a, PT: \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
b, Ta có: \(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\)
\(V_{O_2}=18,48.\dfrac{1}{5}=3,696\left(l\right)\Rightarrow n_{O_2}=\dfrac{3,696}{22,4}=0,165\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,2}{4}>\dfrac{0,165}{5}\), ta được P dư.
Theo PT: \(n_{P_2O_5}=\dfrac{2}{5}n_{O_2}=0,066\left(mol\right)\)
\(\Rightarrow m_{P_2O_5}=0,066.142=9,372\left(g\right)\)