\(n_{Na_2SO_4}=\dfrac{9,94}{142}=0,07\left(mol\right)\)
\(n_{Ba\left(OH\right)_2}=\dfrac{100.20,52\%}{171}=0,12\left(mol\right)\)
\(Na_2SO_4+Ba\left(OH\right)_2\rightarrow BaSO_4+2NaOH\)
0,07..........0,12
Lập tỉ lệ : \(\dfrac{0,07}{1}< \dfrac{0,12}{1}\) => Sau phản ứng Ba(OH)2 dư
=> \(m_{BaSO_4}=0,07.233=16,31\left(g\right)\)
Dung dịch A gồm Ba(OH)2 dư, NaCl
\(C\%_{Ba\left(OH\right)_2\left(dư\right)}=\dfrac{\left(0,12-0,07\right).171}{9,94+100-16,31}.100=9,13\%\)
\(C\%_{NaOH}=\dfrac{0,07.2.40}{9,94+100-16,31}.100=5,98\%\)
nNa2SO4=\(\dfrac{9,94}{142}=0,07mol\)
mBa(OH)2= \(\dfrac{100.20,52}{100}=20,52\) g
nBa(OH)2=\(\dfrac{20,52}{171}=0,12mol\)
Na2SO4 + Ba(OH)2 → 2NaOH + BaSO4
Bđ: 0,07 0,12
Pư: 0,07 0,07 0,14 0,07
Sau pư: 0 0,05 0,14 0,07
a) mBaSO4= 0,07.233=16,31g
b) mdd sau pư = mNa2SO4 + mddBa(OH)2 - mBaSO4
= 9,94 + 100 - 16,31=93,63g
C% Ba(OH)2 dư=\(\dfrac{0,05.171}{93,63}.100\%\approx9,13\%\)
C% NaOH=\(\dfrac{0,14.40}{93,63}.100\%\approx5,98\%\)