H2SO4 -> ZnSO4 + H2
a_________a______a______a(mol)
Fe+ H2SO4 -> FeSO4 + H2
b____b___b______b(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}56a+65b=17,7\\a+b=0,3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\)
=> mFe=0,2.56=11,2(g)
=>%mFe= (11,2/17,7).100=63,277%
=>%mZn= 36,723%
b) nFeSO4= nFe=0,2(mol); nZnSO4=nZn=0,1(mol)
nH2SO4(dư)=0,5-0,3=0,2(mol)
Vddsau= VddH2SO4(bđ)=0,5(l)
=>CMddH2SO4(dư)=0,2/0,5=0,4(M)
CMddZnSO4= 0,1/0,5=0,2(M)
CMddFeSO4=0,2/0,5=0,4(M)